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Pure Appl. Chem., 2005, Vol. 77, No. 11, pp. 1823-1833

http://dx.doi.org/10.1351/pac200577111823

Is the single transition-state model appropriate for the fundamental reactions of organic chemistry?

Vernon D. Parker

Department of Chemistry and Biochemistry, Utah State University, Logan, UT 84322-0300, USA

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  • Parker Vernon D., Kar Tapas, Bethell Donald: The Polar Mechanism for the Nitration of Benzene with Nitronium Ion: Ab Initio Structures of Intermediates and Transition States. J. Org. Chem. 2013, 78, 9522. <http://dx.doi.org/10.1021/jo401775u>
  • Han Xiaozhen, Hao Weifang, Zhu Xiao-Qing, Parker Vernon D.: A Thermodynamic and Kinetic Study of Hydride Transfer of a Caffeine Derivative. J. Org. Chem. 2012, 77, 6520. <http://dx.doi.org/10.1021/jo301042d>
  • Hao Weifang, Parker Vernon D.: Oxygen-Initiated Chain Mechanism for Hydride Transfer Between NADH and NAD+ Models. Reaction of 1-Benzyl-3-Cyanoquinolinium Ion with N-Methyl-9,10-Dihydroacridine in Acetonitrile. J. Org. Chem. 2012, 77, 9286. <http://dx.doi.org/10.1021/jo301874q>
  • Li Zhao, Cheng Jin-Pei, Parker Vernon D.: Reactions of the simple nitroalkanes with hydroxide ion in water. Evidence for a complex mechanism. Biomol Chem 2011, 9, 4563. <http://dx.doi.org/10.1039/c1ob05270e>
  • Perrin Charles L., Zhao Chen: Intramolecular kinetic isotope effect in hydride transfer from dihydroacridine to a quinolinium ion. Rejection of a proposed two-step mechanism with a kinetically significant intermediate. Org Biomol Chem 2008, 6, 3349. <http://dx.doi.org/10.1039/b806869k>
  • Parker Vernon D.: Instantaneous rate constants in physical organic chemistry: application to acyl transfer reactions ofp-nitrophenyl acetate to hydroxide ion. J Phys Org Chem 2006, 19, 714. <http://dx.doi.org/10.1002/poc.1064>