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Pure Appl. Chem., 1973, Vol. 33, No. 4, pp. 527-544

http://dx.doi.org/10.1351/pac197333040527

Octahedral substitution mechanisms and reactive intermediates

A. M. Sargeson

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  • Morgenstern Bernd, Neis Christian, Zaschka Anton, Romba Jens, Weyhermüller Thomas, Hegetschweiler Kaspar: Formation and Base Hydrolysis of Oxidimethaneamine Bridges in CoIII–Amine Complexes. Inorg. Chem. 2013, 52, 12080. <http://dx.doi.org/10.1021/ic4019053>
  • Beck Wolfgang, Fehlhammer Wolf Peter: Reactions of Metal Carbonyls with the Azide Ion and - vice versa - Reactions of Azido Complexes with Carbon Monoxide: Isocyanato Complexes. Analogous Reactions in NO+/N3 - Transition Metal Chemistry [1]. Z anorg allg Chem 2010, 636, 157. <http://dx.doi.org/10.1002/zaac.200900473>
  • Wijesekera R.D., Sargeson A.M.: Reactivities of coordinated phosphodiesters. J Coord Chem 2005, 58, 3. <http://dx.doi.org/10.1080/00958970512331327393>
  • Banerjea Debabrata: Mechanisms of reactions of metal complexes: Some recent developments. Trans Met Chem 1987, 12, 97. <http://dx.doi.org/10.1007/BF01022335>
  • Rotzinger François P., Marty Werner: A Unified Interpretation of Kinetic Data on the Acid-Induced Cleavage and of Product-Analysis Data on Spontaneous Cleavage of the Mono-ol Cation μ-Hydroxo-bis[pentaamminecobalt(III)] ([(NH3)5CoOHCo(NH3)5]5+). HCA 1985, 68, 1914. <http://dx.doi.org/10.1002/hlca.19850680715>
  • Wilmarth W.K., Ashley K.R., Harmon J.C., Fredericks J., Crumbliss A.L.: Kinetics and mechanism of base aquation of chloroamminebis(dimethylglyoximato)cobalt(III) and chloropyridinebis(dimethylglyoximato)cobalt(III). Coord Chem Rev - 1983, 51, 225. <http://dx.doi.org/10.1016/0010-8545(83)85013-9>
  • Jackson W.G., Begbie C.M., Randall M.L.: Anion competition in the hydrolysis reactions of pentaamminecobalt(III) complexes. Inorg Chim Ada 1983, 70, 7. <http://dx.doi.org/10.1016/S0020-1693(00)82770-X>
  • Jackson W.G.: Aquation of Trans-chloro(dimethylsulfoxide)bis(ethylenediamine)cobalt(III). Inorg Chim Ada 1981, 47, 159. <http://dx.doi.org/10.1016/S0020-1693(00)89323-8>
  • Comba Peter, Marty Werner: Complete Racemization in the Base Hydrolysis of Optically Active mer-[Chloro(diethylene triamine) (1,3-diaminopropan-2-ol-N,N′) cobalt (III)]tetrachlorozincate. HCA 1980, 63, 693. <http://dx.doi.org/10.1002/hlca.19800630319>
  • Buckingham David A., Marty Werner, Sargeson Alan M.: On the mechanism of the Hg2+ and base induced hydrolysis reactions of the β2-(RR, SS)-Co (trien) (glyOR)Cl2+ions (R = H, C2H5), evidence for the site of deprotonation in the reactive conjugate base. HCA 1978, 61, 2223. <http://dx.doi.org/10.1002/hlca.19780610624>
  • Tinner Ursula, Marty Werner: Stereospecific Formation of Pentaamine Complexes of Co(III) with Terdentate 2,6-Bis(aminomethyl)pyridine. HCA 1977, 60, 1629. <http://dx.doi.org/10.1002/hlca.19770600518>
  • Jackson W.G.: Further observations on the case for pentaco-ordinate intermediate formation in octahedral cobalt(III) aquation. Inorg Chim Ada 1974, 10, 51. <http://dx.doi.org/10.1016/S0020-1693(00)86708-0>