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Pure Appl. Chem., 1990, Vol. 62, No. 4, pp. 691-698

http://dx.doi.org/10.1351/pac199062040691

Chromium carbene complexes in the synthesis of molecules of biological interest

L. S. Hegedus

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  • Ganesamoorthi R., Thakur Arunabha, Sharmila D., Ramkumar V., Ghosh Sundargopal: Synthesis and characterization of N-phenyl pyrrole anchored to Fischer carbene complex through ring closing metathesis oxidative aromatization and various aryl substituted Fischer carbene complexes. Journal of Organometallic Chemistry 2013, 726, 56. <http://dx.doi.org/10.1016/j.jorganchem.2012.12.014>
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  • Kunkely Horst, Vogler Arnd: Optical properties of transition metal complexes with N-heterocyclic carbenes as ligands. 1,3-di-t-Butylimidazol-2-ylidene as charge transfer donor and acceptor. J Organomet Chem 2003, 684, 113. <http://dx.doi.org/10.1016/S0022-328X(03)00518-7>
  • Beste Ariana, Krämer Oliver, Gerhard Anja, Frenking Gernot: The Lewis Basicity of Diaminocarbene – A Theoretical Study of Donor–Acceptor Complexes of C(NH2)2, NH3 and CO with the Lewis Acids EF3, ECl3 (E = B, Al, Ga, In), TiF4 and TiCl4. Eur J Inorg Chem 1999, 1999, 2037. <http://dx.doi.org/10.1002/(SICI)1099-0682(199911)1999:11<2037::AID-EJIC2037>3.0.CO;2-T>
  • Christoffers Jens: An Unusual Acyliminium Cyclization and Other Drawbacks during an Attempted Synthesis of a Chiral Primary α-Phosphinoalkanamine. HCA 1998, 81, 845. <http://dx.doi.org/10.1002/hlca.19980810506>
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  • Heinz Dötz Karl, Tomuschat Philipp, Nieger Martin: Reactions of Complex Ligands, LXXVII. Axial-Chiral Metal Carbenes: Synthesis and Structure of 1,1-Binaphthyl-Derived Carbonyl-Carbene Complexes of Chromium. Chem Ber 1997, 130, 1605. <http://dx.doi.org/10.1002/cber.19971301108>
  • Yu Zhengkun, Aumann Rudolf, Fröhlich Roland, Roths Klaus, Hecht Jürgen: Organic syntheses via transition metal complexes, LXXXVIII 1-metalla-1,3,5,7-octatetraenes from (1-alkynyl) carbene complexes of chromium and tungsten via [6-(1-alkenyl)] pyranylidene complexes. J Organomet Chem 1997, 541, 187. <http://dx.doi.org/10.1016/S0022-328X(97)00051-X>
  • Alvarez-Toledano Cecilio, Baldovino O., Espinoza G., Toscano R. Alfredo, Gutiérrez-Pérez René, García-Mellado Olivia: Reactivity of a two heteroatom stabilized anionic chromium (0) carbene complex towards a mono- and a disubstituted alkyne: New synthesis of γ-aminobutenolides and formation of a novel oligomer chromium (0) complex. J Organomet Chem 1997, 540, 41. <http://dx.doi.org/10.1016/S0022-328X(97)00091-0>
  • Dötz K.H., Ehlenz R., Straub W., Weber J.C., Airola K., Nieger M.: Organotransition metal modified sugars 4. Carbene complex functionalized acyclic carbohydrates. J Organomet Chem 1997, 548, 91. <http://dx.doi.org/10.1016/S0022-328X(97)00335-5>
  • Filippou Alexander C., Wössner Dirk, Lungwitz Bernhard, Kociok-Köhn Gabriele: Carbenkomplexe des zweiwertigen Chroms. Angew Chem 1996, 108, 981. <http://dx.doi.org/10.1002/ange.19961080827>
  • Dötz Karl Heinz, Straub Wolfgang, Ehlenz Richard, Peseke Elaus, Meisel Roland: Carbenkomplex-funktionalisierte Zucker. Angew Chem 1995, 107, 2023. <http://dx.doi.org/10.1002/ange.19951071721>
  • Christoffers Jens, Dötz Karl Heinz: Oxacycloalkenyliden-Komplexe von Chrom, Molybdän und Wolfram: Synthese, Anellierung mit Alkinen und Diels-Alder-Reaktionen mit Dienen. Chem Ber 1995, 128, 157. <http://dx.doi.org/10.1002/cber.19951280212>
  • Dötz Karl Heinz, Christoffers Carmen: Synthese von Carben-Carbonyl-Isonitril-Komplexen von Chrom und deren Anellierungsreaktion mit Alkinen. Chem Ber 1995, 128, 163. <http://dx.doi.org/10.1002/cber.19951280213>
  • Christoffers Jens, Dötz Karl Heinz: Reactions of Complex Ligands, LXIV. Synthesis of 5,5′-Diphenyl-2,2′-bifuran, a Biaryl Compound with Remarkable Fluorescence Properties. Chem Ber 1995, 128, 641. <http://dx.doi.org/10.1002/cber.19951280618>
