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Pure Appl. Chem., 1995, Vol. 67, No. 6, pp. 859-872

http://dx.doi.org/10.1351/pac199567060859

Thermodynamics in the treatment of vapor/liquid equilibrium (VLE) data

H. C. Van Ness

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  • Lasala Silvia, Chiesa Paolo, Di Bona Daniele, Consonni Stefano: Vapour – Liquid Equilibrium Measurements of CO2 based Mixtures: Experimental Apparatus and Testing Procedures. Energy Procedia 2014, 45, 1215. <http://dx.doi.org/10.1016/j.egypro.2014.01.127>
  • Urdaneta P. Mario R.: Using the NRTL model with the Vidal equation of state EOS-qE formulation for vapor/liquid equilibrium calculations. Fluid Phase Equilibria 2014, 365, 123. <http://dx.doi.org/10.1016/j.fluid.2014.01.001>
  • Lin Yi-Feng, Tu Chein-Hsiun: Isobaric vapor–liquid equilibria for the binary and ternary mixtures of 2-propanol, water, and 1,3-propanediol at P=101.3kPa: Effect of the 1,3-propanediol addition. Fluid Phase Equilibria 2014, 368, 104. <http://dx.doi.org/10.1016/j.fluid.2014.02.006>
  • Klauck Mandy, Silbermann Rico, Metasch Robert, Jasinowski Tatjana, Kalies Grit, Schmelzer Jürgen: VLE and LLE in ternary systems of two associating components (water, aniline, and cyclohexylamine) and a hydrocarbon (cyclohexane or methylcyclohexane). Fluid Phase Equilibria 2014, 369, 95. <http://dx.doi.org/10.1016/j.fluid.2014.02.023>
  • Lai Hung-Sheng, Lin Yi-Feng, Tu Chein-Hsiun: Isobaric (vapor+liquid) equilibria for the ternary system of (ethanol+water+1,3-propanediol) and three constituent binary systems at P=101.3kPa. The Journal of Chemical Thermodynamics 2014, 68, 13. <http://dx.doi.org/10.1016/j.jct.2013.08.020>
  • Hirawan Ranjeetha, Sinha Sumit, Iwarere Samuel A., Raal J. David, Naidoo Paramespri, Ramjugernath Deresh: Vapor–Liquid Equilibrium Data for 1-Methyl-2-Pyrrolidone + (1-Butanol or 1-Hexene or Water) Binary Mixtures. J. Chem. Eng. Data 2014, 140402155655004. <http://dx.doi.org/10.1021/je500092v>
  • Hartono Ardi, Saeed Muhammad, Ciftja Arlinda F., Svendsen Hallvard F.: Binary and ternary VLE of the 2-amino-2-methyl-1-propanol (AMP)/piperazine (Pz)/water system. Chemical Engineering Science 2013, 91, 151. <http://dx.doi.org/10.1016/j.ces.2013.01.015>
  • Hartono Ardi, Saleem Fahad, Arshad Muhammad Waseem, Usman Muhammad, Svendsen Hallvard F.: Binary and ternary VLE of the 2-(diethylamino)-ethanol (DEEA)/3-(methylamino)-propylamine (MAPA)/water system. Chemical Engineering Science 2013, 101, 401. <http://dx.doi.org/10.1016/j.ces.2013.06.052>
  • Narasigadu Caleb, Naidoo Paramespri, Coquelet Christophe, Richon Dominique, Ramjugernath Deresh: A novel static analytical apparatus for phase equilibrium measurements. Fluid Phase Equilibria 2013, 338, 188. <http://dx.doi.org/10.1016/j.fluid.2012.11.008>
  • Pavlíček Jan, Andresová Adéla, Bogdanić Grozdana, Wichterle Ivan: Vapour–liquid equilibria in binary and ternary systems composed of 2,3-dimethylbutane, diisopropyl ether, and 3-methyl-2-butanone at 313.15, 323.15 and 313.15K. Fluid Phase Equilibria 2013, 344, 59. <http://dx.doi.org/10.1016/j.fluid.2013.01.020>
  • Teodorescu Mariana, Dragoescu Dana, Gheorghe Daniela: Isothermal (vapour+liquid) equilibria for (nitromethane or nitroethane+1,4-dichlorobutane) binary systems at temperatures between (343.15 and 363.15)K. The Journal of Chemical Thermodynamics 2013, 56, 32. <http://dx.doi.org/10.1016/j.jct.2012.06.033>
