Pure and Applied Chemistry

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• Pekel Özgen Ömür, Erdik Ender: Reactivity of mixed organozinc and mixed organocopper reagents: 10 Comparison of the transferability of the same group in acylation of mixed and homo halozinc diorganocuprates with benzoyl chloride. A kinetic study. Journal of Organometallic Chemistry 2014, 751, 644. <http://dx.doi.org/10.1016/j.jorganchem.2013.10.030>
• Otero Antonio, Fernández-Baeza Juan, Lara-Sánchez Agustín, Sánchez-Barba Luis F.: Metal complexes with heteroscorpionate ligands based on the bis(pyrazol-1-yl)methane moiety: Catalytic chemistry. Coordination Chemistry Reviews 2013, 257, 1806. <http://dx.doi.org/10.1016/j.ccr.2013.01.027>
• Essa Ali H., Lerrick Reinner I., Tuna Floriana, Harrington Ross W., Clegg William, Hall Michael J.: Reduction of 2,2,2-trichloro-1-arylethanones by RMgX: mechanistic investigation and the synthesis of substituted α,α-dichloroketones. Chem. Commun. 2013, 49, 2756. <http://dx.doi.org/10.1039/c3cc39147g>
• Zong Hua, Huang Huayin, Liu Junfeng, Bian Guangling, Song Ling: Added-Metal-Free Catalytic Nucleophilic Addition of Grignard Reagents to Ketones. J Org Chern 2012, 77, 4645. <http://dx.doi.org/10.1021/jo3004277>
• Otero Antonio, Fernández-Baeza Juan, Sánchez-Barba Luis F., Tejeda Juan, Honrado Manuel, Garcés Andrés, Lara-Sánchez Agustín, Rodríguez Ana M.: Chiral N,N,O-Scorpionate Zinc Alkyls as Effective and Stereoselective Initiators for the Living ROP of Lactides. Organometallics 2012, 31, 4191. <http://dx.doi.org/10.1021/om300146n>
• Shen Ruwei, Iwasaki Takanori, Terao Jun, Kambe Nobuaki: Copper-catalyzed coupling reaction of unactivated secondary alkyl iodides with alkyl Grignard reagents in the presence of 1,3-butadiene as an effective additive. Chem. Commun. 2012, 48, 9313. <http://dx.doi.org/10.1039/c2cc34847k>
• Henriques André M., Barbosa André G. H.: Chemical Bonding and the Equilibrium Composition of Grignard Reagents in Ethereal Solutions. J Phys Chem A 2011, 115, 12259. <http://dx.doi.org/10.1021/jp202762p>
• Wu Shupeng, Huang Li, Tian Hongkun, Geng Yanhou, Wang Fosong: LiCl-Promoted Chain Growth Kumada Catalyst-Transfer Polycondensation of the “Reversed” Thiophene Monomer. Macro­molecules 2011, 44, 7558. <http://dx.doi.org/10.1021/ma201192p>
• Sánchez-Barba Luis F., Garcés Andrés, Fernández-Baeza Juan, Otero Antonio, Alonso-Moreno Carlos, Lara-Sánchez Agustín, Rodríguez Ana M.: Stereoselective Production of Poly(rac-lactide) by ROP with Highly Efficient Bulky Heteroscorpionate Alkylmagnesium Initiators. Organomet 2011, 30, 2775. <http://dx.doi.org/10.1021/om200163t>
• Kaim Wolfgang: Einelektronenübertragung: Abschied von Elektronenpaar-Mechanismen?. Nachr Chem Tech Lab 2010, 32, 436. <http://dx.doi.org/10.1002/nadc.19840320509>
• Fleury Lauren M., Ashfeld Brandon L.: Generation of allyl Grignard reagents via titanocene-catalyzed activation of allyl halides. Tetrahetron Lett 2010, 51, 2427. <http://dx.doi.org/10.1016/j.tetlet.2010.02.144>
• Eroğlu Fatma, Kâhya Didem, Erdik Ender: Leaving group effect in the sulfonyl transfer reactions of aryl benzenesulfonates with Grignard reagents. React Kinet Catal Lett 2009, 98, 365. <http://dx.doi.org/10.1007/s11144-009-0053-x>
• Bracca Andrea B. J., Kaufman Teodoro S.: Synthesis of the Carbon Framework of the Stephaoxocanes Employing a Sequential RCM/Pomeranz–Fritsch Approach. Eur J Org Chem 2007, 2007, 5284. <http://dx.doi.org/10.1002/ejoc.200700570>
