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Pure Appl. Chem., 1989, Vol. 61, No. 4, pp. 685-692

http://dx.doi.org/10.1351/pac198961040685

Generation of elusive neutrals and dications by neutralization resp. Charge stripping of monocations in beam experiments

H. Schwarz

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  • Schröder Detlef, Schwarz Helmut, Roithová Jana: Neutralization–reionization study of the allyloxide anion. Int J Mass Spectrosc 2011, 301, 84. <http://dx.doi.org/10.1016/j.ijms.2010.07.007>
  • McLafferty Fred W.: A Century of Progress in Molecular Mass Spectrometry. Annu Rev Anal Chem 2011, 4, 1. <http://dx.doi.org/10.1146/annurev-anchem-061010-114018>
  • Stach Joachim, Möder Monika, Herzschuh Rainer: Tandem-Massenspektrometrie - Grundlagen und Applikationen. Z Chem 2010, 30, 157. <http://dx.doi.org/10.1002/zfch.19900300502>
  • Price Stephen D.: Coincidence studies of the bond-forming reactivity and reaction dynamics of molecular dications. Int J Mass Spectrosc 2007, 260, 1. <http://dx.doi.org/10.1016/j.ijms.2006.06.018>
  • Zagorevskii Dmitri: The generation and characterization of elusive metal complexes in the gas phase: neutralization–reionization mass spectrometry and related experiments. Coord Chem Rev - 2002, 225, 5. <http://dx.doi.org/10.1016/S0010-8545(01)00404-0>
  • Vivekananda S., Raghunath P., Bhanuprakash K., Srinivas R.: Characterization of ammonia phosphorus oxide H3NPO+ ions and their neutral counterparts by mass spectrometry and computational chemistry. Int J Mass Spectrosc 2001, 208, 59. <http://dx.doi.org/10.1016/S1387-3806(01)00382-7>
  • Zagorevskii Dmitri V., Holmes John L.: Neutralization-reionization mass spectrometry applied to organometallic and coordination chemistry (update: 1994-1998). Mass Spectrom Rev 1999, 18, 87. <http://dx.doi.org/10.1002/(SICI)1098-2787(1999)18:2<87::AID-MAS1>3.0.CO;2-J>
  • O’Hair Richard A.J., Blanksby Stephen, Styles Michelle, Bowie John H.: Characterization of [M–H] cations, radicals and anions of glycine in the gas phase: a combined experimental and ab initio study. Int J Mass Spectrosc 1999, 182-183, 203. <http://dx.doi.org/10.1016/S1387-3806(98)14249-5>
  • Keck Helmut, Kuchen Wilhelm, Terlouw Johan K., Tommes Peter: DOES PHENYLPHOSPHINIDENE EXIST? - MASS SPECTROMETRIC GENERATION AND CHARACTERIZATION OF Ph-P. Phosphorus Sulfur Silicon Relat Elem 1999, 149, 23. <http://dx.doi.org/10.1080/10426509908037019>
  • Hornung Georg, Schalley Christoph A., Dieterle Martin, Schröder Detlef, Schwarz Helmut: A Study of the Gas-Phase Reactivity of Neutral Alkoxy Radicals by Mass Spectrometry: α-Cleavages and Barton-type Hydrogen Migrations. Chem Eur J 1997, 3, 1866. <http://dx.doi.org/10.1002/chem.19970031120>
  • Wright James S., Carpenter David J., Alekseyev Aleksey B., Liebermann Heinz-Peter, Lingott Rainer, Buenker Robert J.: Thermodynamically stable diatomic dications: potential curves and radiative lifetimes for CaCl2+ including relativistic effects. chem phys letts 1997, 266, 391. <http://dx.doi.org/10.1016/S0009-2614(97)00007-9>
