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Pure Appl. Chem., 2003, Vol. 75, No. 9, pp. 1305-1313

http://dx.doi.org/10.1351/pac200375091305

Boron clusters: Do they receive the deserved interest?

Francesc Teixidor, Clara Viñas, Albert Demonceau and Rosario Nuñez

Institut de Ciència de Materials de Barcelona (CSIC), Campus U.A.B., E-08193 Bellaterra, Spain

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  • Matějíček Pavel, Uchman Mariusz, Lepšík Martin, Srnec Martin, Zedník Jiří, Kozlík Petr, Kalíková Květa: Preparation and Separation of Telechelic Carborane-Containing Poly(ethylene glycol)s. ChemPlusChem 2013, 78, 528. <http://dx.doi.org/10.1002/cplu.201300046>
  • Loginov Dmitry A., Starikova Zoya A., Corsini Maddalena, Zanello Piero, Kudinov Alexander R.: (Cyclopentadienyl)metalladicarbollides 3-(η-C5R5)-3,1,2-MC2B9H11 (M = Co, Rh, Ir): Synthesis, electrochemistry, and bonding. Journal of Organometallic Chemistry 2013, 747, 69. <http://dx.doi.org/10.1016/j.jorganchem.2012.12.021>
  • Nie Yong, Miao Jinling, Pritzkow Hans, Wadepohl Hubert, Siebert Walter: Weak intramolecular C–H⋯H–B and C–H⋯Cl interactions in C-aminoboryl-o-carboranes. Journal of Organometallic Chemistry 2013, 747, 174. <http://dx.doi.org/10.1016/j.jorganchem.2013.03.016>
  • Ol’shevskaya Valentina A., Makarenkov Anton V., Kononova Elena G., Petrovskii Pavel V., Grigoriev Mikhail S., Kalinin Valery N.: Use of carborane carboxylic acids in the synthesis of boronated nitrogen heterocycles. Polyhedron 2013, 51, 235. <http://dx.doi.org/10.1016/j.poly.2012.12.035>
  • Wütz Tobias, Fleischhauer Sebastian, Wesemann Lars: B–N bond formation at stanna-closo-dodecaborate. Dalton Trans. 2013, 42, 753. <http://dx.doi.org/10.1039/c2dt31749d>
  • Juárez-Pérez Emilio José, Granier Michel, Viñas Clara, Mutin P. Hubert, Núñez Rosario: Grafting of Metallacarboranes onto Self-Assembled Monolayers Deposited on Silicon Wafers. Chem —Asian J 2012, 7, 277. <http://dx.doi.org/10.1002/asia.201100750>
  • Ferrer-Ugalde Albert, Juárez-Pérez Emilio José, Teixidor Francesc, Viñas Clara, Sillanpää Reijo, Pérez-Inestrosa Ezequiel, Núñez Rosario: Synthesis and Characterization of New Fluorescent Styrene-Containing Carborane Derivatives: The Singular Quenching Role of a Phenyl Substituent. Chemistry A European Journal 2012, 18, 544. <http://dx.doi.org/10.1002/chem.201101881>
  • Popescu Adrian-Radu, Musteti Ana Daniela, Ferrer-Ugalde Albert, Viñas Clara, Núñez Rosario, Teixidor Francesc: Influential Role of Ethereal Solvent on Organolithium Compounds: The Case of Carboranyllithium. Chem. Eur. J. 2012, 18, 3174. <http://dx.doi.org/10.1002/chem.201102626>
  • Yinghuai Zhu, Shiwei Xiao, Vangala Venu R., Chia Sze Chen, Cheong Angie, Qin Ong Nuan, Hosmane Narayan S.: Carboranylimine-complexed titanium (IV) organometallics: An investigation of synthesis, structure and catalytic polymerization. Journal of Organometallic Chemistry 2012, 721-722, 119. <http://dx.doi.org/10.1016/j.jorganchem.2012.07.010>
  • Di Salvo Florencia, Teixidor Francesc, Viñas Clara, Planas José Giner, Light Mark E., Hursthouse Michael B., Aliaga-Alcalde Núria: Metallosupramolecular Chemistry of Novel Chiral closo-o-Carboranylalcohol Pyridine and Quinoline Ligands: Syntheses, Characterization, and Properties of Cobalt Complexes. Crystal Growth & Design 2012, 12, 5720. <http://dx.doi.org/10.1021/cg301249a>
