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Pure Appl. Chem., 1989, Vol. 61, No. 5, pp. 795-804

Structure and reactivity of rhodium(II) complexes

F. P. Pruchnik

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  • Jia Ai-Quan, Chiu Wai-Hang, Huang Xiang-Hong, Leung Wa-Hung, Zhang Qian-Feng: Isolation and structures of rhodium(III) complexes with cyclometalated bis(dialkylthiophosphoryl)imides via intramolecular C–H activation. Journal of Organometallic Chemistry 2014, 761, 98. <>
  • Mehrotra Ripul, Shukla Satyendra N., Gaur Pratiksha: Spectroscopic characterization of Schiff base coordinating monomolecular trinuclear complexes prepared through tailored synthesis. J Coord Chem 2012, 65, 176. <>
  • Ćwikowska Magdalena, Pruchnik Florian P., Starosta Radosław, Chojnacki Henryk, Wilczok Adam, Ułaszewski Stanisław: Dinuclear Rh(II) complexes with one polypyridyl ligand, structure, properties and antitumor activity. Inorg Chim Ada 2010, 363, 2401. <>
  • Ćwikowska Magdalena, Pruchnik Florian P., Pavlyuk Oleksiy, Lafolet Frédéric, Chardon-Noblat Sylvie, Deronzier Alain: Soluble {[Rh2(μ-OOCCH3)2(dbbpy)2][BF4]}n molecular wire and [Rh2(μ-OOCCH3)2(dbbpy)2L2]2+ complexes; dbbpy=4,4′-di-tert-butyl-2,2′-bipyridine: Synthesis and physicochemical characterization. J Polyhedron 2010, 29, 3059. <>
  • Rak Magdalena, Pruchnik Florian P., Ciunik Leszek Z., Lafolet Frédéric, Chardon-Noblat Sylvie, Deronzier Alain: Synthesis and Structural and Physicochemical Characterization of {[Rh2(μ-OOCCH3)2(dmbpy)2][BF4]}n Molecular Wire. Eur J Inorg Chem 2009, 2009, 111. <>
  • Bertin V., Lopez-Rendón R., del Angel G., Poulain E., Avilés R., Uc-Rosas V.: Comparative theoretical study of small Rhn nanoparticles (2 ≤ n ≤ 8) using DFT methods. Int J Quantum Chem 2009, NA. <>
  • Zuber M., Pruchnik F.P.: Hydridobipyridine rhodium complexes as a result of the C–H bond activation in coordinated ligand, NMR studies. J Polyhedron 2006, 25, 2773. <>
  • Stasicka Zofia, Ziółkowski Józef J.: Origin and development of coordination chemistry in Poland—Introductory remarks. Coord Chem Rev - 2005, 249, 2133. <>
  • Wajda-Hermanowicz Katarzyna, Pruchnik Florian P., Zuber Marek, Ciunik Zbigniew: Studies of the interaction between adenosine 5′-triphosphate and [Rh2(OAc)2(phen)2(H2O)2](OAc)2. J Polyhedron 2005, 24, 1577. <>
  • Frelek Jadwiga, Jaźwiński Jarosław, Masnyk Marek, Ruśkowska Patrycja, Szmigielski Rafał: Dirhodium tetraacetate as an auxiliary chromophore in a circular dichroic study on vic-amino alcohols. Tet Asymm 2005, 16, 2437. <>
  • Frelek Jadwiga, Górecki Marcin, Jaźwiński Jarosław, Masnyk Marek, Ruśkowska Patrycja, Szmigielski Rafał: Configurational assignment of vic-amino alcohols from their circular dichroism spectra with dirhodium tetracetate as an auxiliary chromophore. Tet Asymm 2005, 16, 3188. <>
  • Pruchnik Florian P., Jutarska Anna, Ciunik Zbigniew, Pruchnik Mirosław: Structure of binuclear Rh(II) carboxylato complexes with 2,2′-bipyridine and an unprecedented rhodium wire with Rh45+ core. Inorg Chim Ada 2004, 357, 3019. <>
  • Moszner Monika, Kubiak Maria, Ziółkowski Józef J.: New rhodium complexes of the tetradentate ligand bis(diacetylmonoxime-imino)propane 1,3 (H2dopn): synthesis and crystal structure of trans-[Rh(Hdopn)Cl]2 and trans-[Rh(Hdopn)(I)2]. Inorg Chim Ada 2004, 357, 115. <>
