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Pure Appl. Chem., 1989, Vol. 61, No. 10, pp. 1681-1694

http://dx.doi.org/10.1351/pac198961101681

Tuning the reactivity of metals held in a rigid ligand environment

G. van Koten

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  • van Koten Gerard: Pincer ligands as powerful tools for catalysis in organic synthesis. Journal of Organometallic Chemistry 2013, 730, 156. <http://dx.doi.org/10.1016/j.jorganchem.2012.12.035>
  • Hayashi Yukiko, Szalda David J., Grills David C., Hanson Jonathan C., Huang Kuo-Wei, Muckerman James T., Fujita Etsuko: Isolation and X-ray structures of four Rh(PCP) complexes including a Rh(I) dioxygen complex with a short O–O bond. Polyhedron 2013, 58, 106. <http://dx.doi.org/10.1016/j.poly.2012.10.006>
  • Wingard Leah A., Finniss Mathew C., Norris Michael, White Peter S., Brookhart Maurice, Templeton Joseph L.: Synthesis, Structure, and Reactivity of Iridium(III) Complexes Containing a 4,6-Dimethyl-1,3-benzenediphenylimine Pincer Ligand. Inorg. Chem. 2013, 52, 515. <http://dx.doi.org/10.1021/ic302589b>
  • Budagumpi Srinivasa, Endud Salasiah: Group XII Metal–N-Heterocyclic Carbene Complexes: Synthesis, Structural Diversity, Intramolecular Interactions, and Applications. Organometallics 2013, 32, 1537. <http://dx.doi.org/10.1021/om301091p>
  • Bratko Ielyzaveta, Gómez Montserrat: Polymetallic complexes linked to a single-frame ligand: cooperative effects in catalysis. Dalton Trans. 2013, 42, 10664. <http://dx.doi.org/10.1039/c3dt50963j>
  • Hejda Martin, Dostál Libor, Jambor Roman, Růžička Aleš, Jirásko Robert, Holeček Jaroslav: Synthesis, Structure and Transmetalation Activity of Various C,Y-Chelated Organogold(I) Compounds. Euro J Inorg Chem 2012, 2012, 2578. <http://dx.doi.org/10.1002/ejic.201200152>
  • Musa Sanaa, Shpruhman Alina, Gelman Dmitri: New PC(sp3)P pincer complexes of platinum and palladium. Journal of Organometallic Chemistry 2012, 699, 92. <http://dx.doi.org/10.1016/j.jorganchem.2011.11.007>
  • Gelman Dmitri, Musa Sanaa: Coordination Versatility of sp3-Hybridized Pincer Ligands toward Ligand–Metal Cooperative Catalysis. ACS Catal. 2012, 2, 2456. <http://dx.doi.org/10.1021/cs3005083>
  • Sattler Aaron, Parkin Gerard: A New Class of Transition Metal Pincer Ligand: Tantalum Complexes that Feature a [CCC] X3-Donor Array Derived from a Terphenyl Ligand. S J Am Chem Soc 2012, 134, 2355. <http://dx.doi.org/10.1021/ja210404x>
  • Vabre Boris, Spasyuk Denis M., Zargarian Davit: Impact of Backbone Substituents on POCOP-Ni Pincer Complexes: A Structural, Spectroscopic, and Electrochemical Study. Organometallics 2012, 31, 8561. <http://dx.doi.org/10.1021/om3009475>
  • Newman Paul D., Cavell Kingsley J., Kariuki Benson M.: Variable coordination of a chiral diphosphine containing an amidinium/NHC group within its backbone: μ-P,P′, κ2-P,P′ and κ3-P,C,P′ coordination modes. Dalton Trans. 2012, 41, 12395. <http://dx.doi.org/10.1039/c2dt31475d>
  • Ohshima Takashi, Kawabata Takahito, Takeuchi Yosuke, Kakinuma Takahiro, Iwasaki Takanori, Yonezawa Takayuki, Murakami Hajime, Nishiyama Hisao, Mashima Kazushi: C1-Symmetric Rh/Phebox-Catalyzed Asymmetric Alkynylation of α-Ketoesters. angew chemie 2011, 123, 6420. <http://dx.doi.org/10.1002/ange.201100252>