  • Cioran Ana M., Musteti Ana D., Teixidor Francesc, Krpetić Željka, Prior Ian A., He Qian, Kiely Christopher J., Brust Mathias, Viñas Clara: Mercaptocarborane-Capped Gold Nanoparticles: Electron Pools and Ion Traps with Switchable Hydrophilicity. S J Am Chem Soc 2012, 134, 212. <http://dx.doi.org/10.1021/ja203367h>
  • Plešek Jaromír, Grüner Bohumír, Šícha Václav, Bőhmer Volker, Císařová Ivana: The Zwitterion [8,8′-μ-CH2O(CH3)-(1,2-C2B9H10)2-3,3′-Co]0 as a Versatile Building Block To Introduce Cobalt Bis(Dicarbollide) Ion into Organic Molecules. Organomettalics 2012, 31, 1703. <http://dx.doi.org/10.1021/om200938n>
  • Dash Barada Prasanna, Satapathy Rashmirekha, Bode Barrie P., Reidl Cory T., Sawicki James W., Mason Allen J., Maguire John A., Hosmane Narayan S.: “Click” Chemistry-Mediated Phenylene-Cored Carborane Dendrimers. Organomettalics 2012, 31, 2931. <http://dx.doi.org/10.1021/om201255b>
  • Dimmer Jörg-Alexander, Hornung Martin, Wütz Tobias, Wesemann Lars: Germa- and Stanna-closo-dodecaborate in Reaction with [PdCl2(Xantphos)]: P–C and B–H Bond Activation. Organometallics 2012, 31, 7044. <http://dx.doi.org/10.1021/om300438x>
  • Wrackmeyer Bernd, Klimkina Elena V., Milius Wolfgang, Bauer Tobias, Kempe Rhett: Synthesis and Reactivity of 4,5-[1,2-Dicarba-closo-dodecaborano(12)]-1,3-diselenacyclopentane: Opening of the Icosahedron to Give a Zwitterionic Intermediate and Conversion into 7,8-Dicarba-nido-undecaborate(1−). Chem Eur J 2011, 17, 3238. <http://dx.doi.org/10.1002/chem.201002277>
  • Fontanet Mònica, Popescu Adrian-Radu, Fontrodona Xavier, Rodríguez Montserrat, Romero Isabel, Teixidor Francesc, Viñas Clara, Aliaga-Alcalde Núria, Ruiz Eliseo: Design of Dinuclear Copper Species with Carboranylcarboxylate Ligands: Study of Their Steric and Electronic Effects. Chemistry A European Journal 2011, 17, 13217. <http://dx.doi.org/10.1002/chem.201101929>
  • Horáková Hana, Grüner Bohumír, Vespalec Radim: Emerging subject for chiral separation science: Cluster boron compounds. Chirality 2011, 23, 307. <http://dx.doi.org/10.1002/chir.20918>
  • Alekseev Leonid S., Lyubimov Sergey E., Dolgushin Fedor M., Novikov Valentin V., Davankov Vadim A., Chizhevsky Igor T.: New Rhodacarborane−Phosphoramidite Catalyst System for Enantioselective Hydrogenation of Functionalized Olefins and Molecular Structure of the Chiral Catalyst Precursor [3,3-{(S)-PipPhos}2-3-H-1,2-(o-xylylene)-closo-3,1,2-RhC2B9H9]. Organomet 2011, 30, 1942. <http://dx.doi.org/10.1021/om101201e>
  • Pieters Grégory, Gaucher Anne, Prim Damien, Besson Thierry, Giner Planas José, Teixidor Francesc, Viñas Clara, Light Mark E., Hursthouse Michael B.: Binaphthyl platform as starting materials for the preparation of electron rich benzo[g,h,i]perylenes. Application to molecular architectures based on amino benzo[g,h,i]perylenes and carborane combinations. Chem Commun 2011, 47, 7725. <http://dx.doi.org/10.1039/c1cc12099a>
  • Lerouge Frédéric, Ferrer-Ugalde Albert, Viñas Clara, Teixidor Francesc, Sillanpää Reijo, Abreu Arturo, Xochitiotzi Elba, Farfán Norberto, Santillan Rosa, Núñez Rosario: Synthesis and fluorescence emission of neutral and anionic di- and tetra-carboranyl compounds. Dalton Trans 2011, 40, 7541. <http://dx.doi.org/10.1039/c1dt10309a>
  • Dash Barada Prasanna, Satapathy Rashmirekha, Maguire John A., Hosmane Narayan S.: Polyhedral boron clusters in materials science. NJC 2011, 35, 1955. <http://dx.doi.org/10.1039/c1nj20228f>
