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Pure Appl. Chem., 2007, Vol. 79, No. 8, pp. 1463-1469

http://dx.doi.org/10.1351/pac200779081463

POLYMER DIVISION
SUBCOMMITTEE ON MODELING OF POLYMERIZATION KINETICS AND PROCESSES

Critically evaluated rate coefficients for free-radical polymerization Part 6: Propagation rate coefficient of methacrylic acid in aqueous solution (IUPAC Technical Report)

Sabine Beuermann1, Michael Buback1, Pascal Hesse1, Frank-Dieter Kuchta2, Igor Lacík3 and Alex M. van Herk2

1 Institute of Physical Chemistry, Georg-August-Universität Göttingen, Tammannstrasse 6, D-37077, Göttingen, Germany
2 Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands
3 Polymer Institute of the Slovak Academy of Sciences, Dúbravská cesta 9, 842 36 Bratislava, Slovak Republic

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  • Haehnel Alexander P., Stach Marek, Chovancová Anna, Rueb Jannick M., Delaittre Guillaume, Misske Andrea M., Lacík Igor, Barner-Kowollik Christopher: (Meth)acrylic monomers with heteroatom-containing ester side chains: a systematic PLP-SEC and polymerization study. Polym. Chem. 2014, 5, 862. <http://dx.doi.org/10.1039/c3py00948c>
  • Schrooten Jens, Lacík Igor, Stach Marek, Hesse Pascal, Buback Michael: Propagation Kinetics of the Radical Polymerization of Methylated Acrylamides in Aqueous Solution. Macromol. Chem. Phys. 2013, 214, 2283. <http://dx.doi.org/10.1002/macp.201300357>
  • Degirmenci Isa., Ozaltın Tugba Furuncuoglu, Karahan Ozlem, Van Speybroeck Veronique, Waroquier Michel., Aviyente Viktorya: Origins of the solvent effect on the propagation kinetics of acrylic acid and methacrylic acid. J. Polym. Sci. A Polym. Chem. 2013, 51, 2024. <http://dx.doi.org/10.1002/pola.26589>
  • Moon Jiyeon, Chung Kyungho, Park Moonsoo: Preparation of Monodisperse Poly(Methacrylic acid) with a Water-Soluble Initiator by Solution Polymerization in the Aqueous Phase. Elastomers and Composites 2013, 48, 294. <http://dx.doi.org/10.7473/EC.2013.48.4.294>
  • Wittenberg Nils F. G., Buback Michael, Stach Marek, Lacík Igor: Chain Transfer to 2-Mercaptoethanol in Methacrylic Acid Polymerization in Aqueous Solution. Macromol. Chem. Phys. 2012, 213, 2653. <http://dx.doi.org/10.1002/macp.201200484>
  • Schrooten Jens, Buback Michael, Hesse Pascal, Hutchinson Robin A., Lacík Igor: Termination Kinetics of 1-Vinylpyrrolidin-2-one Radical Polymerization in Aqueous Solution. Macromol Chem Phys 2011, 212, 1400. <http://dx.doi.org/10.1002/macp.201100021>
  • Liang Kun, Hutchinson Robin A.: The Effect of Hydrogen Bonding on Intramolecular Chain Transfer in Polymerization of Acrylates. Macromol Rapid Commun 2011, 32, 1090. <http://dx.doi.org/10.1002/marc.201100224>
  • Gonçalves Miguel A. D., Pinto Virgínia D., Dias Rolando C. S., Costa Mário Rui P. F. N.: Modeling Studies on the Synthesis of Superabsorbent Hydrogels Using Population Balance Equations. Makromol Symp 2011, 306-307, 107. <http://dx.doi.org/10.1002/masy.201000151>
  • Jeličić Aleksandra, Yasin Muttaqin, Beuermann Sabine: Toward the Description and Prediction of Solvent Induced Variations in Methacrylate Propagation Rate Coefficients on the Basis of Solvatochromic Parameters. Macromol React Eng 2011, 5, 232. <http://dx.doi.org/10.1002/mren.201000058>
