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Pure Appl. Chem., 1992, Vol. 64, No. 7, pp. 1015-1028

http://dx.doi.org/10.1351/pac199264071015

ANALYTICAL CHEMISTRY DIVISION
COMMISSION ON ELECTROANALYTICAL CHEMISTRY

Reactant adsorption in analytical pulse voltammetry: Methodology and recommendations (Technical Report)

H. P. van Leeuwen, J. Buffle and Milivoj Lovric

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  • Zelić Marina, Omanović Dario, Pižeta Ivanka, Jagnjić Željko: Symmetry and Shape of Voltammetric Signals in the Light of Time-Series Classification based on Qualitative Space Fragmentation. Journal of Electroanalytical Chemistry 2013. <http://dx.doi.org/10.1016/j.jelechem.2013.04.030>
  • Zelić Marina, Lovrić Milivoj: Components of the Net Current in Differential Pulse Polarography. Part 2. Kinetics and Adsorption. Electroanalysis (N Y ) 2011, n/a. <http://dx.doi.org/10.1002/elan.201000630>
  • Ribeiro José A., Carreira Cátia A., Lee Hye Jin, Silva Fernando, Martins Ana, Pereira Carlos M.: Voltammetric determination of paraquat at DNA–gold nanoparticle composite electrodes. Electrochimica Acta 2010, 55, 7892. <http://dx.doi.org/10.1016/j.electacta.2010.03.058>
  • Zelić Marina, Jadreško Dijana: Components of the Net Current in Differential Pulse Polarography. Electroanalysis (N Y ) 2008, 20, 1897. <http://dx.doi.org/10.1002/elan.200804265>
  • Garrigosa Anna Maria, Díaz-Cruz José Manuel, Ariño Cristina, Esteban Miquel: Multivariate curve resolution as a tool to minimize the effects of electrodic adsorption in normal pulse voltammetry. Electrochimica Acta 2008, 53, 5579. <http://dx.doi.org/10.1016/j.electacta.2008.02.067>
  • Garrigosa Anna M., Ariño Cristina, Díaz-Cruz José Manuel, Esteban Miquel: Minimization of Electrode Adsorption Effects: The Cadmium–Humic Acid System Studied by Phase Sensitive Alternating Current Polarography. Electroanalysis (N Y ) 2006, 18, 1215. <http://dx.doi.org/10.1002/elan.200603548>
  • Domingos Rute F., Benedetti Marc F., Croué Jean P., Pinheiro José P.: Electrochemical methodology to study labile trace metal/natural organic matter complexation at low concentration levels in natural waters. Analytica Chimica Acta 2004, 521, 77. <http://dx.doi.org/10.1016/j.aca.2004.05.027>
  • Zelić Marina, Lovrić Milivoj: The influence of electrolyte concentration on the parameters of the Frumkin isotherm in the Cd2+–I− system. Journal of Electroanalytical Chemistry 2003, 541, 67. <http://dx.doi.org/10.1016/S0022-0728(02)01415-8>
  • Lovrić Milivoj, Zelić Marina, Komorsky-Lovrić Šebojka: Theoretical Analysis of Pulse and Differential Pulse Polarography of Reversible Redox Reaction Complicated by Reactant Adsorption. Collect Czech Chem Commun 2001, 66, 423. <http://dx.doi.org/10.1135/cccc20010423>
  • Cruz Boris H., Díaz-Cruz José Manuel, Ariño Cristina, Esteban Miquel: Heavy Metal Binding by Tannic Acid: A Voltammetric Study. Electroanalysis (N Y ) 2000, 12, 1130. <http://dx.doi.org/10.1002/1521-4109(200010)12:14<1130::AID-ELAN1130>3.0.CO;2-7>
  • Komorsky-Lovrić Šebojka: Adsorption and Reduction of Berberine at a Mercury Electrode. Electroanalysis (N Y ) 2000, 12, 599. <http://dx.doi.org/10.1002/(SICI)1521-4109(200005)12:8<599::AID-ELAN599>3.0.CO;2-U>
  • Murimboh J, Lam Michael T, Hassan Nouri M, Chakrabarti C.L: A study of Nafion-coated and uncoated thin mercury film-rotating disk electrodes for cadmium and lead speciation in model solutions of fulvic acid. Analytica Chimica Acta 2000, 423, 115. <http://dx.doi.org/10.1016/S0003-2670(00)01075-8>
