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Pure Appl. Chem., 1983, Vol. 55, No. 11, pp. 1677-1688

Template catalysis via non-transition metal complexes. New highly selective syntheses on phenol systems

G. Casnati, G. Casiraghi, A. Pochini, G. Sartori and R. Ungaro

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  • Xu Cong, Yuan Hongjuan, Liu Yingjie, Wang Mang, Liu Qun: Hydrobromic acid-catalyzed Friedel–Crafts type reactions of naphthols. RSC Adv. 2014, 4, 1559. <>
  • Chiusoli Gian Paolo, Catellani Marta, Costa Mirco, Motti Elena, Della Ca’ Nicola, Maestri Giovanni: Catalytic C–C coupling through C–H arylation of arenes or heteroarenes. Coord Chem Rev - 2010, 254, 456. <>
  • Catellani Marta, Motti Elena, Della Ca' Nicola, Ferraccioli Raffaella: Recent Developments in Catalytic Aryl Coupling Reactions. Eur J Org Chem 2007, 2007, 4153. <>
  • Bougdid Lahoussine, Heynderickx Arnault, Delbaere Stéphanie, Moustrou Corinne: First synthesis of nitro-substituted 2,2-diphenyl-2H-1-benzopyrans via the ipso-nitration reaction. Tetrahedron 2007, 63, 8242. <>
  • Li Min, Wu Anmei, Zhou Peijie: A concise synthesis of (+)-pancratistatin using pinitol as a chiral building block. Tetrahetron Lett 2006, 47, 3707. <>
  • Ohishi Takeshi, Kojima Tomoyuki, Matsuoka Tatsuomi, Shiro Motoo, Kotsuki Hiyoshizo: High-yielding TfOH-catalyzed condensation of phenols with aromatic aldehydes at high pressure. A model synthesis of the benzylidene biphenol key skeleton of blepharismins. Tetrahetron Lett 2001, 42, 2493. <>
  • Hewawasam Piyasena, Erway Matthew: Reactivity and regioselectivity of magnesium phenolates towards isatins: One-step synthesis of 3-(2-hydroxyaryl)-3-hydroxyindolones. Tetrahetron Lett 1998, 39, 3981. <>
  • Bocelli Gabriele, Cantoni Andrea, Sartori Giovanni, Maggi Raimondo, Bigi Franca: Metal-Template Electrophilic Substitution on Phenols: Synthesis and Crystal Structure of Bromomagnesium Phenolate and Its Reactive Complex withpara-Isopropylbenzaldehyde. Chem Eur J 1997, 3, 1269. <>
  • Sartori Giovanni, Maggi Raimondo, Bigi Franca, Porta Cecilia, Tao Xiaochun, Bernardi Gian Luca, Ianelli Sandra, Nardelli Mario: Selective synthesis of 1-indanones via tandem knoevenagel condensation-cycloalkylation of β-dicarbonyl compounds and aldehydes. Tetrahedron 1995, 51, 12179. <>
  • Sartori Giovanni, Bigi Franca, Maggi Raimondo, Porta Cecilia: Metal-template ortho-regioselective mono- and bis-de-tert-butylation of poly-tert-butylated phenols. Tetrahetron Lett 1994, 35, 7073. <>
  • Guanti Giuseppe, Banfi Luca, Riva Renata: Regioselective synthesis of 1,8-dihydroxytetralins through a tandem reduction/intramolecular hydroxyalkylation of 4-(3-hydroxyphenyl)alkanoates. Tetrahedron 1994, 50, 11945. <>
  • Sartori Giovanni, Maggi Raimondo, Bigi Franca, Arienti Attillio, Porta Cecilia, Predieri Giovanni: Metal-template ortho-regioselective synthesis of 2′-hydroxyphenylpyridinemethanols. Tetrahedron 1994, 50, 10587. <>
  • Sartori Giovanni, Bigi Francia, Maggi Raimondo, Bernardi Gian Luca: Friedel-crafts coordinated processes: 1-Oxoindanes from aromatic β-dicarbonyl compounds and aldehydes. Tetrahetron Lett 1993, 34, 7339. <>
  • Sartori Giovanni, Maggi Raimondo, Cantarelli Edo, Galaverna Gianni, Bigi Franca: Synthesis of optically active 4-hydroxymandelic acid and derivatives via Regio- and Stereoselective Friedel-Crafts alkylation. Tet Asymm 1993, 4, 2411. <>
  • Sartori Giovanni, Maggi Raimondo, Bigi Franca, Arienti Attilio, Casnati Giuseppe: Regiochemical control in the oxidative coupling of metal phenolates: Highly selective synthesis of symmetric, hydroxylated biaryls. Tetrahetron Lett 1992, 33, 2207. <>
  • Guanti Giuseppe, Banfi Luca, Narisano Enrica, Riva Renata, Thea Sergio: Tandem reduction / intramolecular hydroxyalkylation of (3-hydroxyphenyl)alkanoates: a new regioselective approach to 1,8-dihydroxytetralins. Tetrahetron Lett 1992, 33, 3919. <>
  • Adachi Makoto, Sugasawa Tsutomu: Exclusive Ortho Cyanation and Alkylthiocarbonylation of Anilines and Phenols Using Boron Trichloride. Synth Common 1990, 20, 71. <>
  • Casiraghi Giovanni, Cornia Mara, Rassu Gloria, Zetta Lucia, Gasparri Fava Giovanna, Ferrari Belicchi Marisa: Stereoselective arylation of pyranoid glycals, using bromomagnesium phenolates: An entry to 2,3-unsaturated C-α-glycopyranosylarenes. Carbohydrates Research 1989, 191, 243. <>
  • Sartori Giovanni, Casnati Giuseppe, Bigi Franca, Robles Pasquale: Metal template ortho-acylation of phenols; A new general approach to anthracyclinones. Tetrahetron Lett 1987, 28, 1533. <>
  • Bigi Franca, Casiraghi Giovanni, Casnati Giuseppe, Sartori Giovanni, Soncini Paolo, Fava Giovanna Gasparri, Belicchi Marisa Ferrari: Highly stereocontrolled substitution of phenols with pyruvic esters. A viable route to -hydroxyatrolactic esters of (2R)- and (2S)-configuration. Tetrahetron Lett 1985, 26, 2021. <>
  • Bigi Franca, Casiraghi Giovanni, Casnati Giuseppe, Marchesi Stefania, Sartori Giovanni, Vignali Carlo: Unusual Friedel-Crafts reactions, IX. One-step ortho-acylation of phenols with α,β-unsaturated acyl chlorides. Synthesis of 2'-hydroxychalcones and sorbicillin analogues. Tetrahedron 1984, 40, 4081. <>