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Pure Appl. Chem., 2010, Vol. 82, No. 8, pp. 1647-1662

Published online 2010-06-19

Concerning the ring-opening polymerization of lactide and cyclic esters by coordination metal catalysts

Malcolm H. Chisholm

Department of Chemistry, The Ohio State University, 100 W. 18th Ave., Columbus, OH 43210, USA

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  • Lamberti Marina, Botta Antonella, Mazzeo Mina: Ring-opening polymerization of cyclic esters by pincer complexes derived from alkaline earth metals. Appl. Organometal. Chem. 2014, 28, 140. <>
  • Sauer Andreas, Buffet Jean-Charles, Spaniol Thomas P., Nagae Haruki, Mashima Kazushi, Okuda Jun: Switching the Lactide Polymerization Activity of a Cerium Complex by Redox Reactions. ChemCatChem 2013, 5, 1088. <>
  • Di Iulio Carlo, Middleton Mathew, Kociok-Köhn Gabriele, Jones Matthew D., Johnson Andrew L.: Synthesis and Characterization of Zinc Ketoiminate and Zinc Alkoxide-/Phenoxide-Ketoiminate Complexes. Eur. J. Inorg. Chem. 2013, 2013, 1541. <>
  • Saridis Emmanuel, Maroulas Serafeim-Dionysios, Pitsikalis Marinos: Ring-opening polymerization of L -lactide using half-titanocene complexes of the ATiCl2 Nu type: Synthesis, characterization, and thermal properties. J. Polym. Sci. A Polym. Chem. 2013, 51, 1162. <>
  • Chuang Hui-Ju, Chen Hsiao-Li, Huang Bor-Hunn, Tsai Tsung-En, Huang Pei-Ling, Liao Tzu-Ting, Lin Chu-Chieh: Efficient zinc initiators supported by NNO-tridentate ketiminate ligands for cyclic esters polymerization. J. Polym. Sci. A Polym. Chem. 2013, 51, 1185. <>
  • Chisholm Malcolm H., Choojun Kittisak, Chow Albert S., Fraenkel Gideon, Gallucci Judith C.: THF Exchange and Molecular Dynamics in the Series (BDI)MgX(THF), Where X = Bun, NEt2, and OBut and BDI = 2-[(2,6-Diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene. Inorg. Chem. 2013, 52, 11302. <>
  • Reisberg Solomon H., Hurley Harry J., Mathers Robert T., Tanski Joseph M., Getzler Yutan D. Y. L.: Lactide Cyclopolymerization Kinetics, X-ray Structure, and Solution Dynamics of (tBu-SalAmEE)Al and a Cautionary Tale Of Polymetalate Formation. Macromolecules 2013, 46, 3273. <>
  • Kumar Anuj, Ghosh Prasenjit: Studies of the Electronic Properties of N-Heterocyclic Carbene Ligands in the Context of Homogeneous Catalysis and Bioorganometallic Chemistry. Eur. J. Inorg. Chem. 2012, 2012, 3955. <>
  • Alemán Carlos, Bertran Oscar, Houk K. N., Padías Anne Buyle, Hall Henry K.: Thermodynamic and stereochemical aspects of the polymerizability of glycolide and lactide. Theor Chem Accounts 2012, 131, 1133. <>
  • Yalcin Gamze, Yildiz Ufuk, Kayan Asgar: Preparation of Al, Ti, Zr-perfluoroheptanoate compounds and their use in ring opening polymerization. Applied Catalysis A: General 2012, 423-424, 205. <>
  • Yalcin Gamze, Kayan Asgar: Synthesis and characterization of Zr, Ti, Al-phthalate and pyridine-2-carboxylate compounds and their use in ring opening polymerization. Applied Catalysis A: General 2012, 433-434, 223. <>
  • Upare Pravin P., Hwang Young Kyu, Chang Jong-San, Hwang Dong Won: Synthesis of Lactide from Alkyl Lactate via a Prepolymer Route. Industrial Eng Chem Res 2012, 51, 4837. <>
  • Otero Antonio, Fernández-Baeza Juan, Sánchez-Barba Luis F., Tejeda Juan, Honrado Manuel, Garcés Andrés, Lara-Sánchez Agustín, Rodríguez Ana M.: Chiral N,N,O-Scorpionate Zinc Alkyls as Effective and Stereoselective Initiators for the Living ROP of Lactides. Organometallics 2012, 31, 4191. <>
  • Chisholm Malcolm H., Choojun Kittisak, Gallucci Judith C., Wambua Pasco M.: Chemistry of magnesium alkyls supported by 1,5,9-trimesityldipyrromethene and 2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene. A comparative study. Chem. Sci. 2012, 3, 3445. <>
  • Quinque Geoffrey T., Oliver Allen G., Rood Jeffrey A.: Synthesis and Structural Characterization of Bis(salicylaldiminato)magnesium Complexes of Varying Aggregation and Coordination State. Eur J Inorg Chem 2011, 2011, 3321. <>
  • Ma Wen-An, Wang Zhong-Xia: Zinc and Aluminum Complexes Supported by Quinoline-Based N,N,N-Chelate Ligands: Synthesis, Characterization, and Catalysis in the Ring-Opening Polymerization of ε-Caprolactone and rac-Lactide. Organomettalics 2011, 30, 4364. <>
  • Chisholm Malcolm H.: POLYMERS FROM RENEWABLE RESOURCES: THE ROLE OF METAL ALKOXIDE CATALYSTS. Comments Inorg Chem 2010, 31, 111. <>