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Pure Appl. Chem., 1999, Vol. 71, No. 3, pp. 453-462

http://dx.doi.org/10.1351/pac199971030453

Kinetics and mechanisms of the reactions of Si=C and Ge=C double bonds

W. J. Leigh

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  • Naka Akinobu, Kajihara Tomohito, Miura Toshiko, Kobayashi Hisayoshi, Ishikawa Mitsuo: Thermal and photochemical reactions of phenylethynyltris-(trimethylsilyl)germane. Journal of Organometallic Chemistry 2013, 727, 50. <http://dx.doi.org/10.1016/j.jorganchem.2012.12.018>
  • Liao Wei-Hung, Ho Pei-Yun, Su Ming-Der: Mechanisms for the Reactions of Group 10 Transition Metal Complexes with Metal–Group 14 Element Bonds, Bbt(Br)E═M(PCy3)2 (E = C, Si, Ge, Sn, Pb; M = Pd and Pt). Inorg. Chem. 2013, 52, 1338. <http://dx.doi.org/10.1021/ic302031f>
  • Wu Chi-Shiun, Su Ming-Der: Theoretical investigations of the reactivities of four-membered N-heterocyclic carbene analogues of the group 13 elements. J  Comput Chem 2012, 33, 103. <http://dx.doi.org/10.1002/jcc.21949>
  • Marino Tiziana, Michelini Maria C., Russo Nino, Sicilia Emilia, Toscano Marirosa: The nature of the C–As bonds in arsaalkynes: an atoms in molecules and electron localization function study. Theor Chem Accounts 2012, 131, 1141. <http://dx.doi.org/10.1007/s00214-012-1141-y>
  • Li Bo-Ying, Su Ming-Der: Theoretical Investigation of the Mechanisms for the Reaction of Fused Tricyclic Dimetallenes Containing Highly Strained E═E (E = C, Si, Ge, Sn, and Pb) Double Bonds. J Phys Chem A 2012, 116, 4222. <http://dx.doi.org/10.1021/jp3018138>
  • Li Bo-Ying, Su Ming-Der: Theoretical Investigations of the Reactions of Phosphino Disilenes and Their Derivatives with an E═E (E = C, Si, Ge, Sn, and Pb) Double Bond. J. Phys. Chem. A 2012, 116, 9412. <http://dx.doi.org/10.1021/jp3071822>
  • Hardwick Julie A., Pavelka Laura C., Baines Kim M.: The addition of amides to group 14 (di)-metallenes. DALTON T 2012, 41, 609. <http://dx.doi.org/10.1039/c1dt11450f>
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  • Li Bo-Ying, Su Ming-Der: Reactivities of Adamantyl-Substituted Metallenes with a C═E (E = C, Si, Ge, Sn, and Pb) Double Bond. A Theoretical Study. Organomettalics 2011, 30, 6189. <http://dx.doi.org/10.1021/om200725u>
  • Ibrahim Al-Rafia S. M., Malcolm Adam C., Liew Sean K., Ferguson Michael J., McDonald Robert, Rivard Eric: Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin. Chem Commun 2011, 47, 6987. <http://dx.doi.org/10.1039/c1cc11737h>
  • Leigh William J.: ChemInform Abstract: Kinetics and Mechanisms of the Reactions of Si=C and Ge=C Double Bonds. ChemInform 2010, 30, no. <http://dx.doi.org/10.1002/chin.199948286>
  • Naka Akinobu, Ueda Shinsuke, Fujimoto Hiroki, Miura Toshiko, Kobayashi Hisayoshi, Ishikawa Mitsuo: Silyl–substituted germenes. The reactions of germenes generated thermally from acyltris(trimethylsilyl)germane with conjugated enones. J Organomet Chem 2010, 695, 1663. <http://dx.doi.org/10.1016/j.jorganchem.2010.04.007>
  • Lai Chin-Hung, Su Ming-Der: Theoretical characterizations of HAsXH (X = N, P, As, Sb, and Bi) isomers in the singlet and triplet states. J Comput Chem 2008, 29, 2487. <http://dx.doi.org/10.1002/jcc.20970>
  • Naka Akinobu, Ueda Shinsuke, Ishikawa Mitsuo: The reactions of germenes generated thermally from pivaloyl- and adamantoyltris(trimethylsilyl)germane with 1,3-butadienes. J Organomet Chem 2007, 692, 2357. <http://dx.doi.org/10.1016/j.jorganchem.2007.02.011>
  • Tackett Brandon S., Clouthier Dennis J.: In search of the germanium halomethylidyne (Ge[Double Bond]C–X; X=F,Cl,Br) free radicals: Ab initio studies of their spectroscopic signatures. J Chem Phys 2006, 124, 144308. <http://dx.doi.org/10.1063/1.2187474>
  • Hu Ya-Hui, Su Ming-Der: Substituent effect on relative stabilities of the phosphorus and tin multiple bonds. chem phys letts 2003, 378, 289. <http://dx.doi.org/10.1016/S0009-2614(03)01268-5>
  • Gusel'nikov Leonid E.: Hetero-π-systems from 2+2 cycloreversions. Part 1. Gusel'nikov–Flowers route to silenes and origination of the chemistry of doubly bonded silicon. Coord Chem Rev - 2003, 244, 149. <http://dx.doi.org/10.1016/S0010-8545(03)00104-8>
  • Lai Chin-Hung, Su Ming-Der, Chu San-Yan: Relative stability of multiple bonds between germanium and arsenic. A theoretical study. J Polyhedron 2002, 21, 579. <http://dx.doi.org/10.1016/S0277-5387(01)01021-X>
  • Liao Hsin-Yi, Su Ming-Der, Chu San-Yan: A stable species with a formal GeC triple bond – a theoretical study. chem phys letts 2001, 341, 122. <http://dx.doi.org/10.1016/S0009-2614(01)00461-4>
  • Smith Tony C., Clouthier Dennis J., Steimle Timothy C.: Hyperfine structure and the Stark effect in the electronic spectrum of the SiCH radical with implications for microwave spectroscopy and radioastronomy. J Chem Phys 2001, 115, 817. <http://dx.doi.org/10.1063/1.1378818>
  • Smith Tony C., Clouthier Dennis J., Steimle Timothy C.: Determination of the electric dipole moment and excited state Fermi contact parameter of the GeCH radical. J Chem Phys 2001, 115, 5047. <http://dx.doi.org/10.1063/1.1394215>