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Pure Appl. Chem., 1971, Vol. 28, No. 2-3, pp. 181-194

http://dx.doi.org/10.1351/pac197128020181

The theoretical design of novel stabilized systems

R. Hoffmann

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  • Wu Menghao, Pei Yong, Dai Jun, Li Hui, Zeng Xiao Cheng: Tri-Wing Graphene Nano-Paddle-Wheel with a Single-File Metal Joint: Formation of Multi-Planar Tetracoordinated-Carbon (ptC) Strips. J. Phys. Chem. C 2012, 116, 11378. <http://dx.doi.org/10.1021/jp302115n>
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  • Hu Han-Shi, Qiu Yi-Heng, Xiong Xiao-Gen, Schwarz W. H. Eugen, Li Jun: On the maximum bond multiplicity of carbon: unusual C≣U quadruple bonding in molecular CUO. Chem. Sci. 2012, 3, 2786. <http://dx.doi.org/10.1039/c2sc20329d>
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  • Li Yafei, Li Fengyu, Zhou Zhen, Chen Zhongfang: SiC2 Silagraphene and Its One-Dimensional Derivatives: Where Planar Tetracoordinate Silicon Happens. J. Am. Chem. Soc. 2011, 133, 900. <http://dx.doi.org/10.1021/ja107711m>
  • Cui Zhong-hua, Ding Yi-hong: NXAl3+ (X = N, P, As): penta-atomic planar tetracoordinate nitrogen with N–X multiple bonding. Phys Chem Chem Phys 2011, 13, 5960. <http://dx.doi.org/10.1039/c0cp02475a>
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  • Cui Zhong-hua, Shao Chang-bin, Gao Si-meng, Ding Yi-hong: Pentaatomic planar tetracoordinate carbon molecules [XCAl3]q [(X,q) = (B,−2), (C,−1), (N,0)] with C–X multiple bonding. Phys Chem Chem Phys 2010, 12, 13637. <http://dx.doi.org/10.1039/c0cp00296h>
  • Shao Chang-bin, Ding Yi-hong: Is the planar hexacoordinate nitrogen molecule NB6− viable?. Phys Chem Chem Phys 2010, 12, 13153. <http://dx.doi.org/10.1039/c0cp00676a>
  • Yang Li-ming, Li Xiao-ping, Ding Yi-hong, Sun Chia-chung: CSi2Ga2: a neutral planar tetracoordinate carbon (ptC) building block. J Mol Model 2009, 15, 97. <http://dx.doi.org/10.1007/s00894-008-0362-4>
  • Yang Li-Ming, Ding Yi-Hong, Sun Chia-Chung: The Si-doped planar tetracoordinate carbon (ptC) unit CAl3Si− could be used as a building block or inorganic ligand during cluster-assembly. Theor Chem Acc 2008, 119, 335. <http://dx.doi.org/10.1007/s00214-007-0389-0>
  • Gribanova T. N., Minyaev R. M., Minkin V. I.: Theoretical design of planar systems with hypercoordinate p elements of the second period in a nonmetallic environment. Russ J Gen Chem 2008, 78, 750. <http://dx.doi.org/10.1134/S107036320804035X>
  • Wang Lei-Ming, Huang Wei, Averkiev Boris B., Boldyrev Alexander I., Wang Lai-Sheng: CB7−: Experimental and Theoretical Evidence against Hypercoordinate Planar Carbon. Angew Chem 2007, 119, 4634. <http://dx.doi.org/10.1002/ange.200700869>
  • Wang Lei-Ming, Huang Wei, Averkiev Boris B., Boldyrev Alexander I., Wang Lai-Sheng: CB7−: Experimental and Theoretical Evidence against Hypercoordinate Planar Carbon. Angew Chem Int Ed 2007, 46, 4550. <http://dx.doi.org/10.1002/anie.200700869>
  • Sateesh B., Srinivas Reddy A., Narahari Sastry G.: Towards design of the smallest planar tetracoordinate carbon and boron systems. J Comput Chem 2007, 28, 335. <http://dx.doi.org/10.1002/jcc.20552>
  • Yang Li-ming, Ding Yi-hong, Tian Wei Quan, Sun Chia-chung: Planar carbon radical’s assembly and stabilization, a way to design spin-based molecular materials. Phys Chem Chem Phys 2007, 9, 5304. <http://dx.doi.org/10.1039/b707898f>
