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Pure Appl. Chem., 2004, Vol. 76, No. 3, pp. 477-494

Synthetic applications of planar chiral cationic η3-allylmolybdenum complexes

P. Kocienski, Richard Bell, Elyse Bourque, J. A. Christopher, John Cooksey, Andrew Gunn, Alexander Kuhl, Y. Li, S. Uppal and Josephine Yuen

Department of Chemistry, Leeds University, Leeds LS2 9JT, UK; Department of Chemistry, Glasgow University, Glasgow G12 8QQ, UK; GlaxoSmithKline Research and Development, Medicines Research Centre, Stevenage, Hertfordshire SG1 2NY, UK

Abstract: The synthesis of planar chiral η3-allylmolybdenum complexes is described together with some examples of the nucleophilic addition of organocopper(I) reagents.