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Pure Appl. Chem., 1989, Vol. 61, No. 10, pp. 1771-1776

http://dx.doi.org/10.1351/pac198961101771

Applications of 2-dimensional NMR in organometallic chemistry

P. S. Pregosin and Christian Ammann

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  • Geldbach Tilmann J., Pregosin Paul S.: η1 to η6 Ru−Arene π Complexation: New Bonding Modes and P−C Bond Cleavage Chemistry. Eur J Inorg Chem 2002, 2002, 1907. <http://dx.doi.org/10.1002/1099-0682(200208)2002:8<1907::AID-EJIC1907>3.0.CO;2-K>
  • Canovese Luciano, Visentin Fabiano, Uguagliati Paolo, Chessa Gavino, Lucchini Vittorio, Bandoli Giuliano: Novel palladium(II) allyl complexes with nitrogen-sulfur donor bidentate ligands. Mechanism of allyl amination of [Pd(η3-allyl)-(N-SR)]ClO4 (allyl = C3H5; N-SR = C5H4N-2-CH2SR, R = C6H5, C2H5) in the presence of activated olefins. X-ray structure determination and fluxional behavior. Inorg Chim Ada 1998, 275-276, 385. <http://dx.doi.org/10.1016/S0020-1693(97)06076-3>
  • Canovese Luciano, Visentin Fabiano, Uguagliati Paolo, Chessa Gavino, Pesce Andrea: Palladium(II) allyl complexes with nitrogen–sulfur bidentate ligands. Substituent effects in the mechanism of allyl amination. J Organomet Chem 1998, 566, 61. <http://dx.doi.org/10.1016/S0022-328X(98)00715-3>
  • Pregosin Paul S., Salzmann Renzo: Structure and dynamics of chiral allyl complexes of Pd(II): NMR spectroscopy and enantioselective allylic alkylation. Coord Chem Rev - 1996, 155, 35. <http://dx.doi.org/10.1016/S0010-8545(96)90176-9>
  • Hälg Werner J., Öhrström Lars R., Rüegger Heinz, Venanzi Luigi M., Gerfin Tobias, Gramlich Volker: The Dynamic Behaviour and NMR Solution structures of complexes of the type (Bisphosphine)(cycloocta-1,5-diene)iridium(I) and the X-ray crystal structure of (cycloocta-1,5-diene)((−)-norphos)iridium(I) hexafluorophosphate. HCA 1993, 76, 788. <http://dx.doi.org/10.1002/hlca.19930760203>
  • Ammann Christian J., Pregosin Paul S., Rüegger Heinz, Albinati Alberto, Lianza Francesca, Kunz Roland W.: Chemistry of PdII complexes containing both BINAP (2′2′-bis(diphenylphosphino)binaphthyl) and a η3-pinene or -allyl ligand. NMR studies on [Pd(η3-C10H15){S(−)BINAP}] (CF3SO3). The crystal structure of [Pd(η3-C10H15)(4,4′-dimethylbipyridine)](CF3SO3). J Organomet Chem 1992, 423, 415. <http://dx.doi.org/10.1016/0022-328X(92)83135-5>
  • Rüegger Heinz, Kunz Roland W., Ammann Christian J., Pregosin Paul S.: 2D NOESY studies on [Pd(η3-C10H15){(R)( + )-BINAP}]+ defining the relative spatial orientation of the phenyl and π-allyl moieties. Magn Reson Chem 1991, 29, 197. <http://dx.doi.org/10.1002/mrc.1260290302>
  • Pregosin Paul S., Wombacher Franz: Interactions and 2D NOESY. Pd(II) and Pt(II) cylometallation chemistry. Magn Reson Chem 1991, 29, S106. <http://dx.doi.org/10.1002/mrc.1260291319>
  • Togni Antonio, Rihs Grety, Pregosin Paul S., Ammann Christian: Synthesis, Structure, and 2D-NMR Studies of Novel Chiral (η3-Allyl)palladium(II) Complexes Containing the Bidentate Ligand Sparteine. HCA 1990, 73, 723. <http://dx.doi.org/10.1002/hlca.19900730321>