  • Wrackmeyer Bernd, Klimkina Elena V., Milius Wolfgang: Synthesis, molecular structure and reactivity of the dimethyl sulfide adduct of a 1,3,2-diselenaborolane with an annelated dicarba-closo-dodecaborane(12) unit. J Polyhedron 2010, 29, 2324. <http://dx.doi.org/10.1016/j.poly.2010.04.032>
  • Dash Barada Prasanna, Satapathy Rashmirekha, Gaillard Elizabeth R., Maguire John A., Hosmane Narayan S.: Synthesis and Properties of Carborane-Appended C3-Symmetrical Extended π Systems. J Am Chem Soc 2010, 132, 6578. <http://dx.doi.org/10.1021/ja101845m>
  • Wrackmeyer Bernd, Klimkina Elena V., Milius Wolfgang: Synthesis and reactivity of some diselenasila cycles containing an annelated dicarba-closo-dodecaborane(12) unit. Appl Organometal Chem 2009, n/a. <http://dx.doi.org/10.1002/aoc.1582>
  • Teixidor Francesc, Sillanpää Reijo, Kivekäs Raikko, Arca Massimiliano, Puga Alberto V., Barberà Gemma, Viñas Clara: From Mono- to Poly-Substituted Frameworks: A Way of Tuning the Acidic Character of CcH in o-Carborane Derivatives. Chem Eur J 2009, 15, 9755. <http://dx.doi.org/10.1002/chem.200900925>
  • Lesnikowski Zbigniew J.: Nucleoside–boron cluster conjugates – Beyond pyrimidine nucleosides and carboranes. J Organomet Chem 2009, 694, 1771. <http://dx.doi.org/10.1016/j.jorganchem.2008.12.061>
  • Prasanna Dash Barada, Satapathy Rashmirekha, Maguire John A., Hosmane Narayan S.: Boron-enriched star-shaped molecule via cycloaddition reaction. Chem Commun 2009, 3267. <http://dx.doi.org/10.1039/b905076k>
  • Valeri Anna Lucia, Kremser Leopold, Raggi Maria Augusta, Grüner Bohumir, Vespalec Radim, Kenndler Ernst: Capillary electrophoresis of boron cluster compounds in aqueous and nonaqueous solvents. Eletrophoresis 2008, 29, 1658. <http://dx.doi.org/10.1002/elps.200700815>
  • Semioshkin Andrey A., Sivaev Igor B., Bregadze Vladimir I.: Cyclic oxonium derivatives of polyhedral boron hydrides and their synthetic applications. Dalton Trans 2008, 977. <http://dx.doi.org/10.1039/b715363e>
  • Vespalec Radim, Horáková Hana: Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water–methanol background electrolytes. Eletrophoresis 2007, 28, 3639. <http://dx.doi.org/10.1002/elps.200600814>
  • Lesnikowski Zbigniew J.: Boron Units as Pharmacophores - New Applications and Opportunities of Boron Cluster Chemistry. Collect Czech Chem Commun 2007, 72, 1646. <http://dx.doi.org/10.1135/cccc20071646>
  • Oliva Josep M., Serrano-Andrés Luis: A computational study of the lowest singlet and triplet states of neutral and dianionic 1,2-substituted icosahedral and octahedral o-carboranes. J Comput Chem 2006, 27, 524. <http://dx.doi.org/10.1002/jcc.20359>
  • Batsanov Andrei S., Clegg William, Copley Royston C.B., Fox Mark A., Gill Wendy R., Grimditch Rachel S., Hibbert Thomas G., Howard Judith A.K., MacBride J.A. Hugh, Wade Kenneth: Preparative and structural studies on sulfur-linked carborane icosahedra: 2-Phenyl-ortho-carboranyl-sulfur systems (2-Ph-1,2-C2B10H10)2X (X=S, S2 or SO), and ortho-carboran-di-yl systems (1,2-C2B10H10Y)2 (Y=S or SO). J Polyhedron 2006, 25, 300. <http://dx.doi.org/10.1016/j.poly.2005.06.046>
  • Tutusaus Oscar, Delfosse Sébastien, Demonceau Albert, Noels Alfred F, Viñas Clara, Teixidor Francesc: Kharasch addition catalysed by half-sandwich ruthenium complexes. Enhanced activity of ruthenacarboranes. Tetrahetron Lett 2003, 44, 8421. <http://dx.doi.org/10.1016/j.tetlet.2003.09.100>