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Pure Appl. Chem., 2006, Vol. 78, No. 2, pp. 425-434

Indium-catalyzed addition of carbon units to acetylenes: Development of a new C-C bond formation toward exploitation of chemical resources

Masaharu Nakamura

Department of Chemistry, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan

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  • Shen Zhi-Liang, Wang Shun-Yi, Chok Yew-Keong, Xu Yun-He, Loh Teck-Peng: Organoindium Reagents: The Preparation and Application in Organic Synthesis. Chem. Rev. 2013, 113, 271. <>
  • Kim Ju Hyun, Chun Yu Sung, Lee Sang-gi: Tandem Blaise/retro-Blaise Reaction for the Nitrile-Mediated Regioselective Intermolecular Addition of Unstabilized Zinc Ester Enolates (Reformatsky Reagents) to 1-Alkynes and 1,3-Enynes. J. Org. Chem. 2013, 78, 11483. <>
  • Surendra Karavadhi, Qiu Wenwei, Corey E. J.: A Powerful New Construction of Complex Chiral Polycycles by an Indium(III)-Catalyzed Cationic Cascade. J Am Chem Soc 2011, 133, 9724. <>
  • Qiu Wen-Wei, Surendra Karavadhi, Yin Liang, Corey E. J.: Selective Formation of Six-Membered Oxa- and Carbocycles by the In(III)-Activated Ring Closure of Acetylenic Substrates. Org Lett 2011, 13, 5893. <>
  • Tsuchimoto Teruhisa: Development of New Catalytic Reactions Based on Activation of Hydrocarbon Functional Groups by Lewis Acids. J Syn Org Chem Jpn 2011, 69, 889. <>
  • Sun Hong-Bin, Li Biao, Chen Songjie, Li Jie, Hua Ruimao: An efficient synthesis of unsymmetrical diarylmethanes from the dehydration of arenes with benzyl alcohols using InCl3·4H2O/acetylacetone catalyst system. Tetrahedron 2007, 63, 10185. <>
  • Nakamura Masaharu: Indium-Catalyzed Addition of Carbon Units to Acetylenes: Development of a New C—C Bond Formation Toward Exploitation of Chemical Resources. ChemInform 2006, 37. <>