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Pure Appl. Chem., 1982, Vol. 54, No. 1, pp. 43-58

http://dx.doi.org/10.1351/pac198254010043

Metallacarboranes and metal-boron clusters in organometallic synthesis

R. N. Grimes

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  • Anju V. P., Barik Subrat Kumar, Mondal Bijnaneswar, Ramkumar V., Ghosh Sundargopal: Metallaboranes from Metal Carbonyl Compounds and Their Utilization as Catalysts for Alkyne Cyclotrimerization. ChemPlusChem 2014, 79, 546. <http://dx.doi.org/10.1002/cplu.201400013>
  • Roy Dipak Kumar, Ghosh Sundargopal, Halet Jean-François: Beyond the Icosahedron: The Quest for High-Nuclearity Supraicosahedral Metallaboranes. J Clust Sci 2014, 25, 225. <http://dx.doi.org/10.1007/s10876-013-0682-0>
  • Chakrahari Kiran Kumarvarma, Thakur Arunabha, Mondal Bijan, Ramkumar V., Ghosh Sundargopal: Hypoelectronic Dimetallaheteroboranes of Group 6 Transition Metals Containing Heavier Chalcogen Elements. Inorg. Chem. 2013, 52, 7923. <http://dx.doi.org/10.1021/ic400432v>
  • Yuvaraj K., Roy Dipak Kumar, Geetharani K., Mondal Bijan, Anju V. P., Shankhari Pritam, Ramkumar V., Ghosh Sundargopal: Chemistry of Homo- and Heterometallic Bridged-Borylene Complexes. Organometallics 2013, 32, 2705. <http://dx.doi.org/10.1021/om400167f>
  • Geetharani K., Ramkumar V., Ghosh Sundargopal: Synthesis and Characterization of Novel Ruthenaferracarboranes from Photoinsertion of Alkynes into a Ruthenaferraborane. Organometallics 2012, 31, 6381. <http://dx.doi.org/10.1021/om300607u>
  • Bose Shubhankar Kumar, Mobin Shaikh M., Ghosh Sundargopal: Metallaheteroborane clusters of group 5 transition metals derived from dichalcogenide ligands. j organometall chem 2011, 696, 3121. <http://dx.doi.org/10.1016/j.jorganchem.2011.06.040>
  • Bose Shubhankar Kumar, Geetharani K., Sahoo Satyanarayan, Reddy K. Hari Krishna, Varghese Babu, Jemmis Eluvathingal D., Ghosh Sundargopal: Synthesis, Characterization, and Electronic Structure of New Type of Heterometallic Boride Clusters. Inorg. Chem. 2011, 50, 9414. <http://dx.doi.org/10.1021/ic201046g>
  • Gribanova Tatyana N., Starikov Andrey G., Minyaev Ruslan M., Minkin Vladimir I., Siebert Matthew R., Tantillo Dean J.: Sandwich Compounds of Transition Metals with Cyclopolyenes and Isolobal Boron Analogues. Chem Eur J 2010, 16, 2272. <http://dx.doi.org/10.1002/chem.200902004>
  • Geetharani K., Bose Shubhankar Kumar, Varghese Babu, Ghosh Sundargopal: From Metallaborane to Borylene Complexes: Syntheses and Structures of Triply Bridged Ruthenium and Tantalum Borylene Complexes. Chem Eur J 2010, 16, 11357. <http://dx.doi.org/10.1002/chem.201001208>
  • Geetharani K., Kumar Bose Shubhankar, Pramanik Goutam, Kumar Saha Tanmoy, Ramkumar V., Ghosh Sundargopal: An Efficient Route to Group 6 and 8 Metallaborane Compounds: Synthesis of arachno-[Cp*Fe(CO)B3H8] and closo-[(Cp*M)2B5H9] (M = Mo, W). Eur J Inorg Chem 2009, 2009, 1483. <http://dx.doi.org/10.1002/ejic.200801137>
  • Gribanova T. N., Minyaev R. M., Starikov A. G., Minkin V. I.: π-Complexes of transition metal tricarbonyls with cyclopolyenes and their boron analogs. Russ Chem Bull 2009, 58, 691. <http://dx.doi.org/10.1007/s11172-009-0080-9>
  • Bose Shubhankar Kumar, Geetharani K., Varghese Babu, Mobin Shaikh M., Ghosh Sundargopal: Metallaboranes of the Early Transition Metals: Direct Synthesis and Characterization of [{(η5-C5Me5)Ta}2BnHm] (n=4, m=10; n=5, m=11), [{(η5-C5Me5)Ta}2B5H10(C6H4CH3)], and [{(η5-C5Me5)TaCl}2B5H11]. Chem Eur J 2008, 14, 9058. <http://dx.doi.org/10.1002/chem.200800487>
  • Ghosh Sundargopal, Noll Bruce C., Fehlner Thomas P.: Expansion of iridaborane clusters by addition of monoborane. Novel metallaboranes and mechanistic detail. Dalton Trans 2008, 371. <http://dx.doi.org/10.1039/b715040g>
  • Yan Hong, Noll Bruce C., Fehlner Thomas P.: Reaction of nido-1,2-(Cp∗RuH)2B3H7 with ethynylferrocene to yield new metallacarboranes. J Organomet Chem 2006, 691, 5060. <http://dx.doi.org/10.1016/j.jorganchem.2006.08.003>
  • Yan Hong, Beatty Alicia M., Fehlner Thomas P.: Reaction of 2-Butyne withnido-[1,2-(Cp*RuH)2B3H7]: Improved Kinetic Control Leads to Metallacarboranes of Novel Composition and Structure. Angew Chem Int Ed 2002, 41, 2578. <http://dx.doi.org/10.1002/1521-3773(20020715)41:14<2578::AID-ANIE2578>3.0.CO;2-X>
  • Weller Andrew S., Aldridge Simon, Fehlner Thomas P.: Early versus late transition metals. Electronic structure of nido-2-CpMLnB4H8, CpMLn=CpTaCl2, CpWH3 and CpCo. Inorg Chim Ada 1999, 289, 85. <http://dx.doi.org/10.1016/S0020-1693(99)00061-4>
  • Halet Jean-Frangois: Limitations of the polyhedral skeletal electron pair theory in organometallic cluster chemistry: examples in tri- and tetrametallic systems. Coord Chem Rev - 1995, 143, 637. <http://dx.doi.org/10.1016/0010-8545(95)08002-M>
  • Alexander John J.: Iron. J Organomet Chem 1985, 283, 415. <http://dx.doi.org/10.1016/0022-328X(85)80004-8>