• Kaim Wolfgang: Elektronenübertragung durch Grignard-Reagentien: Direkter Nachweis von Organomagnesium-Radikalkomplexen. Angew Chem 2006, 94, 150. <http://dx.doi.org/10.1002/ange.19820940232>
• Kaim Wolfgang: Die vielseitige Chemie der 1,4-Diazine: Organische, anorganische und biochemische Aspekte. Angew Chem 2006, 95, 201. <http://dx.doi.org/10.1002/ange.19830950305>
• Panov Dmitri, Tuulmets Ants, Nguyen Binh T.: Impact of reaction products on the Grignard reaction with silanes and ketones. J Organomet Chem 2006, 691, 4076. <http://dx.doi.org/10.1016/j.jorganchem.2006.06.012>
• Lund Henning, Svith Heidi, Pedersen Steen Uttrup, Daasbjerg Kim: Versatile electrochemically based preparation of unusual Grignard reagents containing electrophilic substituents. Electrochimica Acta 2005, 51, 655. <http://dx.doi.org/10.1016/j.electacta.2005.05.027>
• Bull Steven D., Davies Stephen G., Garner A. Christopher, Savory Edward D., Snow Emma J., Smith Andrew D.: 2-Halo-diketopiperazines as chiral glycine cation equivalents. Tet Asymm 2004, 15, 3989. <http://dx.doi.org/10.1016/j.tetasy.2004.11.022>
• Shimizu Makoto, Yamataka Hiroshi: Direct Rate Measurements of the Reactions of Benzophenone with RMgX and RLi: Effects of Substituents and Reagent Concentration on Rates. Bull Chem Soc Jpn 2004, 77, 1757. <http://dx.doi.org/10.1246/bcsj.77.1757>
• Sassian Meeri, Tuulmets Ants: Solvation Effects in theGrignard Reaction with Carbonyl Compounds. HCA 2003, 86, 82. <http://dx.doi.org/10.1002/hlca.200390021>
• Wu Guisheng, Sun Yuhan, Li Yong-Wang, Jiao Haijun, Xiang Hong-Wei, Xu Yuanyuan, Benhallam Rajae, Zair Touria, Jarid Abdellah, Ibrahim-Ouali Malika, Fern��ndez G��mez M, Navarro A, Brand��n S.A, Socolsky C, Ben Altabef A, Varetti E.L: The Nature of Cu/ZrO2 catalyst: experimental and theoretical studies. Journal of Molecular Structure: THEOCHEM 2003, 626, 287. <http://dx.doi.org/10.1016/S0166-1280(02)00667-X>
• Andrews David R, Dahanukar Vilas H, Eckert Jeffrey M, Gala Dinesh, Lucas Brian S, Schumacher Doris P, Zavialov Ilia A: Reaction of aziridinium ions with organometallic reagents: optimization of the key step of ecopipam synthesis. Tetrahetron Lett 2002, 43, 6121. <http://dx.doi.org/10.1016/S0040-4039(02)01337-0>
• Sassian, Meeri, Tuulmets, Ants: REACTIONS OF PARTIALLY SOLVATED GRIGNARD REAGENTS WITH BENZALDEHYDE. MGMC 2002, 25, 745. <http://dx.doi.org/10.1515/MGMC.2002.25.12.745>
• Feeder Neil, Lawson Yvonne G., Raithby Paul R., Rawson Jeremy M., Steiner Alexander, Wood Jody A., Woods Anthony D., Wright Dominic S.: Ein Li10-Käfig mit dem Dianion [C6H11P⋅⋅⋅–C(Ph)⋅⋅⋅–N]2− – Umpolung bei der Oligomerisierung eines Nitrils. Angew Chem 2000, 112, 4309. <http://dx.doi.org/10.1002/1521-3757(20001117)112:22<4309::AID-ANGE4309>3.0.CO;2-#>
• Feeder Neil, Lawson Yvonne G., Raithby Paul R., Rawson Jeremy M., Steiner Alexander, Wood Jody A., Woods Anthony D., Wright Dominic S.: A Li10 Cage Containing the [C6H11P⋅⋅⋅–C(Ph)⋅⋅⋅–N]2− Ion: Umpolung in the Oligomerization of a Nitrile. Angew Chem 2000, 39, 4145. <http://dx.doi.org/10.1002/1521-3773(20001117)39:22<4145::AID-ANIE4145>3.0.CO;2-J>
• Inoue Atsushi, Shinokubo Hiroshi, Oshima Koichiro: Formation of Organomagnesium Compounds via EtMgBr-Mediated Radical Cyclization of Allyl β-Iodoacetals. Org Lett 2000, 2, 651. <http://dx.doi.org/10.1021/ol991403a>