  • Ohshima Takashi, Kawabata Takahito, Takeuchi Yosuke, Kakinuma Takahiro, Iwasaki Takanori, Yonezawa Takayuki, Murakami Hajime, Nishiyama Hisao, Mashima Kazushi: C1-Symmetric Rh/Phebox-Catalyzed Asymmetric Alkynylation of α-Ketoesters. Angewandte Chemie-Int Ed 2011, 50, 6296. <http://dx.doi.org/10.1002/anie.201100252>
  • Wanniarachchi Sarath, Liddle Brendan J., Lindeman Sergey V., Gardinier James R.: Preparation, properties, and reactivity of carbonylrhodium(I) complexes of di(2-pyrazolylaryl)amido-pincer ligands. J Organomet Chem 2011, 696, 3623. <http://dx.doi.org/10.1016/j.jorganchem.2011.08.013>
  • Serra Daniel, Cao Peng, Cabrera José, Padilla Robin, Rominger Frank, Limbach Michael: Development of Platinum(II) and -(IV) CNC Pincer Complexes and Their Application in a Hydrovinylation Reaction. Organomet 2011, 30, 1885. <http://dx.doi.org/10.1021/om101128f>
  • Allen Olivia R., Field Leslie D., Magill Alison M., Vuong Khuong Q., Bhadbhade Mohan M., Dalgarno Scott J.: Ruthenium Complexes of CP3: A New Carbon-Centered Polydentate Podand Ligand. Organomettalics 2011, 30, 6433. <http://dx.doi.org/10.1021/om200718j>
  • Luo Qun-Li, Tan Jian-Ping, Li Zhi-Fu, Qin Yue, Ma Lin, Xiao Dong-Rong: Novel bis(azole) pincer palladium complexes: synthesis, structures and applications in Mizoroki–Heck reactions. Dalton Trans 2011, 40, 3601. <http://dx.doi.org/10.1039/c0dt01414a>
  • Musa Sanaa, Romm Ronit, Azerraf Clarite, Kozuch Sebastian, Gelman Dmitri: New possible mode of ligand–metal cooperation in PC(sp3)P pincer complexes. DALTON T 2011, 40, 8760. <http://dx.doi.org/10.1039/c1dt10167f>
  • Gómez-Sal Pilar, Parra Andrés, Galajov Miguel, Galindo Agustín, García Carlos, Gómez Manuel: Synthetic and structural studies of monocyclopentadienyl cyclometalated aryl tantalum(v) compounds. Dalton Trans 2011, 40, 8399. <http://dx.doi.org/10.1039/c1dt10223k>
  • Dostál Libor, Jambor Roman, Růžička Aleš, Jirásko Robert, Holeček Jaroslav, De Proft Frank: OCO and NCO chelated derivatives of heavier group 15 elements. Study on possibility of cyclization reaction via intramolecular ether bond cleavage. DALTON T 2011, 40, 8922. <http://dx.doi.org/10.1039/c1dt10234f>
  • van Koten Gerard, Gebbink R. J. M. (Bert) Klein: The monoanionic pincer–metal platform: a scaffold for meeting challenges in catalysis and materials research. DALTON T 2011, 40, 8731. <http://dx.doi.org/10.1039/c1dt90120f>
  • Li Jie, Siegler Maxime, Lutz Martin, Spek Anthony L., Klein Gebbink Robertus J. M., van Koten Gerard: PCN- and PCS-Pincer Palladium Complexes as Tandem Catalysts in Homoallylation Reactions. Adv Synth Catal 2010, 352, 2474. <http://dx.doi.org/10.1002/adsc.201000204>
  • van de Kuil Lucia A., Veldhuizen Yvonne S. J., Grove David M., Zwikker Jan W., Jenneskens Leonardus W., Drenth Wiendelt, Smeets Wilberth J. J., Spek Anthony L., van Koten Gerard: Organonickel(II) complexes containing aryl ligands with chiral pyrrolidinyl ring systems; syntheses and use as homogeneous catalysts for the Kharasch addition reaction. Recl Trav Chim Pays-Bas 2010, 113, 267. <http://dx.doi.org/10.1002/recl.19941130502>
