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Pure Appl. Chem., 1987, Vol. 59, No. 11, pp. 1549-1560

http://dx.doi.org/10.1351/pac198759111549

ANALYTICAL CHEMISTRY DIVISION
COMMISSION ON ELECTROANALYTICAL CHEMISTRY

Reference value standards and primary standards for pH measurements in organic solvents and water + organic solvent mixtures of moderate to high permittivities

S. Rondinini, P. R. Mussini and T. Mussini

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  • Zevatskii Yu. E., Samoilov D. V., Mchedlov-Petrosyan N. O.: Conthemporary methods for the experimental determination of dissociation constants of organic acids in solutions. Russ J Gen Chem 2009, 79, 1859. <http://dx.doi.org/10.1134/S1070363209090138>
  • Berezkin V. G., Sumina E. G., Shtykov S. N., Atayan V. Z., Zagniboroda D. A., Nekhoroshev G. A.: Effect of Chamber Gas Phase on Mobile Phase pH and on Separation Efficiency in TLC. A New Mode of Chromatography. Chroma 2006, 64, 105. <http://dx.doi.org/10.1365/s10337-006-0836-4>
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  • Sanz-Nebot V, Andón B, Barbosa J: Characterization of metallothionein isoforms from rabbit liver by liquid chromatography coupled to electrospray mass spectrometry. J Chromatogr B 2003, 796, 379. <http://dx.doi.org/10.1016/j.jchromb.2003.08.024>
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  • Barbosa J, Barrón D, Jiménez-Lozano E, Sanz-Nebot V: Comparison between capillary electrophoresis, liquid chromatography, potentiometric and spectrophotometric techniques for evaluation of pKa values of zwitterionic drugs in acetonitrile–water mixtures. Analytica Chimica Acta 2001, 437, 309. <http://dx.doi.org/10.1016/S0003-2670(01)00997-7>
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  • Antonini D, Falciola L, Mussini P.R, Mussini T: Medium effects, comparability and predictability of pH-standards in aqueous+organic solvent mixtures: behavior of the (ethylene carbonate+water) and (propylene carbonate+water) systems. Journal of Electroanalytical Chemistry 2001, 503, 153. <http://dx.doi.org/10.1016/S0022-0728(01)00345-X>
  • Barbosa J., Barrón D., Cano J., Jiménez-Lozano E., Sanz-Nebot V., Toro I.: Evaluation of electrophoretic method versus chromatographic, potentiometric and absorptiometric methodologies for determing pKa values of quinolones in hydroorganic mixtures. J  Pharm Biomed Anal 2001, 24, 1087. <http://dx.doi.org/10.1016/S0731-7085(00)00561-6>
  • Barrón D., Jiménez-Lozano E., Barbosa J.: Capillary electrophoresis in mixed aqueous-organic media: Effect of tetrahydrofuran on mobilities, dissociation constants and separation of a series of quinolones. Chroma 2000, 52, 395. <http://dx.doi.org/10.1007/BF02535709>
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  • Barrón Dolores, Jiménez-Lozano Eulalia, Barbosa José: Electrophoretic behaviour of zwitterionic compounds in capillary electrophoresis. Analytica Chimica Acta 2000, 415, 83. <http://dx.doi.org/10.1016/S0003-2670(00)00884-9>
  • Barrón D., Barbosa J.: Acid–base behaviour of substituted phenolic substances and resolution of acid strength in tetrahydrofuran. Analytica Chimica Acta 2000, 403, 339. <http://dx.doi.org/10.1016/S0003-2670(99)00635-2>
  • Barrón D., Buti S., Barbosa J.: Standardization of potentiometric sensors and acid–base behaviour of a series of bases in nitrobenzene. Analytica Chimica Acta 2000, 403, 349. <http://dx.doi.org/10.1016/S0003-2670(99)00636-4>
  • Rosés M: Dissociation constants of phenols in methanol–water mixtures. J Chromatogr A 2000, 867, 45. <http://dx.doi.org/10.1016/S0021-9673(99)01139-5>
  • Barbosa José, Barrón Dolores, Butí Salvador: Autoprotolysis Constants and Standardization of pH Measurements in Tetrahydrofuran-Water Mixtures. Electroanalysis (N Y ) 1999, 11, 627. <http://dx.doi.org/10.1002/(SICI)1521-4109(199907)11:9<627::AID-ELAN627>3.0.CO;2-V>
