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Pure Appl. Chem., 2006, Vol. 78, No. 2, pp. 457-462

Cycloruthenated compounds as efficient catalyst for asymmetric hydride transfer reaction

Jean-Baptiste Sortais1, Laurent Barloy1, Claude Sirlin1, André H. M. de Vries2, Johannes G. de Vries2 and Michel Pfeffer1

1 CNRS, UMR 7177, Laboratoire de Synthèses Métallo-Induites, Université Louis Pasteur, 4, rue Blaise Pascal, 67000 Strasbourg, France
2 DSM Pharmaceutical Chemicals, Advanced Synthesis, Catalysis, and Development, P.O. Box 18, 6160 MD Geleen, The Netherlands

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  • Djukic Jean-Pierre, Iali Wissam, Pfeffer Michel, Le Goff Xavier-Frédéric: Synthesis of Planar Chiral Iridacycles by Cationic Metal π-Coordination: Facial Selectivity, and Conformational and Stereochemical Consequences. Chemistry A European Journal 2012, 18, 6063. <>
  • Chang Xu, Chuan Low Wei, Yongxin Li, Pullarkat Sumod A.: One-pot β-alkylation of secondary alcohols with primary alcohols catalyzed by ruthenacycles. Tetrahedron Letters 2012, 53, 1450. <>
  • O Wylie W. N., Lough Alan J., Morris Robert H.: Bifunctional Mechanism with Unconventional Intermediates for the Hydrogenation of Ketones Catalyzed by an Iridium(III) Complex Containing an N-Heterocyclic Carbene with a Primary Amine Donor. Organomettalics 2012, 31, 2152. <>
  • O Wylie W. N., Lough Alan J., Morris Robert H.: Factors Favoring Efficient Bifunctional Catalysis. Study of a Ruthenium(II) Hydrogenation Catalyst Containing an N-Heterocyclic Carbene with a Primary Amine Donor. Organomettalics 2012, 31, 2137. <>
  • Pannetier Nicolas, Sortais Jean-Baptiste, Issenhuth Jean-Thomas, Barloy Laurent, Sirlin Claude, Holuigue Alexandre, Lefort Laurent, Panella Lavinia, de Vries Johannes G., Pfeffer Michel: Cyclometalated Complexes of Ruthenium, Rhodium and Iridium as Catalysts for Transfer Hydrogenation of Ketones and Imines. Synth Catal 2011, 353, 2844. <>
  • Parkhomenko Ksenia, Barloy Laurent, Sortais Jean-Baptiste, Djukic Jean-Pierre, Pfeffer Michel: Cycloruthenated complexes as homogeneous catalysts for atom-transfer radical additions. Tetrahetron Lett 2010, 51, 822. <>
  • Jerphagnon Thomas, Gayet Arnaud J. A., Berthiol Florian, Ritleng Vincent, Mršić Nataša, Meetsma Auke, Pfeffer Michel, Minnaard Adriaan J., Feringa Ben L., de Vries Johannes G.: Fast Racemisation of Chiral Amines and Alcohols by Using Cationic Half-Sandwich Ruthena- and Iridacycle Catalysts. Chem Eur J 2009, 15, 12780. <>
  • Djukic Jean-Pierre, Sortais Jean-Baptiste, Barloy Laurent, Pfeffer Michel: Cycloruthenated Compounds - Synthesis and Applications. Eur J Inorg Chem 2009, 2009, 817. <>
  • Djukic Jean-Pierre, Hijazi Akram, Flack Howard D., Bernardinelli Gérald: Non-racemic (scalemic) planar-chiral five-membered metallacycles: routes, means, and pitfalls in their synthesis and characterization. Chem Soc Rev 2008, 37, 406. <>
  • Sortais Jean-Baptiste, Brelot Lydia, Pfeffer Michel, Barloy Laurent: μ3-Carbonato-κ3 O:O′:O′′-tris{(η6-benzene)[(R)-1-(1-aminoethyl)naphthyl-κ2 C 2,N]ruthenium(II)} hexafluoridophosphate dichloromethane solvate. Acta Crystallogr E Struct Rep Online 2008, 64, m483. <>
  • Sortais Jean-Baptiste, Barloy Laurent, Sirlin Claude, de Vries Andre H. M., de Vries Johannes G., Pfeffer Michel: Cycloruthenated Compounds as Efficient Catalyst for Asymmetric Hydride Transfer Reaction. ChemInform 2006, 37. <>