  • Suijkerbuijk Bart M. J. M., Schamhart Daniël J., Kooijman Huub, Spek Anthony L., van Koten Gerard, Klein Gebbink Robertus J. M.: Mono(NCN-pincer palladium)-metalloporphyrin catalysts: evidence for supramolecular bimetallic catalysis. Dalton Trans 2010, 39, 6198. <http://dx.doi.org/10.1039/b925236n>
  • Vrána Jan, Jambor Roman, Růžička Aleš, Holeček Jaroslav, Dostál Libor: NCO-Chelated organoantimony(III) and organobismuth(III) dichlorides: Syntheses and structures. Collect Czech Chem Commun 2010, 75, 1041. <http://dx.doi.org/10.1135/cccc2010051>
  • Chang Gao-Fong, Kumar Anil, Ching Wei-Min, Chu Han-Wei, Hung Chen-Hsiung: Tetramethyl-m-benziporphodimethene and Isomeric α,β-Unsaturated γ-Lactam Embedded N-Confused Tetramethyl-m-benziporphodimethenes. Chem Asian J 2009, 4, 164. <http://dx.doi.org/10.1002/asia.200800279>
  • Ronde Niek J., Totev Daniel, Müller Christian, Lutz Martin, Spek Anthony L., Vogt Dieter: Molecular-Weight-Enlarged Multiple-Pincer Ligands: Synthesis and Application in Palladium-Catalyzed Allylic Substitution Reactions. ChemSusChem 2009, 2, 558. <http://dx.doi.org/10.1002/cssc.200800256>
  • Bockholt Andreas, Jutzi Peter, Mix Andreas, Neumann Beate, Stammler Anja, Stammler Hans-Georg: Neutral and Cationic Silicon Species Containing Aryl-OCO- or Aryl-SCS-Type Pincer Ligands: Synthesis, Structure, Bonding, and Comparison with Aryl-NCN Systems. Z anorg allg Chem 2009, 635, 1326. <http://dx.doi.org/10.1002/zaac.200900162>
  • Kruithof Cornelis A., Berger Alexsandro, Dijkstra Harmen P., Soulimani Fouad, Visser Tom, Lutz Martin, Spek Anthony L., Gebbink Robertus J. M. Klein, van Koten Gerard: Sulfato-bridged ECE-pincer palladium(ii) complexes: structures in the solid-state and in solution, and catalytic properties. Dalton Trans 2009, 3306. <http://dx.doi.org/10.1039/b816936e>
  • Gagliardo Marcella, Selander Nicklas, Mehendale Nilesh C., van Koten Gerard, Klein Gebbink Robertus J. M., Szabó Kálmán J.: Catalytic Performance of Symmetrical and Unsymmetrical Sulfur-Containing Pincer Complexes: Synthesis and Tandem Catalytic Activity of the First PCS-Pincer Palladium Complex. Chem Eur J 2008, 14, 4800. <http://dx.doi.org/10.1002/chem.200800350>
  • Dahlenburg Lutz, Treffert Harald, Heinemann Frank W.: 1,3-Bis(α-aminoisopropyl)benzene, meta-C6H4(CMe2NH2)2: An N,N-bridging and N,C,N-cyclometalating ligand. Inorg Chim Ada 2008, 361, 1311. <http://dx.doi.org/10.1016/j.ica.2007.08.027>
  • Ramírez Paola, Contreras Raúl, Valderrama Mauricio, Carmona Daniel, Lahoz Fernando J., Balana Ana I.: Cyclometallated platinum(II) complexes containing the chiral ligand [2-(diphenyl-phosphanyl)-benzylidene]-(1-phenyl-ethyl)-amine: Synthesis and molecular structures of the compounds [PtCl(Me){κ2-(R)-Ph2P(C6H4)CHNCH(Ph)Me-P,N}] and [Pt{κ3-(S)-Ph2P(C6H4)CHNCH(C6H4)Me-P,N,C}Py]BF4. J Organomet Chem 2008, 693, 349. <http://dx.doi.org/10.1016/j.jorganchem.2007.10.032>
  • Chase Preston A., Lutz Martin, Spek Anthony L., Gossage Robert A., van Koten Gerard: Solid-state and solution structures of hetero-aggregates formed between nBuLi and NCN pincer aryl lithium. Dalton Trans 2008, 5783. <http://dx.doi.org/10.1039/b805092a>