  • Filella Montserrat, Town Raewyn M.: Determination of metal ion binding parameters for humic substances. Journal of Electroanalytical Chemistry 2000, 485, 21. <http://dx.doi.org/10.1016/S0022-0728(00)00083-8>
  • Guaus Ester, Sanz Fausto: Metal-Halide-Complex and Ligand Simultaneous Adsorption. Chronocoulometry Study in the Cd(II), KI/Hg System at Several Ionic Strengths. Electroanalysis (N Y ) 1999, 11, 424. <http://dx.doi.org/10.1002/(SICI)1521-4109(199905)11:6<424::AID-ELAN424>3.0.CO;2-N>
  • Almeida P.J, Rodrigues J.A, Barros A.A, Fogg A.G: Voltammetric studies of anthraquinone dyes adsorbed at a hanging mercury drop electrode using fast pulse techniques. Analytica Chimica Acta 1999, 385, 287. <http://dx.doi.org/10.1016/S0003-2670(98)00586-8>
  • Barros A.A., Rodrigues J.A., Almeida P.J., Rodrigues P.G., Fogg A.G.: Voltammetry of compounds confined at the hanging mercury drop electrode surface. Analytica Chimica Acta 1999, 385, 315. <http://dx.doi.org/10.1016/S0003-2670(98)00659-X>
  • Dı́az-Cruz M.S, Mendieta J, Monjonell A, Tauler R, Esteban M: Zinc-binding properties of the C-terminal hexapeptide Lys–Cys–Thr–Cys–Cys–Ala from mouse metallothionein: analysis by differential pulse polarography and multivariate curve resolution. Analytica Chimica Acta 1999, 385, 353. <http://dx.doi.org/10.1016/S0003-2670(98)00695-3>
  • Fatouros N., Krulic D.: Limiting current in normal pulse polarography with reactant adsorption obeying the Langmuir and the Frumkin isotherms. Journal of Electroanalytical Chemistry 1999, 478, 25. <http://dx.doi.org/10.1016/S0022-0728(99)00409-X>
  • Davison W., Buffle J., DeVitre R.: Voltammetric characterization of a dissolved iron sulphide species by laboratory and field studies. Analytica Chimica Acta 1998, 377, 193. <http://dx.doi.org/10.1016/S0003-2670(98)00334-1>
  • Wonders Jeannette H.A.M., Van Leeuwen Herman P.: Voltammetric metal speciation in colloidal latex dispersions. Electrochimica Acta 1998, 43, 3401. <http://dx.doi.org/10.1016/S0013-4686(98)00086-3>
  • Galceran Josep, Salvador José, Puy Jaume, Mas Francesc, Giménez Dolors, Esteban Miquel: Amalgamation effects in reverse pulse polarography at spherical electrodes. Influence on speciation measurements. Journal of Electroanalytical Chemistry 1998, 442, 151. <http://dx.doi.org/10.1016/S0022-0728(97)00483-X>
  • Puy Jaume, Torrent Marià, Monné Josep, Cecı́lia Joan, Galceran Josep, Salvador José, Lluı́s Garcés Josep, Mas Francesc, Berbel Francisco: Influence of the adsorption phenomena on the NPP and RPP limiting currents for labile metal-macromolecule systems. Journal of Electroanalytical Chemistry 1998, 457, 229. <http://dx.doi.org/10.1016/S0022-0728(98)00300-3>
  • Zelić Marina, Pižeta Ivanka: Voltammetric evidence of adsorption in cadmium(II)-iodide system at different ionic strengths. Electroanalysis (N Y ) 1997, 9, 155. <http://dx.doi.org/10.1002/elan.1140090214>
  • Zanoni M.V.B., Fogg A.G., Barek J., Zima J.: Electrochemical investigations of reactive dyes; cathodic stripping voltammetric determination of anthraquinone-based chlorotriazine dyes at a hanging mercury drop electrode. Analytica Chimica Acta 1997, 349, 101. <http://dx.doi.org/10.1016/S0003-2670(97)00268-7>