• Tuulmets Ants, Sassian Meeri: Reactions of partially solvated Grignard reagents with a ketone. J Organomet Chem 1999, 586, 145. <http://dx.doi.org/10.1016/S0022-328X(99)00254-5>
• Ooi Takashi, Takahashi Makoto, Maruoka Keiji: Erhöhung der Reaktionsgeschwindigkeit bei der nucleophilen Alkylierung von Carbonylverbindungen durch ein neues Templat mit zwei Metallzentren. Angew Chem 1998, 110, 875. <http://dx.doi.org/10.1002/(SICI)1521-3757(19980316)110:6<875::AID-ANGE875>3.0.CO;2-L>
• Gillmore Jason G., Tanko James M.: Radical ion probes. 11. Reaction of 1,1-dimethyl-5,7-di-t-butylspiro[2.5]octa-4,7-dien-6-one with 5-hexenyl magnesium bromide. Tetrahetron Lett 1998, 39, 8795. <http://dx.doi.org/10.1016/S0040-4039(98)01975-3>
• Patz Matthias, Fukuzumi Shunichi: ELECTRON TRANSFER IN ORGANIC REACTIONS. J Phys Org Chem 1997, 10, 129. <http://dx.doi.org/10.1002/(SICI)1099-1395(199703)10:3<129::AID-POC884>3.0.CO;2-4>
• Holm Torkil: α-Deuterium kinetic isotope effects in reactions of methyllithium: is better aggregation the cause of lower reactivity?. J Organomet Chem 1996, 506, 37. <http://dx.doi.org/10.1016/0022-328X(95)05629-4>
• Alexander Hill E, Boyd Winston A, Desai Hemnalini, Darki Amir, Bivens Lymel: Infrared and nuclear magnetic resonance spectroscopic studies of the structure and dynamics of allylic magnesium compounds. J Organomet Chem 1996, 514, 1. <http://dx.doi.org/10.1016/0022-328X(95)06014-N>
• Eisch J. J.: Single electron transfers in the reactions of carbanions. Res. Chem. Intermed. 1996, 22, 145. <http://dx.doi.org/10.1163/156856796X00593>
• Kanai Motomu, Tomioka Kiyoshi: Catalytic asymmetric conjugate addition of grignard reagents mediated by copper(I)-chiral bidentate phosphine complex. Tetrahetron Lett 1995, 36, 4275. <http://dx.doi.org/10.1016/0040-4039(95)00759-6>
• Majewski Marek, Gleave D.Mark: Reduction with lithium dialkylamides. J Organomet Chem 1994, 470, 1. <http://dx.doi.org/10.1016/0022-328X(94)80142-8>
• M. Aleksandrov Alexander, A. Bourne Susan, Krawiec Mariusz, J.Pehk Tonis, E. Petrenko Alexander, H. Watson William: New route to 4,4,6,7-tetrasubstituted pentacyclo[6.3.0.02,6.03.10.05,9]undecanes. Tetrahedron 1994, 50, 8597. <http://dx.doi.org/10.1016/S0040-4020(01)85334-5>
• Weber Beat, Seebach Dieter: Highly enantioselective addition of primary alkyl Grignard reagents to carbocyclic and heterocyclic arylketones in the presence of magnesium TADDOLate preparative and mechanistic aspects. Tetrahedron 1994, 50, 6117. <http://dx.doi.org/10.1016/S0040-4020(01)90463-6>
• Kamie��ska-Trela Krystyna, Dabrowski Andrzej, Januszewski Henryk, Stolov A.A., Khafizov F.T., Kamalova D.I., Morozov A.I., Remizov A.B., Weber Mark, Blass William E, Nadler Shachar, Halsey George W, Maguire William C, Hillman John J: One-bond CC spin���spin coupling constants in derivatives of benzene. Non-linearity of 1J(CC) vs substituent electronegativity. Spectrochimica Acta Part A: Molecular Spectroscopy 1993, 49, 1613. <http://dx.doi.org/10.1016/0584-8539(93)80118-T>
• Munavalli S., Rossman D.I., Rohrbaugh D.K., Ferguson C.P.: Unusual reaction of Grignard reagents with bis(trifluoromethyl) disulfide. J FLUORINE CHEM 1993, 61, 147. <http://dx.doi.org/10.1016/S0022-1139(00)80425-X>
• Ertel T.S., Bertagnolli H.: An EXAFS study of Grignard compounds in solution. J Polyhedron 1993, 12, 2175. <http://dx.doi.org/10.1016/S0277-5387(00)88254-6>
