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Pure Appl. Chem., 2008, Vol. 80, No. 5, pp. 953-966

http://dx.doi.org/10.1351/pac200880050953

Asymmetric synthesis: From transition metals to organocatalysis

Pavel Kočovský and Andrei V. Malkov

Department of Chemistry, WestChem, University of Glasgow, Glasgow G12 8QQ, Scotland, UK

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  • Malkov Andrei V., Derrien Nolwenn, Barłóg Maciej, Kočovský Pavel: Palladium-Catalyzed Alkoxycarbonylation of Terminal Alkenes To Produce α,β-Unsaturated Esters: The Key Role of Acetonitrile as a Ligand. Chem. Eur. J. 2014, 20, 4542. <http://dx.doi.org/10.1002/chem.201304798>
  • Deng Yongming, Kumar Siddhartha, Wang Hong: Synergistic–cooperative combination of enamine catalysis with transition metal catalysis. Chem. Commun. 2014, 50, 4272. <http://dx.doi.org/10.1039/c4cc00072b>
  • Malkov Andrei V., Stončius Sigitas, Bell Mark, Castelluzzo Fabiomassimo, Ramírez-López Pedro, Biedermannová Lada, Langer Vratislav, Rulíšek Lubomír, Kočovský Pavel: Mechanistic Dichotomy in the Asymmetric Allylation of Aldehydes with Allyltrichlorosilanes Catalyzed by Chiral Pyridine N -Oxides. Chem. Eur. J. 2013, 19, 9167. <http://dx.doi.org/10.1002/chem.201203817>
  • Malkov Andrei V., Barłóg Maciej, Miller-Potucká Lucie, Kabeshov Mikhail A., Farrugia Louis J., Kočovský Pavel: Stereoselective Palladium-Catalyzed Functionalization of Homoallylic Alcohols: A Convenient Synthesis of Di- and Trisubstituted Isoxazolidines and β-Amino-δ-Hydroxy Esters. Chem. Eur. J. 2012, 18, 6873. <http://dx.doi.org/10.1002/chem.201102716>
  • Fidaly Kassim, Ceballos Claire, Falguières Annie, Veitia Maité Sylla-Iyarreta, Guy Alain, Ferroud Clotilde: Visible light photoredox organocatalysis: a fully transition metal-free direct asymmetric α-alkylation of aldehydes. Green Chem 2012, 14, 1293. <http://dx.doi.org/10.1039/c2gc35118h>
  • Sakiyama Norifumi, Hojo Daiki, Noguchi Keiichi, Tanaka Ken: Enantioselective Synthesis of Axially Chiral 1-Arylisoquinolines by Rhodium-Catalyzed [2+2+2] Cycloaddition. Chem Eur J 2011, 17, 1428. <http://dx.doi.org/10.1002/chem.201003134>
  • Malkov Andrei V., Kysilka Ondřej, Edgar Mark, Kadlčíková Aneta, Kotora Martin, Kočovský Pavel: A Novel Bifunctional Allyldisilane as a Triple Allylation Reagent in the Stereoselective Synthesis of Trisubstituted Tetrahydrofurans. Chem Eur J 2011, 17, 7162. <http://dx.doi.org/10.1002/chem.201100513>
  • Naicker Tricia, Arvidsson Per I., Kruger Hendrik G., Maguire Glenn E. M., Govender Thavendran: Tetrahydroisoquinoline-Based N-Oxides as Chiral Organocatalysts for the Asymmetric Allylation of Aldehydes. Eur J Org 2011, 2011, 6923. <http://dx.doi.org/10.1002/ejoc.201100923>
  • Chelucci Giorgio, Marchetti Mauro, Malkov Andrei V., Friscourt Frédéric, Swarbrick Martin E., Kočovský Pavel: New monoterpene-derived phosphinopyridine ligands and their application in the enantioselective iridium-catalyzed hydrogenation. Tetrahedron 2011, 67, 5421. <http://dx.doi.org/10.1016/j.tet.2011.05.075>
  • Malkov Andrei V., Barłóg Maciej, Jewkes Yvonne, Mikušek Jiří, Kočovský Pavel: Enantioselective Allylation of α,β-Unsaturated Aldehydes with Allyltrichlorosilane Catalyzed by METHOX. J Org Chem 2011, 76, 4800. <http://dx.doi.org/10.1021/jo200712p>
  • Štambaský Jan, Kapras Vojtěch, Štefko Martin, Kysilka Ondřej, Hocek Michal, Malkov Andrei V., Kočovský Pavel: A Modular Approach to Aryl-C-ribonucleosides via the Allylic Substitution and Ring-Closing Metathesis Sequence. A Stereocontrolled Synthesis of All Four α-/β- and d-/l-C-Nucleoside Stereoisomers. J Org Chern 2011, 76, 7781. <http://dx.doi.org/10.1021/jo201110z>
  • Kocovsky Pavel, Malkov Andrei V.: ChemInform Abstract: Asymmetric Synthesis: From Transition Metals to Organocatalysis. ChemInform 2008, 39. <http://dx.doi.org/10.1002/chin.200843246>