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Pure Appl. Chem., 1995, Vol. 67, No. 5, pp. 769-775

NMR spectroscopic and computational investigations of σ-interactions in carbocations: The β-silyl effect in vinyl cations

H.-U. Siehl

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  • Hwu Jih Ru, Swain Sharada P.: Silicon-Induced Phenanthrene Formation from Benzynes and Allenylsilanes. Chem. Eur. J. 2013, 19, 6556. <>
  • Alkhafaji Haider M. H., Ryabukhin Dmitry S., Muzalevskiy Vasiliy M., Vasilyev Aleksander V., Fukin Georgy K., Shastin Alexey V., Nenajdenko Valentine G.: Regiocontrolled Hydroarylation of (Trifluoromethyl)acetylenes in Superacids: Synthesis of CF3 -Substituted 1,1-Diarylethenes. Eur. J. Org. Chem. 2013, 2013, 1132. <>
  • Yadav J.S., Thrimurtulu N., Lakshmi K. Anantha, Prasad A.R., Reddy B.V. Subba: The silylalkyne-Prins cyclization: a novel synthesis of 4-iododihydropyrans. Tetrahetron Lett 2010, 51, 661. <>
  • Miranda Pedro O., Ramírez Miguel A., Martín Víctor S., Padrón Juan I.: Factors Controlling the Alkyne Prins Cyclization: The Stability of Dihydropyranyl Cations. Chem Eur J 2008, 14, 6260. <>
  • Yoon Mi Young, Kim Jin Hong, Choi Doo Seoung, Shin Ueon Sang, Lee Jin Yong, Song Choong Eui: Metal Triflate-Catalyzed Regio- and Stereoselective Friedel–Crafts Alkenylation of Arenes with Alkynes in an Ionic Liquid: Scope and Mechanism. Adv Synth Catal 2007, 349, 1725. <>
  • Miranda Pedro O., Ramírez Miguel A., Martín Víctor S., Padrón Juan I.: The Silylalkyne-Prins Cyclization:  Stereoselective Synthesis of Tetra- and Pentasubstituted Halodihydropyrans. Org Lett 2006, 8, 1633. <>
  • Siehl Hans-Ullrich, Müller Thomas, Gauss Jürgen: NMR Spectroscopic and quantum chemical characterization of the (E)− and (Z)− isomers of the penta-1,3-dienyl-2-cation. J Phys Org Chem 2003, 16, 577. <>