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Pure Appl. Chem., 1991, Vol. 63, No. 5, pp. 665-680

http://dx.doi.org/10.1351/pac199163050665

Developing the reactivity of multiple bonds between metal atoms: inorganic functional groups

M. H. Chisholm

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  • Krackl Sebastian, Company Anna, Enthaler Stephan, Driess Matthias: Low-Valent Molybdenum-Based Dual Pre-Catalysts for Highly Efficient Catalytic Epoxidation of Alkenes and Deoxygenation of Sulfoxides. ChemCatChem 2011, 3, 1186. <http://dx.doi.org/10.1002/cctc.201100007>
  • Krackl Sebastian, Ma Jian-Gong, Aksu Yilmaz, Driess Matthias: Facile Access to Homo- and Heteroleptic, Triply Bonded Dimolybdenum Hexaalkoxides with Unsaturated Alkoxide Ligands. Eur J Inorg Chem 2011, 2011, 1725. <http://dx.doi.org/10.1002/ejic.201001236>
  • CHISHOLM M. H.: ChemInform Abstract: Developing the Reactivity of Multiple Bonds Between Metal Atoms: Inorganic Functional Groups. ChemInform 2010, 22, no. <http://dx.doi.org/10.1002/chin.199141288>
  • Giannini Luca, Solari Euro, Zanotti-Gerosa Antonio, Floriani Carlo, Chiesi-Villa Angiola, Rizzoli Corrado: Bildung von Metall-Metall-Mehrfachbindungen zwischen zwei Wolfram-Calix[4]aren-Einheiten durch reduktive Kupplung. Angew Chem 1997, 109, 763. <http://dx.doi.org/10.1002/ange.19971090714>
  • Finniss Gary M., Canadell Enric, Campana Charles, Dunbar Kim R.: Präzedenzlose Umwandlung einer Verbindung mit Metall-Metall-Bindung in einen solvatisierten molekularen Draht. Angew Chem 1996, 108, 2946. <http://dx.doi.org/10.1002/ange.19961082308>
  • Budzichowski T. A., Chisholm M. H., Folting K.: Substrate Uptake and Activation by Dimolybdenum and Ditungsten Hexaalkoxides–Factors Influencing the Cleavage of C–X Multiple Bonds in the Reactions Between [Mo2(OR)6] (R tBu or CH2tBu) and Ar2CS, Et2NCN, and P(nBu)3. Chem Eur J 1996, 2, 110. <http://dx.doi.org/10.1002/chem.19960020119>
  • Budzichowski Theodore A., Chisholm Malcolm H., Huffman John C., Eisenstein Odile: [K([18]Krone-6)]+ [Mo4(μ4-H)(OCH2tBu)12]−, der erste Alkoxidohydridomolybdäncluster: Hinweise auf einen μ4-Hydridoliganden. Angew Chem 1994, 106, 203. <http://dx.doi.org/10.1002/ange.19941060213>
  • Budzichowski Theodore A., Chisholm Malcolm H.: Coordination chemistry of complexes with metalmetal multiple bonds: Reversible coordination of cyanide ion by dimolybdenum and ditungsten hexaalkoxides. J Polyhedron 1994, 13, 2035. <http://dx.doi.org/10.1016/S0277-5387(00)83486-5>
  • Budzichowski Theodore A., Chisholm Malcolm H., Huffman John C., S. Kramer Keith, U. Fromhold Mark: Cationic d3-d3 dinuclear compounds of tungsten: [W2(O2CBut)5]+X−, where X−=BF4− and CF3SO3−. Inorg Chim Ada 1993, 213, 141. <http://dx.doi.org/10.1016/S0020-1693(00)83824-4>
  • Chisholm Malcolm H., Cook Cindy M., Folting Kirsten, Streib William E.: Oxygen atom transfer in the reaction between hexakis(dimethyl-tert-butylsiloxy)ditungsten and nitric oxide. A remarkable difference in the reactivity of the tungsten-tungsten triple bond as a function of the attendant ligands: ButO versus ButMe2SiO. Inorg Chim Ada 1992, 198-200, 63. <http://dx.doi.org/10.1016/S0020-1693(00)92347-8>
  • Fanwick Phillip E., Rothwell Ian P., Hill John E.: Synthesis and structure of 1,2-[Mo2R2(η2-ButNCR)4] (R  CH2SiMe3): insertion of ButNC into dimolybdenum alkyl bonds without rupture of the metal-metal triple bond. J Polyhedron 1992, 11, 2825. <http://dx.doi.org/10.1016/S0277-5387(00)83581-0>