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Pure Appl. Chem., 2013, Vol. 85, No. 11, pp. 2089-2095

Published online 2013-10-05

Solid-solute phase equilibria in aqueous solution: Fundamentals and applications

Erich Königsberger

Chemical and Analytical Sciences, Murdoch University, Murdoch, WA 6150, Australia

Abstract: The importance of solid-solution–aqueous-solution (SSAS) equilibria requires the incorporation of solid solutions into thermodynamic models for industrially and environmentally relevant applications. Insights from appropriate measurements and recent database developments have made such extensions feasible. Examples illustrating various types of stable and metastable equilibria involving solid solutions will be given.