• Gatrone Ralph C., Jonson Stephanie D.: The Influence of Radical Stability of Organomagnesium Halide Reagents on the Direction of Addition to an α-β-Unsaturated Phosphoryl Group. Synth Common 1993, 23, 2743. <http://dx.doi.org/10.1080/00397919308013805>
• Poster. Phosphorus Sulfur Silicon Relat Elem 1993, 77, 141. <http://dx.doi.org/10.1080/10426509308045639>
• Nicola O., Mackey D., Morley Christopher P.: The reactions of bis(η-cyclopentadienyl)dihydridomolybdenum and -tungsten with diorganylmagnesium reagents. J Polyhedron 1992, 11, 389. <http://dx.doi.org/10.1016/S0277-5387(00)83188-5>
• Sobota Piotr: Halide ion transfer between main group and transition metal halides as a valuable method for the synthesis of new compounds and catalyst precursors. J Polyhedron 1992, 11, 715. <http://dx.doi.org/10.1016/S0277-5387(00)86002-7>
• Yamataka Hiroshi, Yamaguchi Kazuhiko, Takatsuka Tsutomu, Hanafusa Terukiyo: A New Ketyl Radical Probe. Dehalogenation of o-Halobenzophenone. Bull Chem Soc Jpn 1992, 65, 1157. <http://dx.doi.org/10.1246/bcsj.65.1157>
• Maruyama Kazuhiro, Matano Yoshihiro, Katagiri Toshimasa: Product-determining factors in the grignard reactions of benzophenones. The role of the structure of alkyl groups in grignard reagents. J Phys Org Chem 1991, 4, 501. <http://dx.doi.org/10.1002/poc.610040806>
• Markies Peter R., Schat Gerrit, Villena Alan, Akkerman Otto S., Bickelhaupt F., Smeets Wilbert J.J., Spek Anthony L.: The remarkable crystal structure of the dimeric species [bis(ortho-anisyl)magnesium · THF]2. J Organomet Chem 1991, 411, 291. <http://dx.doi.org/10.1016/0022-328X(91)83036-4>
• Han Runyu, Bachrach Max, Parkin Gerard: Competitive alkyl and halide metathesis in the reactions of grignard reagents with Tl{η3-HB(3-Butpz)3}. J Polyhedron 1990, 9, 1775. <http://dx.doi.org/10.1016/S0277-5387(00)83987-X>
• Keys Boyd A., Eliel Ernest L.: Stereochemistry of Electrophilic Reactions of 4-t -Butyl-1-phenylcyclohexyllithium, -sodium, -potassium and -cesium. Isr. J. Chem. 1989, 29, 171. <http://dx.doi.org/10.1002/ijch.198900025>
• Imamoto Tsuneo, Sugiura Yasushi: Selective 1,2-addition of organocerium(III) reagents to α,β-unsaturated carbonyl compounds. J Phys Org Chem 1989, 2, 93. <http://dx.doi.org/10.1002/poc.610020202>
• Bonini Bianca F., Maccagnani Gaetano, Masiero Stefano, Mazzanti Germana, Zani Paolo: Chiral silicon in asymmetric synthesis. Addition of organometallic reagents to a silyl thione chiral at silicon. Tetrahetron Lett 1989, 30, 2677. <http://dx.doi.org/10.1016/S0040-4039(00)99096-8>
• Aurbach Irmgard, Ponti Pier Paolo, Salbeck Erika, Schmuck Heike, Daub Jörg: Ladungstrennung auf molekularer Basis: Chemoselektivität, Regio- und Stereoselektivität der CC-Verknüpfung als Sonden für Elektronentransfer-Prozesse. Chem Ber 1988, 121, 1101. <http://dx.doi.org/10.1002/cber.19881210613>
• Maruyama Kazuhiro, Katagiri Toshimasa: Structure of radical intermediates appearing in the grignard reaction of monoketones. J Phys Org Chem 1988, 1, 21. <http://dx.doi.org/10.1002/poc.610010104>
• Yasuda Hajime, Nakamura Akira: Dien-, Alkin-, Alken- und Alkyl-Komplexe früher Übergangsmetalle: Strukturen und synthetische Anwendungen in Organischer Chemie und Polymerchemie. Angew Chem 1987, 99, 745. <http://dx.doi.org/10.1002/ange.19870990806>
• Sobota Piotr, Duda Barbara: Influence of MgCl2 on Grignard reagent composition in tetrahydrofuran. III. J Organomet Chem 1987, 332, 239. <http://dx.doi.org/10.1016/0022-328X(87)85090-8>