  • Dötz Karl Heinz, Christoffers Carmen, Christoffers Jens, Böttcher Dirk, Nieger Martin, Kotila Sirpa: Reactions of Complex Ligands, LXV. Vinylidene and Methoxy(alkynyl)carbene Molybdenum Complexes: Competitive Formation During Fischer Carbene Complex Synthesis and Crystal Structure Determination. Chem Ber 1995, 128, 645. <http://dx.doi.org/10.1002/cber.19951280619>
  • Kretschik Oliver, Nieger Martin, Dötz Karl Heinz: Reactions of Complex Ligands, LXVI. Diastereomerically Pure 2-Ethynylcyclopropanecarboxylic Acid Derivatives and (2-Ethynylcyclopropyl)methoxycarbene Complexes of Chromium and Tungsten. Chem Ber 1995, 128, 987. <http://dx.doi.org/10.1002/cber.19951281005>
  • Heinz Dötz Karl, Christoffers Carmen, Knochel Paul: Reaktionen von komplexliganden. LXIII. Diethylzink-induzierte Dimerisierung von alkinylcarbenliganden: regioselektive synthese eines cyclopentenyliden-komplexes. J Organomet Chem 1995, 489, C84. <http://dx.doi.org/10.1016/0022-328X(94)05305-U>
  • Dötz K.H., Böttcher D., Jendro M.: Manganese and tungsten carbene complex mediated intramolecular Diels-Alder reactions. Inorg Chim Ada 1994, 222, 291. <http://dx.doi.org/10.1016/0020-1693(94)03920-8>
  • Danks Timothy N., Velo-Rego David: Reaction of a chromium carbene complex with 1-azadienes and the synthesis of trisubstituted pyrroles. Tetrahetron Lett 1994, 35, 9443. <http://dx.doi.org/10.1016/S0040-4039(00)78565-0>
  • Nakamura Takako, Matsuyama Haruo, Iyoda Masahiko: New Method for the Preparation of Alkoxycarbene Complexes of Chromium, Molybdenum, and Tungsten Using Sulfonium Salts. Chem Lett 1994, 1537. <http://dx.doi.org/10.1246/cl.1994.1537>
  • Füstner Alois: Chemie von und mit hochaktiven Metallen. Angew Chem 1993, 105, 171. <http://dx.doi.org/10.1002/ange.19931050205>
  • Aumann Rudolf: Organische Synthesen mit übergangsmetall-Komplexen, 66. 2-Aminopyrrole durch Metathese von (β-Aminovinyl)carben-Chrom- und -Wolfram-Komplexen mit Isocyaniden. Chem Ber 1993, 126, 2325. <http://dx.doi.org/10.1002/cber.19931261022>
  • Yeh Wen-Yann, Chen Shu-Ling, Peng Shie-Ming, Lee Gene-Hsiang: Synthesis, crystal structure and reactivity of OS3(CO)9(μ3-η2-C2Ph2)(μ-C(OMe)Ph). J Organomet Chem 1993, 461, 207. <http://dx.doi.org/10.1016/0022-328X(93)83294-6>
  • Dötz Karl Heinz, Kroll Friedrich, Harms Klaus: Reaktionen von Komplexliganden LVII. Amidinocarben-Chelatkomplexe des Chroms und Molybdäns: Synthese, Struktur und Cycloadditionen mit Alkinen. J Organomet Chem 1993, 459, 169. <http://dx.doi.org/10.1016/0022-328X(93)86069-T>
  • Dötz K.H., Tiriliomis A., Harms K.: Phosphahydroquinones and oxaphospholes via carbene annulation and cycloaddition reactions of chromium carbonyl carbene complexes and phosphaalkynes. Tetrahedron 1993, 49, 5577. <http://dx.doi.org/10.1016/S0040-4020(01)87270-7>
  • Dötz Karl Heinz, Schäfer Thomas, Kroll Friedrich, Harms Klaus: Alkin(carben)-Komplexe: Stabilisierung einer Zwischenstufe der Carbenanellierung. Angew Chem 1992, 104, 1257. <http://dx.doi.org/10.1002/ange.19921040932>
  • Dötz Karl Heinz, Schäfer Thomas, Kroll Friedrich, Harms Klaus: Alkyne(carbene) Complexes: Stabilization of an Intermediate of Carbene Annelation. Angew Chem Int Ed Engl 1992, 31, 1236. <http://dx.doi.org/10.1002/anie.199212361>
  • Dötz Karl Heinz, Larbig Harald, Harms Klaus: Reaktionen von Komplexliganden, LI. Synthese und Reaktionen stabiler (Carben)tetracarbonyl-Chelatkomplexe des Molybdäns. Chem Ber 1992, 125, 2143. <http://dx.doi.org/10.1002/cber.19921250924>
  • Dötz Karl Heinz, Christoffers Jens: Reaktionen von komplexliganden. J Organomet Chem 1992, 426, C58. <http://dx.doi.org/10.1016/0022-328X(92)83074-R>
  • Hegedus Louis S.: Transition metals in organic synthesis annual survey covering the year 1990. J Organomet Chem 1992, 422, 301. <http://dx.doi.org/10.1016/0022-328X(92)88031-D>
  • van der Steen Fred H., van Koten Gerard: Syntheses of 3-amino-2-azetidinones: A literature survey. Tetrahedron 1991, 47, 7503. <http://dx.doi.org/10.1016/S0040-4020(01)88276-4>