  • Stegmann Ralf, Frenking Gernot: Silaacetylene: A possible target for experimental studies. J Comput Chem 1996, 17, 781. <http://dx.doi.org/10.1002/(SICI)1096-987X(199605)17:7<781::AID-JCC3>3.0.CO;2-O>
  • Vékey Károly: Multiply charged ions. Mass Spectrom Rev 1995, 14, 195. <http://dx.doi.org/10.1002/mas.1280140304>
  • Thomas J. Russell, DeLeeuw Bradley J., O’Leary Paul, Schaefer Henry F., Duke Brian J., O’Leary Brian: The ethylenedione anion: Elucidation of the intricate potential energy hypersurface. J Chem Phys 1995, 102, 6525. <http://dx.doi.org/10.1063/1.469366>
  • Schröder Detlef, Hrušák Jan, Tornieporth-Oetting Inis C., Klapötke Thomas M., Schwarz Helmut: Definitiver Beweis für die Existenz von AuF. Angew Chem 1994, 106, 223. <http://dx.doi.org/10.1002/ange.19941060223>
  • Iraqi Muhammad, Goldberg Norman, Schwarz Helmut: Characterization of Neutral and Ionic Sulfur—Nitrogen Cluster Molecules NS2 and NS3 in the Gas Phase. Chem Ber 1994, 127, 1171. <http://dx.doi.org/10.1002/cber.19941270632>
  • Zagorevskii Dmitri V., Holmes John L.: Neutralization-reionization mass spectrometry applied to organometallic and coordination chemistry. Mass Spectrom Rev 1994, 13, 133. <http://dx.doi.org/10.1002/mas.1280130203>
  • Bowen Richard D., Suh Dennis, Terlouw Johan K.: Reactions of ionized dibutyl ether. Org Mass Spectrom 1994, 29, 791. <http://dx.doi.org/10.1002/oms.1210291211>
  • Iraqi Muhammad, Schwarz Helmut: Experimental evidence for the gas phase existence of HSOH (hydrogen thioperoxide) and SOH2 (thiooxonium ylide). chem phys letts 1994, 221, 359. <http://dx.doi.org/10.1016/0009-2614(94)00293-2>
  • McGibbon Graham A., Kingsmill Carol A., Terlouw Johan K.: Experimental evidence for gaseous diaminocarbene H2NCNH2 and its radical cation. chem phys letts 1994, 222, 129. <http://dx.doi.org/10.1016/0009-2614(94)00335-1>
  • Burgers Peter C., McGibbon Graham A., Terlouw Johan K.: Dihydroxycarbene HO-C̈-OH: Its formation in the gas-phase by electron transfer to its radical cation. chem phys letts 1994, 224, 539. <http://dx.doi.org/10.1016/0009-2614(94)00569-9>
  • Goldberg Norman, Iraqi Muhammad, Koch Wolfram, Schwarz Helmut: Gas-phase characterization of the neutral and cationic Si2O2 molecules. A combined experimental and ab initio study. chem phys letts 1994, 225, 404. <http://dx.doi.org/10.1016/0009-2614(94)87102-7>
  • Goldberg Norman, Iraqi Muhammad, Schwarz Helmut, Boldyrev Alexander, Simons Jack: A combined experimental and theoretical study of the neutral, cationic, and anionic Si3N cluster molecule. J Chem Phys 1994, 101, 2871. <http://dx.doi.org/10.1063/1.467601>
  • Schröder Detlef, Hrusak Jan, Schwarz Helmut: Ligand Effects on the Reactivity of Iron (II) Cations FeX+ in the Gas Phase. Berichte der Bunsengesellschaft für physikalische Chemie 1993, 97, 1085. <http://dx.doi.org/10.1002/bbpc.19930970904>
  • Goldberg Norman, Iraqi Muhammad, Schwarz Helmut: Gas-Phase Generation and Characterization of Hydrogen CyanideN-Methylide. Chem Ber 1993, 126, 2353. <http://dx.doi.org/10.1002/cber.19931261025>