  • Xie Hong-bin, Ding Yi-hong: CAl[sub 4]X (X[Double Bond]Si,Ge): Molecules with simultaneous planar tetracoordinate carbon, aluminum, and silicon/germanium. J Chem Phys 2007, 126, 184302. <http://dx.doi.org/10.1063/1.2723109>
  • Krüger Thomas: Periodane—An unexpectedly stable molecule of unique composition. Int J Quantum Chem 2006, 106, 1865. <http://dx.doi.org/10.1002/qua.20948>
  • Cao Xiao-Ping, Barth Dieter, Kuck Dietmar: Multiple Vinylation of Tribenzotriquinacenes and Fenestrindanes at Their Aromatic Peripheries by Use of Nájera’s Catalyst. Eur J Org Chem 2005, 2005, 3482. <http://dx.doi.org/10.1002/ejoc.200500163>
  • Erker Gerhard: Tris(pentafluorophenyl)borane: a special boron Lewis acid for special reactions. Dalton Trans 2005, 1883. <http://dx.doi.org/10.1039/b503688g>
  • Structural and Bonding Trends among the B7C11-,B6C2, and B5C31+. Bulletin of the Korean Chemical Society 2005, 26, 63. <http://dx.doi.org/10.5012/bkcs.2005.26.1.063>
  • Deva Priyakumar U., Narahari Sastry G.: A system with three contiguous planar tetracoordinate carbons is viable: a computational study on a C6H62= isomer. Tetrahetron Lett 2004, 45, 1515. <http://dx.doi.org/10.1016/j.tetlet.2003.12.019>
  • Priyakumar U.Deva, Reddy A.Srinivas, Sastry G.Narahari: The design of molecules containing planar tetracoordinate carbon. Tetrahetron Lett 2004, 45, 2495. <http://dx.doi.org/10.1016/j.tetlet.2004.02.017>
  • Tellenbröker Jörg, Kuck Dietmar: Extending the Chemistry of [5.5.5.5]Fenestranes − Eightfold Peripheral Functionalization of Fenestrindanes. Eur J Org Chem 2001, 2001, 1483. <http://dx.doi.org/10.1002/1099-0690(200104)2001:8<1483::AID-EJOC1483>3.0.CO;2-U>
  • Bredenkötter Björn, Flörke Ulrich, Kuck Dietmar: Benzoannelatedcis,cis,cis,trans-[5.5.5.6]Fenestranes: Syntheses, Base Lability, and Flattened Molecular Structure of Strained Epimers of the all-cis Series. Chem Eur J 2001, 7, 3387. <http://dx.doi.org/10.1002/1521-3765(20010803)7:15<3387::AID-CHEM3387>3.0.CO;2-6>
  • Minyaev R. M., Gribanova T. N.: Stabilization of nonclassical types of valence bond orientation at the carbon atom in organoboron compounds. Russ Chem Bull 2000, 49, 783. <http://dx.doi.org/10.1007/BF02494697>
  • Ding Bangwei, Keese Reinhart, Stoeckli-Evans Helen: Synthese und Struktur des ersten Tetraazasilafenestrans. Angew Chem 1999, 111, 387. <http://dx.doi.org/10.1002/(SICI)1521-3757(19990201)111:3<387::AID-ANGE387>3.0.CO;2-2>
  • Rasmussen Danne R., Radom Leo: Planar tetrakoordinierter Kohlenstoff in einem neutralen gesättigten Kohlenwasserstoff: theoretischer Entwurf und Charakterisierung. Angew Chem 1999, 111, 3051. <http://dx.doi.org/10.1002/(SICI)1521-3757(19991004)111:19<3051::AID-ANGE3051>3.0.CO;2-7>
  • Driess Matthias, Aust Joachim, Merz Klaus, van Wüllen Christoph: van't-Hoff-Le-Bel-Fremdling: Bildung eines Phosphoniumkations mit einem planar-tetrakoordinierten Phosphoratom. Angew Chem 1999, 111, 3967. <http://dx.doi.org/10.1002/(SICI)1521-3757(19991216)111:24<3967::AID-ANGE3967>3.0.CO;2-F>
  • Schottek Jörg, Erker Gerhard, Fröhlich Roland: Formation of Metallocene-Stabilized Planar-Tetracoordinate Carbon Compounds by a Protonation Route. Eur J Inorg Chem 1998, 1998, 551. <http://dx.doi.org/10.1002/(SICI)1099-0682(199805)1998:5<551::AID-EJIC551>3.0.CO;2-H>
  • Röttger Dirk, Erker Gerhard: Verbindungen mit planar tetrakoordiniertem Kohlenstoff. Angew Chem 1997, 109, 840. <http://dx.doi.org/10.1002/ange.19971090805>