  • Rudyk Svetlana: Determination of saturation pressures using experimental data of modified SC-CO2 extraction of crude oil by consistency test. The Journal of Supercritical Fluids 2013, 82, 63. <http://dx.doi.org/10.1016/j.supflu.2013.05.021>
  • Marcilla Antonio, del Mar Olaya María, Serrano María Dolores, Garrido María Angeles: Pitfalls in the Evaluation of the Thermodynamic Consistency of Experimental VLE Data Sets. Ind. Eng. Chem. Res. 2013, 52, 13198. <http://dx.doi.org/10.1021/ie401646j>
  • Narasigadu Caleb, Naidoo Paramespri, Coquelet Christophe, Richon Dominique, Ramjugernath Deresh: Isothermal Vapor–Liquid Equilibrium Data for the Butan-2-one + Methanol or Ethanol Systems Using a Static-Analytic Microcell. J. Chem. Eng. Data 2013, 58, 1280. <http://dx.doi.org/10.1021/je400065j>
  • Klauck Mandy, Silbermann Rico, Metasch Robert, Unger Sven, Schmelzer Jürgen: Introduction of the amine group at cycloaliphatic hydrocarbon (c-CHNH2) for the modified UNIFAC (Dortmund) model and validation in multicomponent systems containing cyclohexylamine. Fluid Phase Equilb 2012, 314, 169. <http://dx.doi.org/10.1016/j.fluid.2011.09.010>
  • Pavlíček Jan, Bogdanić Grozdana, Wichterle Ivan: Vapour–liquid and chemical equilibria in the ethyl ethanoate+ethanol+propyl ethanoate+propanol system accompanied with transesterification reaction. Fluid Phase Equilibria 2012, 328, 61. <http://dx.doi.org/10.1016/j.fluid.2012.05.016>
  • Rozmus Justyna, de Hemptinne Jean-Charles, Ferrando Nicolas, Mougin Pascal: Long chain multifunctional molecules with GC-PPC-SAFT: Limits of data and model. Fluid Phase Equilibria 2012, 329, 78. <http://dx.doi.org/10.1016/j.fluid.2012.06.004>
  • Pavlíček Jan, Wichterle Ivan: Isothermal (vapour+liquid) equilibria in the binary and ternary systems composed of 2-propanol, 2,2,4-trimethylpentane, and 2,4-dimethyl-3-pentanone. J Chem Thermo 2012, 45, 83. <http://dx.doi.org/10.1016/j.jct.2011.09.007>
  • Lin Dun-Yi, Tu Chein-Hsiun: (Vapour+liquid) equilibria for binary and ternary mixtures of 2-propanol, tetrahydropyran, and 2,2,4-trimethylpentane at P=101.3kPa. K J CHEM THERMODYN 2012, 47, 260. <http://dx.doi.org/10.1016/j.jct.2011.10.025>
  • Luis Patricia, Wouters Christine, Sweygers Nick, Creemers Claude, Van der Bruggen Bart: The potential of head-space gas chromatography for VLE measurements. K J CHEM THERMODYN 2012, 49, 128. <http://dx.doi.org/10.1016/j.jct.2012.01.020>
  • Narasigadu C., Subramoney S. C., Naidoo P., Coquelet C., Richon D., Ramjugernath D.: Isothermal Vapor–Liquid Equilibrium Data for the Propan-1-ol + Dodecane System at (323.0, 343.4, 353.2, 363.1, and 369.2) K. J Chemical & Engineering Data 2012, 57, 862. <http://dx.doi.org/10.1021/je201032t>
  • Bernatová Svatoslava, Pavlíček Jan, Wichterle Ivan: Isothermal vapour–liquid equilibria in the binary and ternary systems composed of 2,2,4-trimethylpentane, 2-methyl-1-propanol, and 4-methyl-2-pentanone. Fluid Phase Equilb 2011, 307, 66. <http://dx.doi.org/10.1016/j.fluid.2011.05.011>
  • Liu Jinzhao, Wang Shujuan, Hartono Ardi, Svendsen Hallvard F., Kim Inna, Chen Changhe: Vapor–liquid equilibria of NH3 in (NH3+H2O) and (NH3+PZ+H2O) system. Fluid Phase Equilb 2011, 311, 30. <http://dx.doi.org/10.1016/j.fluid.2011.08.017>
  • Baburao Barath, Visco Donald P.: Methodology for the Development of Thermodynamic Models Describing Substances That Exhibit Complex Association Interactions. J Chem Eng Data 2011, 56, 1506. <http://dx.doi.org/10.1021/je1011955>