  • Goldberg Norman, Holthausen Max C., Hrušák Jan, Koch Wolfram, Schwarz Helmut: Mass-Spectrometric and GAUSSIAN2 Studies of the Diazene (HNNH) and Isodiazene (H2NN) Molecules and Their Radical Cations. Chem Ber 1993, 126, 2753. <http://dx.doi.org/10.1002/cber.19931261227>
  • Chorush Russell A., Vidavsky Ilan, McLafferty Fred W.: Surface-induced ion neutralization with high energy deposition. Org Mass Spectrom 1993, 28, 1016. <http://dx.doi.org/10.1002/oms.1210281008>
  • Goldberg Norman, Sülzle Detlev, Schwarz Helmut: The gas-phase generation and characterization of butatrienylidene H2CCCC: by neutralization—reionization mass spectrometry. chem phys letts 1993, 213, 593. <http://dx.doi.org/10.1016/0009-2614(93)89166-F>
  • Iraqi Muhammad, Schwarz Helmut: Gas-phase generation and characterization of linear silicon carbon hydrides SiCxH. (x = 4, 6) by neutralization-reionization mass spectrometry. chem phys letts 1993, 205, 183. <http://dx.doi.org/10.1016/0009-2614(93)89226-8>
  • Keck Helmut, Kuchen Wilhelm, Tommes Peter: The radical anions of thioxophosphane H-P���S and its tautomer thiohydroxyphosphinidene H-S-P ��� an ab initio study. Journal of Molecular Structure: THEOCHEM 1993, 283, 163. <http://dx.doi.org/10.1016/0166-1280(93)87125-W>
  • Keck Helmut, Kuchen Wilhelm, Tommes Peter, Terlouw Johan K., Wong Thomas: Das Phosphor-Ylid CH2PH3 ist stabil in der Gasphase. Angew Chem 1992, 104, 65. <http://dx.doi.org/10.1002/ange.19921040116>
  • Weiske Thomas, Schwarz Helmut, Terlouw Johan K., Wong Thomas, Krätschmer Wolfgang: Beweis der Existenz einer endohedralen He@C60-Struktur durch Gasphasenneutralisation von HeC.+60. Angew Chem 1992, 104, 242. <http://dx.doi.org/10.1002/ange.19921040241>
  • Muedas César A., Sülzle Detlev, Schwarz Helmut: Mass-spectrometric characterization of isomeric NNCCN and NCNCN Ions and neutrals. Chem Ber 1992, 125, 1517. <http://dx.doi.org/10.1002/cber.19921250631>
  • Keck Helmut, Kuchen Wilhelm, Tommes Peter, Wong Thomas, Terlouw Johan K.: Triphosphorus disulfide: The elusive P3S2˙ radical generated and identified by neutralization/reionization mass spectrometry. Rapid Commun Mass Spectrom 1992, 6, 203. <http://dx.doi.org/10.1002/rcm.1290060310>
  • Keck Helmut, Kuchen Wilhelm, Renneberg Heike, Terlouw Johan K., Visser Herman C.: RS - P  S in der Gasphase - erstmalige Erzeugung von (Organothio)thioxophosphanen. Angew Chem 1991, 103, 331. <http://dx.doi.org/10.1002/ange.19911030323>
  • Winkel Yvar Van Den, Van Baar Ben L. M., Bickelhaupt Friedrich, Kulik Willem, Sierakowski Claudia, Maier Günther: Neutralization-Reionization Mass Spectrometry and Matrix Isolation of Some 9-Silaanthracenes. Chem Ber 1991, 124, 185. <http://dx.doi.org/10.1002/cber.19911240127>
  • Sülzle Detlev, Seemayer Katrin, Schwarz Helmut, Witulski Bernhard, Hopf Henning: On the Generation of Polycarbon Nitride Radicals CnN. (n = 2–5) by Neutralization-Reionization Mass Spectrometry. Chem Ber 1991, 124, 1481. <http://dx.doi.org/10.1002/cber.19911240625>
  • Schwarz Helmut: Chemie „nackter” Moleküle. Oder das Massenspektrometer als Laboratorium. Chem Unserer Zeit 1991, 25, 268. <http://dx.doi.org/10.1002/ciuz.19910250507>