• Chen Qing-Yun, Qiu Zai-Ming, Yang Zhen-Yu: Studies on fluoroalkylation and fluoroalkoxylation. Part 24. Magnesium-induced single electrons transfer in reactions of fluoroalkyl iodides with alkenes and alkynes. J FLUORINE CHEM 1987, 36, 149. <http://dx.doi.org/10.1016/S0022-1139(00)81022-2>
• Reetz M.T., Maus S.: Kinetic studies of the addition of methyltitanium reagents to carbonyl compounds. Tetrahedron 1987, 43, 101. <http://dx.doi.org/10.1016/S0040-4020(01)89935-X>
• Gatrone Ralph C., Kaplan L., Philip Horwitz E.: The Synthesis and Purification of the Carbamoylmethylphosphine Oxides*. Sol Extr Ion Exch 1987, 5, 1075. <http://dx.doi.org/10.1080/07366298708918611>
• Soroka Miroslaw, Shine Henry J.: Reaction of thianthrene cation radical with grignard reagents. Tetrahedron 1986, 42, 6111. <http://dx.doi.org/10.1016/S0040-4020(01)88071-6>
• Cahiez G, Rivas-Enterrios J, Granger-Veyron H: Organomanganese (II) reagents XII: An efficient one-pot preparation of unsymmetrical secondary or tertiary alcohols. Tetrahetron Lett 1986, 27, 4441. <http://dx.doi.org/10.1016/S0040-4039(00)84973-4>
• Braun Manfred, Veith Reiner, Moll Gérard: Regioselektive Addition von Grignard-Reagenzien an 3-Methoxy- und 3-Nitrophthalsäureanhydrid. Chem Ber 1985, 118, 1058. <http://dx.doi.org/10.1002/cber.19851180323>
• Zhang Yunshi, Wenderoth Bernd, Su Wei-Yang, Ashby E.C.: New methodology in determining evidence for single electron transfer in the reaction of Grignard reagents with ketones. J Organomet Chem 1985, 292, 29. <http://dx.doi.org/10.1016/0022-328X(85)87318-6>
• Kaim Wolfgang: The Versatile Chemistry of 1,4-Diazines: Organic, Inorganic and Biochemical Aspects. Angew Chem Int Ed Engl 1983, 22, 171. <http://dx.doi.org/10.1002/anie.198301713>
• Van Koten Gerard, Jastrzebski Johann T.B.H., Vrieze Kees: Stable 1,4-diaza-1,3-butadiene(α-diimine)-zinc and -aluminium radicals formed in single electron transfer reactions: their consequences for organic syntheses. J Organomet Chem 1983, 250, 49. <http://dx.doi.org/10.1016/0022-328X(83)85039-6>
• Kaim Wolfgang: Electorn Transfer by Grignard Reagents: Direct Evidence for Organomagnesium Radical Complexes. Angew Chem Int Ed Engl 1982, 21, 140. <http://dx.doi.org/10.1002/anie.198201401>
• Kaim Wolfgang: Elektronenübertragung durch Grignard-Reagentien: Direkter Nachweis von Organomagnesium-Radikalkomplexen. Angew Chem Int Ed Engl 1982, 21, 289. <http://dx.doi.org/10.1002/anie.198202890>
• Kaim Wolfgang: Ambivalent Coordination Behaviour of Lithium Aluminium Hydride in Electron Transfer Reactions. Angew Chem Int Ed Engl 1982, 21, 298. <http://dx.doi.org/10.1002/anie.198202980>
• Larson Gerald L., Hernández David: A facile synthesis of symmetrical 1,1-disubstituted ethylenes. Tetrahetron Lett 1982, 23, 1035. <http://dx.doi.org/10.1016/S0040-4039(00)87015-X>
• Nagase Shigeru, Uchibori Yukitaka: An ab initio approach to the mechanism of the Grignard reaction. Tetrahetron Lett 1982, 23, 2585. <http://dx.doi.org/10.1016/S0040-4039(00)87402-X>
• Ashby E.C., Goel A.B., DePriest R.N.: EPR evidence for a single electron transfer mechanism in reactions of aromatic ketones with lithium amides. Tetrahetron Lett 1981, 22, 4355. <http://dx.doi.org/10.1016/S0040-4039(01)82955-5>
• Erker Gerhard, Rosenfeldt Frank: Evidence for anchimeric assistance by the Cp2ZrCl-group in the homolytic cleavage of an OCH3 bond. Tetrahetron Lett 1981, 22, 1379. <http://dx.doi.org/10.1016/S0040-4039(01)90326-0>