  • Stey Thomas, Pfeiffer Matthias, Henn Julian, Pandey Sushil K., Stalke Dietmar: Di(benzothiazol-2-yl)phosphanide as a Janus-Head Ligand to Caesium. Chem Eur J 2007, 13, 3636. <http://dx.doi.org/10.1002/chem.200601221>
  • Nishiyama Hisao: Synthesis and use of bisoxazolinyl-phenyl pincers. Chem Soc Rev 2007, 36, 1133. <http://dx.doi.org/10.1039/b605991k>
  • Thoonen Sander H.L., van Hoek Hein, de Wolf Elwin, Lutz Martin, Spek Anthony L., Deelman Berth-Jan, van Koten Gerard: Synthesis of novel terdentate N,C,N′-coordinated butyltin(IV) complexes and their redistribution reactions with SnCl4. J Organomet Chem 2006, 691, 1544. <http://dx.doi.org/10.1016/j.jorganchem.2005.11.063>
  • Chase Preston A., Lutz Martin, Spek Anthony L., van Klink Gerard P.M., van Koten Gerard: Ring closing metathesis employing organometallic substrates and the templated synthesis of macrocycles. Journal of Molecular Catalysis A 2006, 254, 2. <http://dx.doi.org/10.1016/j.molcata.2006.01.071>
  • Okamoto Ken, Kanbara Takaki, Yamamoto Takakazu: Synthesis and Structural Features of a Series of κ3SNS Pincer Complexes of Group 10 Metals σ-Bonded to Centered Pyrrolate Unit. Chem Lett 2006, 35, 558. <http://dx.doi.org/10.1246/cl.2006.558>
  • Gossage Robert A., Jastrzebski Johann T. B. H., van Koten Gerard: Heteroaggregate von Aryl- und Alkyllithiumreagentien: Faszinierende Strukturen mit grundlegender Bedeutung. Angew Chem 2005, 117, 1472. <http://dx.doi.org/10.1002/ange.200462103>
  • Gossage Robert A., Jastrzebski Johann T. B. H., van Koten Gerard: Hetero-Aggregate Compounds of Aryl and Alkyl Lithium Reagents: A Structurally Intriguing Aspect of Organolithium Chemistry. Angew Chem Int Ed 2005, 44, 1448. <http://dx.doi.org/10.1002/anie.200462103>
  • Wang Zhong-Xia, Qi Chun-Yan: Synthesis, structures and reactions of lithium complexes of [(o-RCHC6H4)PPh2NSiMe3]–(R = H, SiMe3) ligands. Dalton Trans 2005, 996. <http://dx.doi.org/10.1039/b418389d>
  • Slagt Martijn Q., Zwieten Don A.P. van, Moerkerk Adrianus J.C.M., Gebbink Robertus J.M. Klein, Koten Gerard van: NCN–pincer palladium complexes with multiple anchoring points for functional groups. Coord Chem Rev - 2004, 248, 2275. <http://dx.doi.org/10.1016/j.ccr.2004.08.014>
  • Das Sunirban, Pal Samudranil: Cyclopalladated complexes with N-(benzoyl)-N′-(2,4-dimethoxybenzylidene)hydrazine: syntheses, characterization and structural studies. J Organomet Chem 2004, 689, 352. <http://dx.doi.org/10.1016/j.jorganchem.2003.10.022>
  • Winter Angelika M, Eichele Klaus, Mack Hans-Georg, Potuznik Suzan, Mayer Hermann A, Kaska William C: Rhodium pincer complexes of 2,2′-bis(diphenylphosphino)diphenylamine. J Organomet Chem 2003, 682, 149. <http://dx.doi.org/10.1016/S0022-328X(03)00776-9>
  • Robitzer Mike, Sirlin Claude, Kyritsakas Nathalie, Pfeffer Michel: Molecular Recognition of Anions by a Novel Organocobalt Receptor: Oxyanion versus Halide Selectivity in Water. Eur J Inorg Chem 2002, 2002, 2312. <http://dx.doi.org/10.1002/1099-0682(200209)2002:9<2312::AID-EJIC2312>3.0.CO;2-4>