  • Pruchnik Florian P, Jutarska Anna, Ciunik Zbigniew, Pruchnik Mirosław: Synthesis and structural characterization of new rhodium formato complexes containing [Rh2]4+ and [Rh4]6+ cores. Inorg Chim Ada 2003, 350, 609. <>
  • Pruchnik Florian P., Jakimowicz Piotr, Ciunik Zbigniew, Stanislawek Kamil, Oro Luis A., Tejel Cristina, Ciriano Miguel A.: Rhodium wires based on binuclear acetate-bridged complexes. J Inorg Chem Commun 2001, 4, 19. <>
  • Pruchnik Florian P., Jakimowicz Piotr, Ciunik Zbigniew: Synthesis and structural characterization of new one-dimensional rhodium complexes. J Inorg Chem Commun 2001, 4, 726. <>
  • Tejel Cristina, Sommovigo Milena, Ciriano Miguel A., López José A., Lahoz Fernando J., Oro Luis A.: Rhodium–Rhodium Bonds in Edge-Sharing Coplanar Dinuclear Complexes. Angew Chem 2000, 112, 2426. <<2426::AID-ANGE2426>3.0.CO;2-9>
  • Exarchos George, Robinson Stephen D: Observations concerning the constitution of some ‘rhodium(II) dithiocarbamato complexes’. J Polyhedron 2000, 19, 123. <>
  • Bień Malgorzata, P. Pruchnik Florian, Seniuk Alicja, M. Lachowicz Tadeusz, Jakimowicz Piotr: Studies of antibacterial activity of binuclear rhodium(II) complexes with heterocyclic nitrogen ligands. J  Inorg Biochem 1999, 73, 49. <>
  • Pruchnik Florian P, Radosław, Starosta, Lis Tadeusz, Lahuerta Pascual: Orthometallation reactions of tris(p-methoxyphenyl)phosphine with dirhodium(II) tetraacetate. J Organomet Chem 1998, 568, 177. <>
  • Moszner Monika, Trzeciak Anna M, Ziółkowski Józef J: Rhodium complexes with dioximes as catalysts of hydroformylation and hydrogenation of 1-hexene. Journal of Molecular Catalysis A 1998, 130, 241. <>
  • Pruchnik F.P., Kluczewska G., Wilczok A., Mazurek U., Wilczok T.: Rhodium(II) complexes with phenanthrolines and their metabolic action on synchronized cell culture. J  Inorg Biochem 1997, 65, 25. <>
  • Trynda-Lemiesz Lilianna, Pruchnik Florian P.: Studies on the interaction between human serum albumin and [Rh2(OAc)2(bpy)2(H2O)2](OAc)2. J  Inorg Biochem 1997, 66, 187. <>
  • Pruchnik Florian, Duś Danuta: Properties of rhodium (II) complexes having cytostatic activity. J  Inorg Biochem 1996, 61, 55. <>
  • King R. Bruce, King Allen D., Bhattacharyya Nripendra K.: Catalytic reactions of formate. 3. Noble metal chlorides as catalyst precursors for formic acid reactions. Trans Met Chem 1995, 20, 321. <>
  • Nifantyev E. E., Teleshev A. T., Popov L. F., Polyakov V. A.: 4-ETHYL-2,6,7-TRIOXA-1-PHOSPHABICYCLO[2.2.2]OCTANE IN COMPLEXING WITH DIRHODIUM(II) TETRAACETATE. Phosphorus Sulfur Silicon Relat Elem 1995, 103, 253. <>
  • Markó László: Transition metals in organic synthesis: hydroformylation, reduction, and oxidation. J Organomet Chem 1991, 404, 325. <>
  • Pruchnik F., Jezierski A., Kalecińska E.: Electron paramagnetic resonance study on radiation reduction of dirhodium(II) [Rh2(O2CR)4] and [Rh2Cl2(O2CR)2(NN)2] complexes. J Polyhedron 1991, 10, 2551. <>
  • Szymaszek A., Pruchnik F.P.: Electrochemical oxidation of tetra-(S)-mandelatodirhodium(II) and tetraformatodirhodium(II). J Polyhedron 1990, 9, 1135. <>