  • Barek Jiřı́, Beranová Jitka, G. Fogg Arnold, Mejstřı́k Viktor, Moreira Josino C, Zima Jiřı́: Polarographic and voltammetric determination of Ostacetate Blue P3R. Analytica Chimica Acta 1997, 356, 231. <http://dx.doi.org/10.1016/S0003-2670(97)00550-3>
  • Cancho Beatriz, Argudo Marco, Ariño Cristina, Esteban Miquel: Voltammetry of MnII and CoII in the presence of polymethacrylate. Electroanalysis (N Y ) 1996, 8, 460. <http://dx.doi.org/10.1002/elan.1140080511>
  • Pižeta Ivanka, Zelić Marina: Parasitic resistance as a source of error in voltammetric measurements. Analytica Chimica Acta 1996, 319, 31. <http://dx.doi.org/10.1016/0003-2670(95)00483-1>
  • Pinheiro J.P., Mota A.M., Simões Gonçalves M.L.S., van der Weijde M., van Leeuwen H.P.: Comparison between polarographic and potentiometric speciation for cadmium/humic acid systems. Journal of Electroanalytical Chemistry 1996, 410, 61. <http://dx.doi.org/10.1016/0022-0728(96)04513-5>
  • Galceran Josep, Salvador José, Puy Jaume, Cecília Joan, Esteban Miquel, Mas Francesc: Influence of adsorption on calibration curves in normal pulse polarography. Analytica Chimica Acta 1995, 305, 273. <http://dx.doi.org/10.1016/0003-2670(94)00372-S>
  • Argudo M., Esteban M.: Voltammetry of macromolecular metal complexes involving a nonreversible process: The Ni(II)-polymethacrylate system. Electroanalysis (N Y ) 1994, 6, 633. <http://dx.doi.org/10.1002/elan.1140060804>
  • Komorsky-Lovrić ŠEbojka, Lovrić Milivoj: Pulse polarography of azobenzene. Electroanalysis (N Y ) 1994, 6, 651. <http://dx.doi.org/10.1002/elan.1140060807>
  • Raspor Biserka, Vorkapić-Furač Jasna, Berkovic Katarina: Reduction mechanism of 3-hydroxy-4-hydroxyiminomethyl-5-hydroxymethyl-1,2-dimethylpyridinium iodide in an acidic medium. Journal of Electroanalytical Chemistry 1994, 367, 149. <http://dx.doi.org/10.1016/0022-0728(93)02946-F>
  • Galceran Josep, Reñe Daniel, Salvador José, Puy Jaume, Esteban Miquel, Mas Francesc: Reverse pulse polarography of labile metal + macromolecule systems with induced reactant adsorption: theoretical analysis and determination of complexation and adsorption parameters. Journal of Electroanalytical Chemistry 1994, 375, 307. <http://dx.doi.org/10.1016/0022-0728(94)03375-7>
  • Esteban Miquel, Díaz-Cruz José M.: General voltammetric method for studying metal complexation in macromolecular systems. Analytica Chimica Acta 1993, 281, 271. <http://dx.doi.org/10.1016/0003-2670(93)85182-J>
  • Komorsky-Lovrić Šebojka, Branica Marko: Adsorptive stripping square-wave voltammetry of Bi(III) in chloride media. Influence of triton X-100. Journal of Electroanalytical Chemistry 1993, 358, 273. <http://dx.doi.org/10.1016/0022-0728(93)80444-M>
  • Puy Jaume, Salvador José, Galceran Josep, Esteban Miquel, Díaz-Cruz José Manuel, Mas Francesc: Voltammetry of labile metal—complex systems with induced reactant adsorption. Theoretical analysis for any ligand-to-metal ratio. Journal of Electroanalytical Chemistry 1993, 360, 1. <http://dx.doi.org/10.1016/0022-0728(93)87001-C>
  • Esteban Miquel, Ariño Cristina, Diaz-Cruz José M., Casassas Enric: Voltammetry of metal ion—macromolecule interactions: Application to speciation problems. Trends in Analytical Chemistry 1993, 12, 276. <http://dx.doi.org/10.1016/0165-9936(93)87003-G>
  • Puy Jaume, Mas Francesc, Díaz-Cruz José M., Esteban Miquel, Cassasas Enric: Induced reactant adsorption in metal—polyelectrolyte systems: pulse polarographic study. Analytica Chimica Acta 1992, 268, 261. <http://dx.doi.org/10.1016/0003-2670(92)85220-Z>