CrossRef enabled

PAC Archives

Archive →

Pure Appl. Chem., 2003, Vol. 75, No. 9, pp. 1183-1195

http://dx.doi.org/10.1351/pac200375091183

Role of B(C6F5)3 in catalyst activation, anion formation, and as C6F5 transfer agent

Manfred Bochmann, Simon J. Lancaster, Mark D. Hannant, Antonio Rodriguez, Mark Schormann, Dennis A. Walker and Timothy J. Woodman

Wolfson Materials and Catalysis Centre, School of Chemical Sciences, University of East Anglia, Norwich NR4 7TJ, UK

CrossRef Cited-by theme picture

CrossRef Cited-by Linking

  • Hounjet Lindsay J., Bannwarth Christoph, Garon Christian N., Caputo Christopher B., Grimme Stefan, Stephan Douglas W.: Combinations of Ethers and B(C 6 F 5 ) 3 Function as Hydrogenation Catalysts. Angew. Chem. 2013, 125, 7640. <http://dx.doi.org/10.1002/ange.201303166>
  • Hounjet Lindsay J., Bannwarth Christoph, Garon Christian N., Caputo Christopher B., Grimme Stefan, Stephan Douglas W.: Combinations of Ethers and B(C 6 F 5 ) 3 Function as Hydrogenation Catalysts. Angew. Chem. Int. Ed. 2013, 52, 7492. <http://dx.doi.org/10.1002/anie.201303166>
  • Qu Zheng-Wang, Zhu Hui: Toward Reversible Dihydrogen Activation by Borole Compounds. J. Phys. Chem. C 2013, 117, 11989. <http://dx.doi.org/10.1021/jp403029c>
  • Strašák Tomáš, Sýkora Jan, Lamač Martin, Kubišta Jiří, Horáček Michal, Gyepes Róbert, Pinkas Jiří: Reactivity of a Titanocene Pendant Si–H Group toward Alcohols. Unexpected Formation of Siloxanes from the Reaction of Hydrosilanes and Ph3COH Catalyzed by B(C6F5)3. Organometallics 2013, 32, 4122. <http://dx.doi.org/10.1021/om400253g>
  • Lawrence Elliot J., Oganesyan Vasily S., Wildgoose Gregory G., Ashley Andrew E.: Exploring the fate of the tris(pentafluorophenyl)borane radical anion in weakly coordinating solvents. Dalton Trans. 2013, 42, 782. <http://dx.doi.org/10.1039/c2dt31622f>
  • Fuller Anna-Marie, Hughes David L., Kostakis George E., Lancaster Simon J., Powell Annie K.: The supramolecular architecture of the second coordination sphere complex between the ammonia adduct of tris(pentafluorophenyl)borane and pyrimidine: Two interpenetrating chiral (10,3)-a (srs) nets assembled through hydrogen bonding. Inorganica Chimica Acta 2011, 366, 380. <http://dx.doi.org/10.1016/j.ica.2010.10.022>
  • Merle Nicolas, Törnroos Karl W., Jensen Vidar R., Le Roux Erwan: Influence of multidentate N-donor ligands on highly electrophilic zinc initiator for the ring-opening polymerization of epoxides. J Organomet Chem 2011, 696, 1691. <http://dx.doi.org/10.1016/j.jorganchem.2011.02.015>
  • Ashley Andrew E., Herrington Thomas J., Wildgoose Gregory G., Zaher Hasna, Thompson Amber L., Rees Nicholas H., Krämer Tobias, O’Hare Dermot: Separating Electrophilicity and Lewis Acidity: The Synthesis, Characterization, and Electrochemistry of the Electron Deficient Tris(aryl)boranes B(C6F5)3–n(C6Cl5)n (n = 1–3). J Ann Chem Soc 2011, 133, 14727. <http://dx.doi.org/10.1021/ja205037t>
  • Pang Keliang, Rong Yi, Parkin Gerard: Molecular structures of three coordinate zinc and cadmium complexes that feature β-diketiminato and anilido-imine ligands. J Polyhedron 2010, 29, 1881. <http://dx.doi.org/10.1016/j.poly.2010.02.020>
  • Martin Eddy, Hughes David L., Hursthouse Michael B., Male Louise, Lancaster Simon J.: The synthesis, structure and reactivity of 4-nonafluorobiphenyl complexes. Dalton Trans 2009, 1593. <http://dx.doi.org/10.1039/b817252h>
  • Stephan Douglas W.: “Frustrated Lewis pairs”: a concept for new reactivity and catalysis. Org Biomol Chem 2008, 6, 1535. <http://dx.doi.org/10.1039/b802575b>
  • Fuller Anna-Marie, Mountford Andrew J., Coles Simon J., Horton Peter N., Hughes David L., Hursthouse Michael B., Male Louise, Lancaster Simon J.: The synthesis, molecular structure and supramolecular architecture of complexes between the ammonia adduct of tris(pentafluorophenyl)boron and a series of mono and polydentate hydrogen-bond acceptors. Dalton Trans 2008, 6381. <http://dx.doi.org/10.1039/b808208a>
  • Fuller Anna-Marie, Clegg William, Harrington Ross W., Hughes David L., Lancaster Simon J.: Mononuclear TiN complexes formed by the facile multiple deprotonation of H3N·B(C6F5)3: the importance of chloride ligands. Chem Commun 2008, 5776. <http://dx.doi.org/10.1039/b812785a>
  • Welch Gregory C., Cabrera Lourdes, Chase Preston A., Hollink Emily, Masuda Jason D., Wei Pingrong, Stephan Douglas W.: Tuning Lewis acidity using the reactivity of “frustrated Lewis pairs”: facile formation of phosphine-boranes and cationic phosphonium-boranes. Dalton Trans 2007, 3407. <http://dx.doi.org/10.1039/b704417h>
  • Hannant Mark D., Schormann Mark, Hughes David L., Bochmann Manfred: Synthesis of cationic zinc complexes from protonated diazadienes and ZnR2 (R=Et, N(SiMe3)2). The crystal structures of [PriDADH][H2N{B(C6F5)3}2], [{PriDADZn(μ-OH)}2][H2N{B(C6F5)3}2]2, and [Ph*DADZnN(SiMe3)2][H2N{B(C6F5)3}2]. Inorg Chim Ada 2005, 358, 1683. <http://dx.doi.org/10.1016/j.ica.2004.11.012>
  • Al-Humydi Abdulaziz, Garrison Jered C., Mohammed Muqtar, Youngs Wiley J., Collins Scott: Propene polymerization using ansa-metallocenium ions: Catalyst deactivation processes during monomer consumption and molecular structures of the products formed. J Polyhedron 2005, 24, 1234. <http://dx.doi.org/10.1016/j.poly.2005.02.005>
  • Mountford Andrew J., Clegg William, Harrington Ross W., Humphrey Simon M., Lancaster Simon J.: New titanium and zirconium complexes with M–NH2 bonds formed by facile deprotonation of H3N·B(C6F5)3. Chem Commun 2005, 2044. <http://dx.doi.org/10.1039/b500407a>
  • Farrow Elaine, Sarazin Yann, Hughes David L., Bochmann Manfred: Synthesis and structure of [Cp2Zr(OPri)(HOPri)]+ and its activity in the polymerisation of propene oxide. J Organomet Chem 2004, 689, 4624. <http://dx.doi.org/10.1016/j.jorganchem.2004.07.012>