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Pure Appl. Chem., 1995, Vol. 67, No. 2, pp. 281-288

Activation of carbon-hydrogen bonds in alkanes and other organic molecules by Ir(I), Rh(I) and Ir(III) complexes

A. A. Bengali, B. A. Arndtsen, P. M. Burger, R. H. Schultz, B. H. Weiller, K. R. Kyle, C. B. Moore and R. G. Bergman

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  • Durak Landon J., Lewis Jared C.: Transmetalation of Alkyl Ligands from Cp*(PMe3)IrR1R2 to (cod)PtR3X. Organometallics 2013, 32, 3153. <>
  • Gómez-Gallego Mar, Sierra Miguel A.: Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms. Chemistry Review 2011, 111, 4857. <>
  • Liu Bo, Chia Zhi-Wen, Cheng Chin-Hsien, Lee Jim-Yang: Promotional Effects of Ir Addition in Carbon-Supported Pt5Rh Electrocatalysts for the Electrooxidation of Ethanol at Room Temperature. Energy Fuels 2011, 25, 3135. <>
  • Geng Dongsheng, Matsuki Daisuke, Wang Jiajia, Kawaguchi Tomoyuki, Sugimoto Wataru, Takasu Yoshio: Activity and Durability of Ternary PtRuIr∕C for Methanol Electro-oxidation. J Electrochem Soc 2009, 156, B397. <>
  • Eguiluz K.I.B., Salazar-Banda G.R., Miwa D., Machado S.A.S., Avaca L.A.: Effect of the catalyst composition in the Ptx(Ru–Ir)1−x/C system on the electro-oxidation of methanol in acid media. J Power Sources - 2008, 179, 42. <>
  • Gunnoe T. Brent: Reactivity of Ruthenium(II) and Copper(I) Complexes that Possess Anionic Heteroatomic Ligands: Synthetic Exploitation of Nucleophilicity and Basicity of Amido, Hydroxo, Alkoxo, and Aryloxo Ligands for the Activation of Substrates that Possess Polar Bonds as well as Nonpolar C–H and H–H Bonds. Eur J Inorg Chem 2007, 2007, 1185. <>
  • Parkin Gerard: Applications of deuterium isotope effects for probing aspects of reactions involving oxidative addition and reductive elimination of H–H and C–H bonds. J Labelled Cpd Radiopharm 2007, 50, 1088. <>
  • Clot E., Eisenstein O., Jones W. D.: Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation between theory and experiment. Proceedings of the National Academy of Sciences 2007, 104, 6939. <>
  • Cobar E. A., Khaliullin R. Z., Bergman R. G., Head-Gordon M.: Theoretical study of the rhenium alkane interaction in transition metal alkane  -complexes. Proceedings of the National Academy of Sciences 2007, 104, 6963. <>
  • Corkey Britton K., Taw Felicia L., Bergman Robert G., Brookhart Maurice: Aromatic and aldehyde carbon–hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C–H oxidative addition. J Polyhedron 2004, 23, 2943. <>
  • Stahl Shannon S., Labinger Jay A., Bercaw John E.: Oxidation von Alkanen durch elektrophile späte Übergangsmetalle in homogener Lösung. Angew Chem 1998, 110, 2298. <<2298::AID-ANGE2298>3.0.CO;2-Y>
  • Holtcamp Matthew W., Henling Lawrence M., Day Michael W., Labinger Jay A., Bercaw John E.: Intramolecular and intermolecular C-H activation at a cationic PtII center. Inorg Chim Ada 1998, 270, 467. <>