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Pure Appl. Chem., 2002, Vol. 74, No. 1, pp. 151-157

Zirconium-catalyzed enantioselective carboalumination of "unactivated" alkenes as a new synthetic tool for asymmetric carbon­carbon bond formation

Ei-ichi Negishi and Shouquan Huo

Herbert C. Brown Laboratories of Chemistry, Purdue University, West Lafayette, IN 47907-1393, USA

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  • Negishi Ei-ichi: Die magische Kraft der Übergangsmetalle: Vergangenheit, Gegenwart und Zukunft (Nobel-Aufsatz). angew chemie 2011, 123, 6870. <>
  • Negishi Ei-ichi: Magical Power of Transition Metals: Past, Present, and Future (Nobel Lecture). Angew Chem Int E 2011, 50, 6738. <>
  • Camara James M., Petros Robby A., Norton Jack R.: Zirconium-Catalyzed Carboalumination of α-Olefins and Chain Growth of Aluminum Alkyls: Kinetics and Mechanism. J Am Chem Soc 2011, 133, 5263. <>
  • Takimoto Masanori, Usami Saori, Hou Zhaomin: Scandium-Catalyzed Regio- and Stereospecific Methylalumination of Silyloxy/Alkoxy-Substituted Alkynes and Alkenes. J Am Chem Soc 2009, 131, 18266. <>
  • Petros Robby A., Camara James M., Norton Jack R.: Enantioselective methylalumination of α-olefins. J Organomet Chem 2007, 692, 4768. <>
  • Molander Gary A., Sommers Erin M.: Chromium(III) catalyzed synthesis of allenes from propargyl derivatives via a carbometalation–elimination sequence. Tetrahetron Lett 2005, 46, 2345. <>
  • Magnin-Lachaux Marina, Tan Ze, Liang Bo, Negishi Ei-ichi: Efficient and Selective Synthesis of Siphonarienolone and Related Reduced Polypropionates via Zr-Catalyzed Asymmetric Carboalumination. Org Lett 2004, 6, 1425. <>