  • Barbosa J, Bergés R, Sanz-Nebot V, Toro I: Chromatographic behavior of ionizable compounds in liquid chromatography. Part 2. Standardization of potentiometric sensors and effect of pH and ionic strength on the retention of analytes using acetonitrile–water mobile phases. Analytica Chimica Acta 1999, 389, 43. <http://dx.doi.org/10.1016/S0003-2670(99)00132-4>
  • Barbosa J, Barrón D, Butı́ S: Chromatographic behaviour of ionizable compounds in liquid chromatography. Part 1. pH scale, pKa and pHS values for standard buffers in tetrahydrofuran–water. Analytica Chimica Acta 1999, 389, 31. <http://dx.doi.org/10.1016/S0003-2670(99)00133-6>
  • Barbosa J, Marqués I, Barrón D, Sanz-Nebot V: The application of factor analysis to solvatochromic parameters and pHs values for the standardization of potentiometric sensors in mobile phases used in liquid chromatography. Trends in Analytical Chemistry 1999, 18, 543. <http://dx.doi.org/10.1016/S0165-9936(99)00131-4>
  • Marqués I, Fonrodona G, Butı́ S, Barbosa J: Solvent effects on mobile phases used in liquid chromatography: factor analysis applied to protonation equilibria and solvatochromic parameters. Trends in Analytical Chemistry 1999, 18, 472. <http://dx.doi.org/10.1016/S0165-9936(99)00134-X>
  • Barrón D., Butı́ S., Ruiz M., Barbosa J.: Evaluation of acidity constants and preferential solvation in tetrahydrofuran–water mixtures. J Polyhedron 1999, 18, 3281. <http://dx.doi.org/10.1016/S0277-5387(99)00265-X>
  • Barbosa J., Barrón D., Butı́ S., Marqués I.: Assignment of pHS values of reference buffer solutions for standardization of potentiometric sensors in THF–water. J Polyhedron 1999, 18, 3361. <http://dx.doi.org/10.1016/S0277-5387(99)00274-0>
  • The quantity ‘pH’. Journal of Electroanalytical Chemistry 1998, 441, 293. <http://dx.doi.org/10.1016/S0022-0728(97)00433-6>
  • Barbosa J, Barrón D, Bergés R, Buti S, Sanz-Nebot V: Evaluation of the effect of organic modifier on pK values of diuretics in mobile phases used in LC. Int J of Pharmaceutics 1998, 160, 173. <http://dx.doi.org/10.1016/S0378-5173(97)00303-7>
  • Announcement of the IUPAC commission concerning pH. J Solution Chem 1997, 26, 1011. <http://dx.doi.org/10.1007/BF02768057>
  • Muinasmaa Urmas, Ràfols Clara, Bosch Elisabeth, Rosés Martí: Ionic equilibria in aqueous organic solvent mixtures the dissociation constants of acids and salts in tetrahydrofuran/water mixtures. Analytica Chimica Acta 1997, 340, 133. <http://dx.doi.org/10.1016/S0003-2670(96)00516-8>
  • Barbosa J., Toro I., Sanz-Nebot V.: Acid-base behaviour of tripeptides in solvents used in liquid chromatography. Correlation between pK values and solvatochromic parameters of acetonitrile-water mixtures. Analytica Chimica Acta 1997, 347, 295. <http://dx.doi.org/10.1016/S0003-2670(97)00163-3>
  • Barbosa J., Marqués I., Fonrodona G., Barrón D., Bergés R.: Factor analysis applied to correlation between acidity constants of series of diuretics, quinolones and buffers, with solvatochromic parameters in water-acetonitrile mixtures. Analytica Chimica Acta 1997, 347, 385. <http://dx.doi.org/10.1016/S0003-2670(97)00172-4>
  • Barbosa J., Fonrodona G., Marqués I., Sanz-Nebot V., Toro I.: Solvent effects on protonation equilibria of peptides and quinolones by factor analysis applied to the correlation between dissociation constants and solvatochromic parameters in acetonitrile-water mixtures. Analytica Chimica Acta 1997, 351, 397. <http://dx.doi.org/10.1016/S0003-2670(97)00234-1>
  • The quantity “pH”: call for experts. Analytica Chimica Acta 1997, 351, I. <http://dx.doi.org/10.1016/S0003-2670(97)90009-X>
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  • Barbosa J., Bergés R., Toro I., Sanz-Nebot V.: Dissociation constants and preferential solvation of fluoroquinolones in hydroorganic mixtures used in LC. Int J of Pharmaceutics 1997, 149, 213. <http://dx.doi.org/10.1016/S0378-5173(97)04871-0>
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