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Pure Appl. Chem., 1986, Vol. 58, No. 4, pp. 597-616

The effect of transition metal benzyl and propargyl species on the behavior of steroidal hormones

G. Jaouen

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  • Davis Rebecca L., Lodewyk Michael W., Siebert Matthew R., Tantillo Dean J.: Complex consequences: Substituent effects on metal⋯arylmethylium interactions. Journal of Organometallic Chemistry 2013, 748, 68. <>
  • Dubarle-Offner Julien, Rose-Munch Françoise, Dötz Karl-Heinz, Rose Eric, Cuvier Anne Sophie, Panossian Armen: Chromium-Templated Benzannulation of (η5-Cyclohexadienyl)Mn(CO)3-Methoxy-Cr(CO)5 Carbenes. Organomettalics 2011, 30, 6778. <>
  • Lellouche Jean-Paul, Piran Maytal, Shahar Lior, Grinblat Judith, Pirlot Christophe: A reversible decoration of multi-walled carbon nanotubes (MWCNTs) by acyclic η4-(1E,3E)-dienyl-Fe(CO)3 complexes. J Mater Chem 2008, 18, 1093. <>
  • Netz Astrid, Drees Markus, Strassner Thomas, Müller Thomas J. J.: Planar Chiral (Arene)chromiumcarbonyl-Substituted Propargyl Cations – A Spectroscopic and Computational Study. Eur J Org Chem 2007, 2007, 540. <>
  • Rose-Munch Françoise, Rose Eric: cine andtele Nucleophilic Substitutions in (η6-Arene)tricarbonylchromium and Tricarbonyl(η5-cyclohexadienyl)manganese Complexes. Eur J Inorg Chem 2002, 2002, 1269. <<1269::AID-EJIC1269>3.0.CO;2-9>
  • Müller Thomas J. J.: Stereoselective Propargylations with Transition-Metal-Stabilized Propargyl Cations. Eur J Org Chem 2001, 2001, 2021. <<2021::AID-EJOC2021>3.0.CO;2-G>
  • Abd-El-Aziz Alaa S., Bernardin Shelly: Synthesis and reactivity of arenes coordinated to cyclopentadienyliron cations. Coord Chem Rev - 2000, 203, 219. <>
  • Pike Robert D., Sweigart Dwight A.: Electrophilic reactivity of coordinated cyclic π-hydrocarbons. Coord Chem Rev - 1999, 187, 183. <>
  • Müller Thomas J.J., Netz Astrid: SN1 reactions with planar chiral (arene)Cr(CO)3-substituted α-propargyl cations - regio- and diastereoselective additions to novel ambident electrophiles. Tetrahetron Lett 1999, 40, 3145. <>
  • Tang Jie, Top Siden, Vessières Anne, Sellier Nicole, Vaissermann Jacqueline, Jaouen Gérard: Synthesis of 17α-ruthenocenyl-17β-oestradiol and its potential as a radiopharmaceutical agent. Appl Organometal Chem 1997, 11, 771. <<771::AID-AOC629>3.0.CO;2-H>
  • Piórko Adam, Sutherland Ronald G., Vessiéres-Jaouen Anne, Jaouen Gerard: Metal-marked steroids of the estrane group from the reaction of steroidal functional groups with arene-iron(Cp) complexes. J Organomet Chem 1996, 512, 79. <>
  • Bitterwolf Thomas E., Hubler Timothy L.: Resolution of racemic mixtures of chiral arenechromiumtricarbonyl complexes using a Bakerbond Chiralcel HPLC column. J Organomet Chem 1995, 487, 119. <>
  • Sénéchal-Tocquer M.C., Senechal D., Le Bihan J.Y., Gentric D., Caro B., Gruselle M., Cordier C., Jaouen G.: Déprotonation des allylbenzènes chrometricarbonyle en milieu basique. Etude RMN 1H et 13C et réeactivité des anions allyliques: influence électronique et stérique du groupement chrometricarbonyle. J Organomet Chem 1993, 458, 105. <>
