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Pure Appl. Chem., 2006, Vol. 78, No. 10, pp. 1867-1876

Unexpected and intriguing reactivity of α-imino esters and iminium salts

Makoto Shimizu

Department of Chemistry for Materials, Mie University, Tsu, Mie 514-8507, Japan

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  • Tanaka Hirotaka, Mizota Isao, Shimizu Makoto: Tandem N-Alkylation/Vinylogous Aldol Reaction of β,γ-Alkenyl α-Iminoester. Org. Lett. 2014, 140410091834008. <>
  • Shimizu Makoto, Takao Yuki, Katsurayama Haruna, Mizota Isao: Synthesis of Indolin-3-ones and Tetrahydro-4-quinolones from α-Imino Esters. Asian Journal of Organic Chemistry 2013, 2, 130. <>
  • Shimizu Makoto, Kurita Daiji, Mizota Isao: Highly Diastereoselective Tandem N -Alkylation-Mannich Reaction of α-Imino Esters. Asian Journal of Organic Chemistry 2013, 2, 208. <>
  • Mizota Isao, Matsuda Yuri, Kamimura Satoshi, Tanaka Hirotaka, Shimizu Makoto: Regioselective Tandem N-Alkylation/C-Acylation of β,γ-Alkynyl α-Imino Esters. Org. Lett. 2013, 15, 4206. <>
  • Mizota Isao, Tanaka Katsuki, Shimizu Makoto: Synthesis of γ,δ-unsaturated quaternary α-alkylamino acids using umpolung reaction and Claisen rearrangement. Tetrahedron Letters 2012, 53, 1847. <>
  • Nishi Takafumi, Mizota Isao, Shimizu Makoto: Integrated reactions using addition to conjugated imines and iminium salts. Pure Appl. Chem. 2012, 1. <>
  • Shimizu Makoto, Kawanishi Mami, Itoh Akinori, Mizota Isao, Hachiya Iwao: Double Nucleophilic Addition to Acrolein with Ketene Silyl Acetals and Allylborolanes Catalyzed by Proline. Chem Lett (Japan) 2011, 40, 862. <>
  • Hata Shingo, Shimizu Makoto: Integrated Reactions Using Addition to Conjugated Imines and Iminium Salts. J Syn Org Chem Jpn 2011, 69, 1134. <>
  • Shimizu Makoto, Itou Hiroyuki, Iwao Takuya, Umeda Yuki: Ene Reaction Using the Iminium Salt Generated by the Oxidation of Aminoketene Silyl Aetal. Chem Lett 2009, 38, 732. <>
  • Shimizu Makoto, Iwao Takuya: Friedel-Crafts Reaction of Indole Derivatives Using the Iminium Salt Generated by the Oxidation of Amino Ketene Silyl Acetal. HETEROCYCLES 2009, 77, 767. <>
  • Dickstein Joshua S., Kozlowski Marisa C.: Organometal additions to α-iminoesters: N-alkylation via umpolung. Chem Soc Rev 2008, 37, 1166. <>