  • Reyes Yuri, Arzamendi Gurutze, Asua José M., Leiza Jose R.: Branching at High Frequency Pulsed Laser Polymerizations of Acrylate Monomers. Macromol 2011, 44, 3674. <http://dx.doi.org/10.1021/ma200389h>
  • Siegmann Rebekka, Jeličić Aleksandra, Beuermann Sabine: Propagation and Termination Kinetics of PEGylated Methacrylate Radical Polymerizations. Macromol Chem Phys 2010, 211, 546. <http://dx.doi.org/10.1002/macp.200900527>
  • Stach Marek, Lacík Igor, Kasák Peter, Chorvát Dušan, Saunders Alan J., Santanakrishnan Sandhya, Hutchinson Robin A.: Free-Radical Propagation Kinetics of N-Vinyl Formamide in Aqueous Solution Studied by PLP-SEC. Macromol Chem Phys 2010, 211, 580. <http://dx.doi.org/10.1002/macp.200900545>
  • Erdmenger Tina, Guerrero-Sanchez Carlos, Vitz Juergen, Hoogenboom Richard, Schubert Ulrich S.: Recent developments in the utilization of green solvents in polymer chemistry. Chem Soc Rev 2010, 39, 3317. <http://dx.doi.org/10.1039/b909964f>
  • Barner-Kowollik Christopher, Bennet Francesca, Schneider-Baumann Maria, Voll Dominik, Rölle Thomas, Fäcke Thomas, Weiser Marc-Stephan, Bruder Friedrich-Karl, Junkers Thomas: Detailed investigation of the propagation rate of urethane acrylates. Polym Chem 2010, 1, 470. <http://dx.doi.org/10.1039/b9py00352e>
  • Beuermann Sabine: Solvent Influence on Propagation Kinetics in Radical Polymerizations Studied by Pulsed Laser Initiated Polymerizations. Macromol Rapid Commun 2009, 30, 1066. <http://dx.doi.org/10.1002/marc.200900131>
  • Coote Michelle L.: Quantum-Chemical Modeling of Free-Radical Polymerization. Macromol Theory Simul 2009, 18, 388. <http://dx.doi.org/10.1002/mats.200900050>
  • Rinaldi David, Hamaide Thierry, Graillat Christian, D'Agosto Franck, Spitz Roger, Georges Sébastien, Mosquet Martin, Maitrasse Philippe: RAFT copolymerization of methacrylic acid and poly(ethylene glycol) methyl ether methacrylate in the presence of a hydrophobic chain transfer agent in organic solution and in water. J Polym Sci A Polym Chem 2009, 47, 3045. <http://dx.doi.org/10.1002/pola.23374>
  • Dervaux Bart, Junkers Thomas, Schneider-Baumann Maria, Du Prez Filip E., Barner-Kowollik Christopher: Propagation rate coefficients of isobornyl acrylate, tert-butyl acrylate and 1-ethoxyethyl acrylate: A high frequency PLP-SEC study. J Polym Sci A Polym Chem 2009, 47, 6641. <http://dx.doi.org/10.1002/pola.23706>
  • Kreft Tomasz, Reed Wayne F.: Predictive control and verification of conversion kinetics and polymer molecular weight in semi-batch free radical homopolymer reactions. Euro Poly J 2009, 45, 2288. <http://dx.doi.org/10.1016/j.eurpolymj.2009.05.006>
  • Barner-Kowollik Christopher, Russell Gregory T.: Chain-length-dependent termination in radical polymerization: Subtle revolution in tackling a long-standing challenge. Prog Polym Sci 2009, 34, 1211. <http://dx.doi.org/10.1016/j.progpolymsci.2009.07.002>
  • Kreft Tomasz, Reed Wayne F.: Direct Monitoring of the Cross-Over from Diffusion-Controlled to Decomposition-Controlled Initiation in Free Radical Polymerization. Macromol Chem Phys 2008, 209, 2463. <http://dx.doi.org/10.1002/macp.200800435>
  • Buback Michael, Hesse Pascal, Lacík Igor: Propagation Rate Coefficient and Fraction of Mid-Chain Radicals for Acrylic Acid Polymerization in Aqueous Solution. Macromol Rapid Commun 2007, 28, 2049. <http://dx.doi.org/10.1002/marc.200700396>