  • Sénéchal-Tocquer M.-C., Sénéchal D., Le Bihan J.-Y., Gentric D., Caro B.: Déprotonation des allylbenzènes chrometricarbonyle en milieu basique. Influence du système basique et du groupement chrometricarbonyle sur la régiosélectivité de l'addition des dérivés carbonylés et sur la nature des produits isolés. J Organomet Chem 1991, 420, 185. <>
  • Ganesh Sambasivam, Sarkar Amitabha: Highly diastereoselective Michael addition to 2-arylidene-1-tetralones complexed with Cr(CO)3. Tetrahetron Lett 1991, 32, 1085. <>
  • Kündig E. Peter, Ferret Celia, Rudolph Bruno: Bicyclo[4.2.0]octa-1,3,5-triene: 2-Mono- and 2,5-Disubstituted Derivativesvia Highly Regioselective Lithiation of Its Cr(CO)3 Complex andvia Reductive Silylation/Oxidation. HCA 1990, 73, 1970. <>
  • Cordier Christine, Gruselle Michel, Jaouen Gérard, Hughes Donald W., McGlinchey Michael J.: Structures of zearalenone and zearalanone in solution: A high-field NMR and molecular modelling study. Magn Reson Chem 1990, 28, 835. <>
  • Kalinin V.N., Moiseev S.K., Bakhmutov V.I., Cherepanov I.A.: Arenetricarbonylchromium complexes in the synthesis of 6,7-benzomorphanes. J Organomet Chem 1990, 383, 85. <>
  • Wright Michael E.: {η6-1,4-(CH3SO3)2C6H4}Cr(CO)3: synthesis, characterization, and reactivity. J Organomet Chem 1989, 376, 353. <>
  • Troitskaya L.L., Sokolov V.I., Bakhmutov V.I., Reutov O.A., Gruselle M., Cordier C., Jaouen G.: Stabilisation of carbenium ions species by two different adjacent organometallic moieties: synthesis, NMR study and synthetic application. J Organomet Chem 1989, 364, 195. <>
  • Ohlsson Bengt, Ullenius Christina, Jagner Susan, Grivet Chantal, Wenger Eric, Kündig E.Peter: Indanetricarbonylchromium: the effects of 1-syn- and 1-anti substituents on the regioselectivity of nucleophilic addition. Crystal structures of 1-syn- and 1-anti- methoxyindanetricarbonylchromium. J Organomet Chem 1989, 365, 243. <>
  • Jaouen Gerard, Howell James A.S., Tirvengadum Marie-Claire, McArdle Patrick, Cunningham Desmond: Diastereoisomer separation and absolute configuration of (ortho- and (meta-MeC6H4CO2Me)Cr(CO)2L (L = (+)-neomenthyl-PPh2). J Organomet Chem 1989, 370, 51. <>
  • Mailvaganam Bavani, Perrier Richard E., Sayer Brian G., McCarry Brian E., Bell Russell A., McGlinchey Michael J.: Chromium tricarbonyl complexes of methyl O-methylpodocarpate: differentiation of diastereomers by high field NMR spectroscopy. J Organomet Chem 1988, 354, 325. <>
  • Le Bihan J.-Y., Senechal-Tocquer M.-C., Senechal D., Gentric D., Caro B., Halet J.-F., Saillard J.-Y., Jaouen G., Top S.: Synthese directe de phenylpyruvates chrome tricarbonyle. Influences de la substitution sur la nature cetonique ou enolique des produits isoles, et du groupement Cr(CO)3 sur l'equilibre tautomere. Tetrahedron 1988, 44, 3565. <>
  • Franck-Neumann Michel, Martina Daniel, Heitz Marie-Paule: Carbanions en α de sites coordonnes au fer-tricarbonyle. Journal of Organometallic Chemistry 1986, 315, 59. <>