  • Faneite Alexis M., Soto Diana, Álvarez Cesar A., Urdaneta Mario R., Garcés Siby I.: Isothermal Vapor–Liquid Equilibrium Data of Propan-1-ol + 2,2,4-Trimethylpentane and Butan-1-ol + 2,2,4-Trimethylpentane at 318.15 K. J Chemical & Engineering Data 2011, 56, 3346. <http://dx.doi.org/10.1021/je200279q>
  • Teodorescu Mariana, Barhala Alexandru, Dragoescu Dana, Gheorghe Daniela: Isothermal Vapor–Liquid Equilibria for Nitromethane and Nitroethane + 1,3-Dichloropropane Binary Systems at Temperatures between (343.15 and 363.15) K. J. Chem. Eng. Data 2011, 56, 4665. <http://dx.doi.org/10.1021/je200651r>
  • Bernatová Svatoslava, Pavlíček Jan, Wichterle Ivan: Isothermal Vapor−Liquid Equilibria in the Two Binary and the Ternary Systems Composed of tert-Amyl Methyl Ether, tert-Butanol, and Isooctane. J Chem Eng Data 2011, 56, 783. <http://dx.doi.org/10.1021/je901026b>
  • Hülsmann Marco, Vrabec Jadran, Maaß Astrid, Reith Dirk: Assessment of numerical optimization algorithms for the development of molecular models. Comp Phys Com 2010, 181, 887. <http://dx.doi.org/10.1016/j.cpc.2010.01.001>
  • Teodorescu Mariana, Barhala Alexandru, Dragoescu Dana: Isothermal vapour–liquid equilibria for 1,2-dichloroethane+nitromethane and + nitroethane binary systems at temperatures between 333.15 and 353.15K. Fluid Phase Equilb 2010, 292, 58. <http://dx.doi.org/10.1016/j.fluid.2010.01.024>
  • Bernatová Svatoslava, Pavlíček Jan, Wichterle Ivan: Isothermal vapour–liquid equilibria in the binary and ternary systems composed of tert-butyl methyl ether, 3,3-dimethyl-2-butanone and 2,2-dimethyl-1-propanol. Fluid Phase Equilb 2009, 278, 129. <http://dx.doi.org/10.1016/j.fluid.2009.01.016>
  • Joseph M.A., Ramjugernath D., Raal J.D.: Computer-aided Measurement of Vapour-Liquid Equilibria in a Dynamic Still at Sub-Atmospheric Pressures. Dev Chem Eng Mineral Process 2008, 10, 615. <http://dx.doi.org/10.1002/apj.5500100612>
  • Psutka Štěpán, Wichterle Ivan: Isothermal vapour–liquid equilibria in the binary and ternary systems composed of 2-propanol, 3-methyl-2-butanone and 2,2,4-trimethylpentane. Fluid Phase Equilb 2008, 264, 55. <http://dx.doi.org/10.1016/j.fluid.2007.10.016>
  • Ramsauer B., Neueder R., Kunz W.: Isobaric vapour–liquid equilibria of binary 1-propoxy-2-propanol mixtures with water and alcohols at reduced pressure. Fluid Phase Equilb 2008, 272, 84. <http://dx.doi.org/10.1016/j.fluid.2008.06.022>
  • Wen Chao-Cheng, Tu Chein-Hsiun: Vapor–liquid equilibria for binary and ternary mixtures of ethanol, 2-butanone, and 2,2,4-trimethylpentane at 101.3kPa. Fluid Phase Equilb 2007, 258, 131. <http://dx.doi.org/10.1016/j.fluid.2007.06.005>
  • Ku Hsu-Chen, Tu Chein-Hsiun: Vapor–liquid equilibria for binary and ternary mixtures of diisopropyl ether, ethanol, and 2,2,4-trimethylpentane at 101.3kPa. Fluid Phase Equilb 2006, 248, 197. <http://dx.doi.org/10.1016/j.fluid.2006.08.004>
  • Al-Hayan Mohammad N. M., Al-Kandary Jasem A. M.: Isobaric Vapor−Liquid Equilibria for Binary Mixtures of 1,2-Dibromoethane with Benzene, Toluene, Fluorobenzene, and Bromobenzene at Atmospheric Pressure. J Chemical & Engineering Data 2006, 51, 366. <http://dx.doi.org/10.1021/je050231r>
  • Grenner Andreas, Klauck Mandy, Kramer Madeleine, Schmelzer Jürgen: Activity Coefficients at Infinite Dilution of Cylcohexylamine + Octane, Toluene, Ethylbenzene, or Aniline and Excess Molar Volumes in Binary Mixtures of Cyclohexylamine + Heptane, Octane, Nonane, Decane, Undecane, Aniline, or Water. J Chemical & Engineering Data 2006, 51, 176. <http://dx.doi.org/10.1021/je050316s>
