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Pure Appl. Chem., 2005, Vol. 77, No. 7, pp. 1153-1160

Total synthesis and structural elucidation of natural products: (–)-Delactonmycin, (+)‑plumerinine, and (–)-parvistemoamide

Ronaldo A. Pilli, Ivan R. Corrêa, Adriano O. Maldaner and Giovanni B. Rosso

Instituto de Química, Unicamp P.O. Box 6154, 13084-971, Campinas, SP Brazil

Abstract: Synthetic studies that established the relative configuration of (–)-delactonmycin, a polyketide with inhibitory activity against HIV-1 Rev protein, and our efforts toward the structural elucidation of the alkaloids (+)-plumerinine, isolated from P. rubra, and (–)-parvistemoamide, isolated from S. parviflora, are discussed.