  • Schottek Jörg, Erker Gerhard, Fröhlich Roland: Stabilisierung einesC2v-verzerrten Methanderivats in einem Organometallgerüst. Angew Chem 1997, 109, 2585. <http://dx.doi.org/10.1002/ange.19971092221>
  • Aglers Wikfgabg, Erker Gerhard, Fröblich Roland, Peuchert Ulrich: Synthesis, Structure, and Dynamic Behavior of (μ-Aldimido)(μ-η1: η2-alkyne)- biszirconocene Cation Complexes That Contain Planar-Tetracoordinate Carbon. Chem Ber 1997, 130, 1069. <http://dx.doi.org/10.1002/cber.19971300808>
  • Hyla-Kryspin Isabella, Gleiter Rolf, Rohmer Marie-Madelaine, Devemy Jérôme, Gunale Anuradha, Pritzkow Hans, Siebert Walter: Quantum-Chemical Investigations of Stabilizing Interactions in μ-Diborylcarbene Dicobalt Complexes with a Planar Tetracoordinate Carbon Atom. Chem. Eur. J. 1997, 3, 294. <http://dx.doi.org/10.1002/chem.19970030219>
  • Dodziuk Helena, Leszczynski Jerzy, Nowinski Krzysztof S.: The quest for a planar and pyramidal carbon atom Part 4: An unsuccessful search for pyramidal carbon atoms in hypothetical unsaturated conjugated paddlane. Journal of Molecular Structure: THEOCHEM 1997, 391, 201. <http://dx.doi.org/10.1016/S0166-1280(96)04801-4>
  • Röttger Dirk, Erker Gerhard, Fröhlich Roland, Kotila Sirpa: Stabilization of a Planar-tetracoordinate Carbon Center in an Organometallic Complex Containing Both a Zirconocene and a Hafnocene Moiety. Chem Ber 1996, 129, 1. <http://dx.doi.org/10.1002/cber.19961290102>
  • Röttger Dirk, Erker Gerhard, Fröhlich Roland: Formation of stable organometallic planar-tetracoordinate carbon compounds containing a cationic (μ-R1CCR2) [μ-chloro(ZrCp2)2] framework. J Organomet Chem 1996, 518, 221. <http://dx.doi.org/10.1016/0022-328X(96)06208-0>
  • Seifert Monika, Kuck Dietmar: Naphtho-anellated [5.6.5]- and [6.5.5.5]fenestranes. Tetrahedron 1996, 52, 13167. <http://dx.doi.org/10.1016/0040-4020(96)00788-0>
  • Menzel Matthias, Steiner Dirk, Winkler Heinz-Jürgen, Schweikart Dieter, Mehle Sigrid, Fau Stefan, Frenking Gernot, Massa Werner, Berndt Armin: Verbindungen mit planar-tetrakoordinierten Boratomen: Anti-van't-Hoff/Le-Bel-Geometrie ohne Metallzentren. Angew Chem 1995, 107, 368. <http://dx.doi.org/10.1002/ange.19951070323>
  • Gleiter Rolf, Silverio Sandro Johannes, Binger Paul, Sandmeyer Frank, Erker Gerhard: Electronic Structure of Planar-Tricoordinated Phosphorus in Titanium-Boron Complexes. Chem Ber 1995, 128, 775. <http://dx.doi.org/10.1002/cber.19951280806>
  • Rassat Andr��, Scalmani Giovanni, Seroussi Dominique, Berthier Gaston, Sorger Klas, Ragu��^Schleyer Paul von, Wang S.G., Schwarz W.H.E.: Structure and stability of spheroalkanes (CH)10. Journal of Molecular Structure: THEOCHEM 1995, 338, 31. <http://dx.doi.org/10.1016/0166-1280(95)04233-V>
  • Lyons Jennifer E., Rasmussen Danne R., McGrath Mark P., Nobes Ross H., Radom Leo: Octaplan: ein gesättigter Kohlenwasserstoff mit ungewöhnlich niedriger Ionisierungsenergie und einem planar-tetrakoordinierten Kohlenstoffatom im Radikalkation. Angew Chem 1994, 106, 1722. <http://dx.doi.org/10.1002/ange.19941061537>
  • Kuck Dietmar: Benzoanellated Centropolyquinanes, 15. Benzoanellated Fenestranes with [5.5.5], [5.5.5.6], and [5.5.5.5] Frameworks: The Route from 1,3-Indandione to Fenestrindan. Chem Ber 1994, 127, 409. <http://dx.doi.org/10.1002/cber.19941270218>
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