  • Peveling Katja, Schürmann Markus, Jurkschat Klaus: The First [4+2]-Coordinated Tetraorganolead Compound: Synthesis, Structure and Conversion into a Triorganolead Cation, a Benzoxaphosphaplumbole, and Diorganolead Dihalides. Z anorg allg Chem 2002, 628, 2435. <http://dx.doi.org/10.1002/1521-3749(200211)628:11<2435::AID-ZAAC2435>3.0.CO;2-S>
  • Rodríguez Gema, Lutz Martin, Spek Anthony L., van Koten Gerard: New Mono- and Tricyclopalladated Dendritic Systems with Encapsulated Catalytic Sites. Chem Eur J 2002, 8, 45. <http://dx.doi.org/10.1002/1521-3765(20020104)8:1<45::AID-CHEM45>3.0.CO;2-P>
  • Berger Alexsandro, Djukic Jean-Pierre, Michon Christophe: Metalated (η6-arene)tricarbonylchromium complexes in organometallic chemistry. Coord Chem Rev - 2002, 225, 215. <http://dx.doi.org/10.1016/S0010-8545(01)00415-5>
  • Kimmich Barbara F.M, Marshall William J, Fagan Paul J, Hauptman Elisabeth, Bullock R.Morris: Palladium complexes with PCP ligands. Inorg Chim Ada 2002, 330, 52. <http://dx.doi.org/10.1016/S0020-1693(01)00736-8>
  • Guillena Gabriela, Rodrı́guez Gema, van Koten Gerard: Palladium(II) pincer complexes of α-amino acids: towards the synthesis of catalytically active artificial peptides. Tetrahetron Lett 2002, 43, 3895. <http://dx.doi.org/10.1016/S0040-4039(02)00656-1>
  • Slagt Martijn Q., Klein Gebbink Robertus J. M., Lutz Martin, Spek Anthony L., van Koten Gerard: Synthetic strategies towards new para-functionalised NCN-pincer palladium(ii) and platinum(ii) complexes. J Chem Soc Dalton Trans 2002, 2591. <http://dx.doi.org/10.1039/b204239h>
  • Haenel Matthias W., Oevers Stephan, Angermund Klaus, Kaska William C., Fan Hua-Jun, Hall Michael B.: Thermally Stable Homogeneous Catalysts for Alkane Dehydrogenation. Angew Chem 2001, 113, 3708. <http://dx.doi.org/10.1002/1521-3757(20011001)113:19<3708::AID-ANGE3708>3.0.CO;2-W>
  • Albrecht Martin, van Koten Gerard: Metallorganische Pinzetten-Komplexe von Elementen der Platingruppe: Sensoren, Schalter und Katalysatoren. Angew Chem 2001, 113, 3866. <http://dx.doi.org/10.1002/1521-3757(20011015)113:20<3866::AID-ANGE3866>3.0.CO;2-J>
  • Albrecht Martin, Hovestad Neldes J., Boersma Jaap, van Koten Gerard: Multiple Use of Soluble Metallodendritic Materials as Catalysts and Dyes. Chem Eur J 2001, 7, 1289. <http://dx.doi.org/10.1002/1521-3765(20010316)7:6<1289::AID-CHEM1289>3.0.CO;2-6>
  • Stępień Marcin, Latos-Grażyński Lechosław: Tetraphenylbenziporphyrin—A Ligand for Organometallic Chemistry. Chem Eur J 2001, 7, 5113. <http://dx.doi.org/10.1002/1521-3765(20011203)7:23<5113::AID-CHEM5113>3.0.CO;2-V>
  • Albrecht Martin, van Koten Gerard: Platinum Group Organometallics Based on “Pincer” Complexes: Sensors, Switches, and Catalysts. Angew Chem Int Ed 2001, 40, 3750. <http://dx.doi.org/10.1002/1521-3773(20011015)40:20<3750::AID-ANIE3750>3.0.CO;2-6>
  • Albrecht Martin, James Stuart L, Veldman Nora, Spek Anthony L, Koten Gerard van: Transmetalation reactions with nitrogen-containing "pincer"-class ligands on platinum(II) centers. Can J Chem 2001, 79, 709. <http://dx.doi.org/10.1139/v01-054>