  • Soni Minal, Ramjugernath Deresh, Raal J. David: Vapor−Liquid Equilibrium for Binary Systems of Diacetyl with Methanol and Acetone. J Chemical & Engineering Data 2006, 51, 2083. <http://dx.doi.org/10.1021/je060174h>
  • Ku Hsu-Chen, Tu Chein-Hsiun: Isobaric vapor–liquid equilibria for mixtures of acetone, ethanol, and 2,2,4-trimethylpentane at 101.3kPa. Fluid Phase Equilb 2005, 231, 99. <http://dx.doi.org/10.1016/j.fluid.2005.01.007>
  • Grenner Andreas, Klauck Mandy, Schmelzer Jürgen: An equipment for dynamic measurements of vapour–liquid equilibria and results in binary systems containing cyclohexylamine. Fluid Phase Equilb 2005, 233, 170. <http://dx.doi.org/10.1016/j.fluid.2005.05.003>
  • Psutka Stepan, Wichterle Ivan: Vapor−Liquid Equilibria in the Binary and Ternary Systems Composed of 2-Methylpentane, 3-Methyl-2-butanone and 3-Methyl-2-butanol. J Chemical & Engineering Data 2005, 50, 1338. <http://dx.doi.org/10.1021/je050062a>
  • Psutka Štěpán, Wichterle Ivan: Isothermal vapour–liquid equilibria in the binary and ternary systems composed of 2-propanol, diisopropyl ether and 1-methoxy-2-propanol. Fluid Phase Equilb 2004, 220, 161. <http://dx.doi.org/10.1016/j.fluid.2004.03.012>
  • Smith Christina M., Visco Donald P.: Evaluating the Thermodynamic Consistency of Experimental Data for HF + H2O at 101.325 kPa. J Chemical & Engineering Data 2004, 49, 306. <http://dx.doi.org/10.1021/je034154g>
  • Chamorro, César R., Segovia, José J., Martı́n Marı́a C., Villamañán Miguel A.: Isothermal v.l.e. and excess molar Gibbs energy of binary and ternary mixtures containing diisopropyl ether,n -heptane and isopropanol at T= 313.15 K. K J CHEM THERMODYN 2002, 34, 13. <http://dx.doi.org/10.1006/jcht.2001.0840>
  • Sewnarain Reshan, Ramjugernath Deresh, Raal J. David: Isobaric Vapor−Liquid Equilibria for the Systems Propionic Acid + Butyric Acid, Isobutyric Acid + Butyric Acid, Butyric Acid + Isovaleric Acid, and Butyric Acid + Hexanoic Acid at 14 kPa. J Chemical & Engineering Data 2002, 47, 603. <http://dx.doi.org/10.1021/je0102412>
  • Du Tz-Bang, Tang Muoi, Chen Yan-Ping: Vapor–liquid equilibria of the binary mixtures of tetrahydrofuran with 2,2,4-trimethylpentane, methylcyclohexane and n-heptane at 101.3 kPa. Fluid Phase Equilb 2001, 192, 71. <http://dx.doi.org/10.1016/S0378-3812(01)00634-3>
  • Al-Hayan M.N.M, Newsham D.M.T: Isobaric vapour–liquid equilibria for mixtures containing halogenated hydrocarbons at atmospheric pressure: Part II. Binary mixtures of fluorobenzene, chlorobenzene and bromobenzene. Fluid Phase Equilb 2000, 168, 259. <http://dx.doi.org/10.1016/S0378-3812(99)00338-6>
  • Eubank Philip T., Lamonte Brad G., Javier Alvarado J. F.: Consistency Tests for Binary VLE Data. J Chemical & Engineering Data 2000, 45, 1040. <http://dx.doi.org/10.1021/je9902692>
  • Wen Tsung-Yao, Tang Muoi, Chen Yan-Ping: Vapor–liquid equilibria of the binary mixtures 2-butanone+t-pentanol, t-pentanol+butyl acetate and 2-propanol+diethyl ketone at 101.3 kPa. Fluid Phase Equilb 1999, 163, 99. <http://dx.doi.org/10.1016/S0378-3812(99)00206-X>
  • Al-Hayan M.N.M, Newsham D.M.T: Isobaric vapour–liquid equilibria for mixtures containing halogenated hydrocarbons at atmospheric pressure. Fluid Phase Equilb 1999, 166, 91. <http://dx.doi.org/10.1016/S0378-3812(99)00297-6>