  • Drinkwater Donald E., Fura Aberra, Zhang Mei-Yi, McLafferty Fred W.: Improved metal vapor neutralization and resolution in neutralization-reionization mass spectrometry. Org Mass Spectrom 1991, 26, 1032. <http://dx.doi.org/10.1002/oms.1210261124>
  • Srinivas Ragampeta, Sülzle Detlev, Schwarz Helmut: Mass spectrometric identification of PS3−, PS3+ and PS˙3. Rapid Commun Mass Spectrom 1991, 5, 70. <http://dx.doi.org/10.1002/rcm.1290050205>
  • Keck Helmut, Kuchen Wilhelm, Tommes Peter, Terlouw Johan K., Wong Thomas: GASEOUS DIPHOSPHORUS AND TRIPHOSPHORUS SULFIDE: GENERATION AND IDENTIFICATION BY NEUTRALIZATION-REIONIZATION MASS SPECTROMETRY. Phosphorus Sulfur Silicon Relat Elem 1991, 63, 307. <http://dx.doi.org/10.1080/10426509108036834>
  • Terlouw Johan K., Sülzle Detlev, Schwarz Helmut: Unterscheidung isomerer Ionen durch Neutralisations-Reionisations-Massenspektrometrie (NRMS): Kohlensäure-Radikalkationen (HO)2CO˙⊕ versus (H2O/CO2)˙⊕-Cluster. Angew Chem 1990, 102, 431. <http://dx.doi.org/10.1002/ange.19901020425>
  • Sülzle Detlev, Schwarz Helmut: Nachweis von 1,2,3-Butatrien-1,4-dion, seinem Radikalanion und seinem Radikalkation in der Gasphase. Angew Chem 1990, 102, 923. <http://dx.doi.org/10.1002/ange.19901020816>
  • Sülzle Detlev, Beye Norbert, Fanghänel Egon, Schwarz Helmut: The laboratory generation of potentially interstellar cumulenes S(Cn)S (n = 2–6) and their radical cations. Chem Ber 1990, 123, 2069. <http://dx.doi.org/10.1002/cber.19901231020>
  • Drewello Thomas, Schwarz Helmut: Generation and characterization of stable monomeric transition-metal acetylides MCCH (M  Fe, Co, Ni) by neutralization—reionization mass spectrometry. chem phys letts 1990, 171, 5. <http://dx.doi.org/10.1016/0009-2614(90)80040-K>
  • Srinivas Ragampeta, Sülzle Detlev, Schwarz Helmut: Gas-phase generation and structural characterization of SiC2H and SiC2H+ by neutralization—reionization mass spectrometry: evidence for the existence of silicon acetylide (HCCSi) and its cation HCCSi+. chem phys letts 1990, 175, 575. <http://dx.doi.org/10.1016/0009-2614(90)85583-X>
  • Drewello Thomas, Lebrilla Carlito B., Asmus Klaus-Dieter, Schwarz Helmut: Dithia-Dikationen aus cyclischen und acyclischen Vorläufern durch Gasphasenoxidation („charge stripping”) von 3e/2c-Radikalkationen. Angew Chem 1989, 101, 1247. <http://dx.doi.org/10.1002/ange.19891010911>
  • Sülzle Detlev, Schwarz Helmut: CCS and S(C4)S: The laboratory generation of interstellar molecules and their radical cations. Chem Ber 1989, 122, 1803. <http://dx.doi.org/10.1002/cber.19891220930>
  • Sülzle Detlev, Beye Norbert, Fanghänel Egon, Schwarz Helmut: Generation of C6S6 and its radical anion and cation in the gas phase. Chem Ber 1989, 122, 2411. <http://dx.doi.org/10.1002/cber.19891221233>
  • Karrass Sigurd, Schwarz Helmut: Site-Specific, Oxidative Addition of CC Bonds by ‘Anchored’ bare Fe(I) cations prior to CH bond activation. Preliminary communication. HCA 1989, 72, 633. <http://dx.doi.org/10.1002/hlca.19890720402>