  • Schlenk Christian, Kleij Arjan W., Frey Holger, van Koten Gerard: Macromolecular-Multisite Catalysts Obtained by Grafting Diaminoaryl Palladium(ii) Complexes onto a Hyperbranched-Polytriallylsilane Support. Angew Chem 2000, 112, 3587. <http://dx.doi.org/10.1002/1521-3757(20001002)112:19<3587::AID-ANGE3587>3.0.CO;2-0>
  • Schlenk Christian, Kleij Arjan W., Frey Holger, van Koten Gerard: Macromolecular-Multisite Catalysts Obtained by Grafting Diaminoaryl Palladium(ii) Complexes onto a Hyperbranched-Polytriallylsilane Support. Angew Chem 2000, 39, 3445. <http://dx.doi.org/10.1002/1521-3773(20001002)39:19<3445::AID-ANIE3445>3.0.CO;2-8>
  • Kleij Arjan W., Gossage Robert A., Jastrzebski Johann T. B. H., Boersma Jaap, van Koten Gerard: Der „dendritische Effekt” in der homogenen Katalyse mit Arylnickel(II)-Katalysatoren auf Carbosilanträgern: Naheinflüsse des aktiven Zentrums bei Atomtransfer-Radikaladditionen. Angew Chem 2000, 112, 179. <http://dx.doi.org/10.1002/(SICI)1521-3757(20000103)112:1<179::AID-ANGE179>3.0.CO;2-B>
  • Anderson Craig, Crespo Margarita, Font-Bardı́a Mercè, Solans Xavier: Oxidative addition of alkyl halides to chiral cyclometallated platinum(II) complexes with thienyl imines. X-ray crystal structure of [PtMe{3-((S)-PhCHMeNCH)C4H2S}SMe2]. J Organomet Chem 2000, 604, 178. <http://dx.doi.org/10.1016/S0022-328X(00)00231-X>
  • Kemp Richard A, Chen Linfeng, Guzei Ilia, Rheingold Arnold L: Synthesis and structural characterization of Group 14 complexes containing two {9-[2-(dimethylamino)ethyl]fluorenyl-} ligands and a unique coupling product. J Organomet Chem 2000, 596, 70. <http://dx.doi.org/10.1016/S0022-328X(99)00540-9>
  • Canty Allan J., Patel Jim, Skelton Brian W., White Allan H.: Facial and meridional [NCN]− intramolecular coordination systems: structure of fac-PtBrMe2{2,6-(pzCH2)2C6H3}·1/2C6H6 {[2,6-(pzCH2)2C6H3]−=2,6-(bis{(pyrazol-1-yl)methyl}phenyl)} and mer-PtBr{2,6-(3,5-Me2pzCH2)2C6H3}, and an alternative synthetic route to the platinum(II) [NCN]− kernel. J Organomet Chem 2000, 599, 195. <http://dx.doi.org/10.1016/S0022-328X(99)00763-9>
  • Grimm Jost C, Nachtigal Christiane, Mack H.-G, Kaska William C, Mayer Hermann A: A novel functionalized P,C,P pincer ligand complex. J Inorg Chem Commun 2000, 3, 511. <http://dx.doi.org/10.1016/S1387-7003(00)00132-5>
  • Albrecht Martin, Rodríguez Gema, Schoenmaker Jeroen, van Koten Gerard: New Peptide Labels Containing Covalently Bonded Platinum(II) Centers as Diagnostic Biomarkers and Biosensors. Org Lett 2000, 2, 3461. <http://dx.doi.org/10.1021/ol006484l>
  • Río Ignacio del, Gossage Robert A, Hannu Milja S, Lutz Martin, Spek Anthony L, Koten Gerard van: Synthesis and characterization of two new "pincer" complexes of zinc(II). The X-ray crystal structures of the five coordinate complexes [ZnCl23-NN'N-2,6-(R2NCH2)2C5H3N}] (R = n-Bu or Me). Can J Chem 2000, 78, 1620. <http://dx.doi.org/10.1139/v00-145>
  • Wingerter Stefan, Gornitzka Heinz, Bertrand Guy, Stalke Dietmar: The Deprotonated Iminophosphoraneo-C6H4PPh2P=NSiMe3 as a Novel Chelating Ligand in Organocopper(I) and -zinc(II) Chemistry. Eur J Inorg Chem 1999, 1999, 173. <http://dx.doi.org/10.1002/(SICI)1099-0682(199901)1999:1<173::AID-EJIC173>3.0.CO;2-T>
  • van Koten Gerard, Jastrzebski Johann T.B.H.: Periphery-functionalized organometallic dendrimers for homogeneous catalysis. Journal of Molecular Catalysis A 1999, 146, 317. <http://dx.doi.org/10.1016/S1381-1169(99)00091-6>
  • Lagunas María-Cristina, Gossage Robert A., Smeets Wilberth J. J., Spek Anthony L., van Koten Gerard: Coordination Behaviour of the New Multidentate Ligand 3,5-Bis(dimethylaminomethyl)pyridine with Palladium(II) and Platinum(II) Metal Centres. Eur J Inorg Chem 1998, 1998, 163. <http://dx.doi.org/10.1002/(SICI)1099-0682(199802)1998:2<163::AID-EJIC163>3.0.CO;2-X>
  • Chuit Claude, Reyé Catherine: Hypercoordinate PII, PIII, and PIV Phosphorus Derivatives with Intramolecular Coordination by Donor Groups. Eur J Inorg Chem 1998, 1998, 1847. <http://dx.doi.org/10.1002/(SICI)1099-0682(199812)1998:12<1847::AID-EJIC1847>3.0.CO;2-K>
  • Steenwinkel Pablo, Gossage Robert A., van Koten Gerard: Recent Findings in Cyclometallation of meta-Substituted Aryl Ligands by Platinum Group Metal Complexes by Caryl-R Bond Activation (R=H, CR3, SiR3). Chem Eur J 1998, 4, 759. <http://dx.doi.org/10.1002/(SICI)1521-3765(19980515)4:5<759::AID-CHEM759>3.0.CO;2-K>
  • Steenwinkel Pablo, Gossage Robert A., Maunula Tatja, Grove David M., van Koten Gerard: The Effect of the Trimethylsilyl Group on Electrophilic Cyclopalladation; A Study of Caryl-Si versus Caryl-H Selective Bond Activation with 2,6-(Me2NCH2)2C6H3R (R=H or SiMe3). Chem Eur J 1998, 4, 763. <http://dx.doi.org/10.1002/(SICI)1521-3765(19980515)4:5<763::AID-CHEM763>3.0.CO;2-3>
  • Kobayashi Katsutoshi, Sato Soichi, Horn Ernst, Furukawa Naomichi: First isolation and characterization of sulfenium cation salts stabilized by the coordination of two nitrogen atoms. Tetrahetron Lett 1998, 39, 2593. <http://dx.doi.org/10.1016/S0040-4039(98)00277-9>
  • Furukawa Naomichi: Creation of Organo-Sulfur, -Selenium- and - Tellurium Multi-Cation Species. Phosphorus Sulfur Silicon Relat Elem 1998, 136, 43. <http://dx.doi.org/10.1080/10426509808545934>
  • Chuit Claude, Corriu Robert J.P., Mehdi Ahmad, Reyé Catherine, Carré Francis: N → P intramolecular stabilization of phosphenium ions and preparation of hypercoordinated phosphanes with unusual properties. J Organomet Chem 1997, 529, 59. <http://dx.doi.org/10.1016/S0022-328X(96)06659-4>
  • Rietveld Marco H.P., Nagelholt Lammert, Grove David M., Veldman Nora, Spek Anthony L., Rauch Monika U., Herrmann Wolfgang A., van Koten Gerard: Synthesis of methyltrioxorhenium(VII) arylamine complexes and mono- and bis(ortho)-chelated arylaminorhenium(VII) trioxides. J Organomet Chem 1997, 530, 159. <http://dx.doi.org/10.1016/S0022-328X(96)06665-X>
  • Jia Guochen, Lee Hon Man, Williams Ian D.: Five- and six-coordinate ruthenium complexes with the tridentate orthometallated aryl bisphosphine ligand [2,6-(Ph2PCH2)2C6H3]−. J Organomet Chem 1997, 534, 173. <http://dx.doi.org/10.1016/S0022-328X(96)06926-4>
  • Schlengermann Robert, Sieler Joachim, Hey-Hawkins Evamarie: Synthesis and Molecular Structures of the Base-stabilized Arylboron Dichlorides BCl2{2,6-(NEt2CH2)2C6H3} and BCl2{2-(NMe2CH2)C6H4}. Main Group Chem 1997, 2, 141. <http://dx.doi.org/10.1080/10241229712331341274>
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