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Pure Appl. Chem., 1986, Vol. 58, No. 4, pp. 513-528

http://dx.doi.org/10.1351/pac198658040513

Transition metal NMR spectroscopy - a probe into organometallic structure and catalysis

W. von Philipsborn

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  • Adeniyi Adebayo A., Ajibade Peter A.: Theoretical study of the electronic and spectroscopic properties of some Ru(II) anticancer complexes. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2013, 105, 456. <http://dx.doi.org/10.1016/j.saa.2012.12.016>
  • Bauer Gernot, Englert Cornelia, Nieger Martin, Gudat Dietrich: Different coordination behavior of a catechol phosphine and its sulfide: Formation of an unprecedented dinuclear rhodium complex with a non-coordinated PS unit. Inorg Chim Ada 2011, 374, 240. <http://dx.doi.org/10.1016/j.ica.2011.02.076>
  • Fabrello Amandine, Dinoi Chiara, Perrin Lionel, Kalck Philippe, Maron Laurent, Urrutigoity Martine, Dechy-Cabaret Odile: Probing the stereo-electronic properties of cationic rhodium complexes bearing chiral diphosphine ligands by 103Rh NMR. Magn Reson Chem 2010, 48, 848. <http://dx.doi.org/10.1002/mrc.2677>
  • Carretero Antonio Segura, Gutiérrez Alberto Fernández, Oña-Burgos Pascual, Casimiro María, Fernández Ignacio, Navarro Angel Valero, Fernández Sánchez Jorge F.: Octahedral iron(ii) phthalocyanine complexes: multinuclear NMR and relevance as NO2 chemical sensors. Dalton Trans 2010, 39, 6231. <http://dx.doi.org/10.1039/b924429h>
  • Zakzeski Joseph, Burton Sarah, Behn Andrew, Head-Gordon Martin, Bell Alexis T.: Spectroscopic investigation of the species involved in the rhodium-catalyzed oxidative carbonylation of toluene to toluic acid. Phys Chem Chem Phys 2009, 11, 9903. <http://dx.doi.org/10.1039/b906883j>
  • Emdin Avril, Lemmerer Andreas, Carlton Laurence, Fernandes Manuel A.: A tungsten-183 NMR study of cis and trans isomers of [W(CO)4(PPh3)(PR3)](PR3 = phosphine, phosphite). Magn Reson Chem 2008, 46, S56. <http://dx.doi.org/10.1002/mrc.2300>
  • Pregosin Paul S.: 31P and 13C NMR studies on metal complexes of phosphorus-donors: Recognizing surprises. Coord Chem Rev - 2008, 252, 2156. <http://dx.doi.org/10.1016/j.ccr.2008.01.035>
  • Wrackmeyer Bernd, Herberhold Max: NMR parameters of the tetrahedrane [Fe2(CO)6(μ-SNH)], studied by experiment and DFT. Struct Chem 2006, 17, 79. <http://dx.doi.org/10.1007/s11224-006-9030-4>
  • Sisak Attila, Szalontai Gábor.: Formation and multinuclear magnetic resonance investigation of silylammonium tetracarbonylcobaltate contact ion pairs. cent eur j chem 2006, 4, 299. <http://dx.doi.org/10.2478/s11532-006-0005-5>
  • Wrackmeyer Bernd, Maisel Heidi E., Tok Oleg L., Milius Wolfgang, Herberhold Max: NMR Spectroscopic Characterization of Isocyano- and 1, 1′-Diisocyanoferrocene. The Molecular Structure of Isocyanoferrocene. Z anorg allg Chem 2004, 630, 2106. <http://dx.doi.org/10.1002/zaac.200400128>
  • Wrackmeyer Bernd, Ayazi Anahid, Maisel Heidi E, Herberhold Max: 57Fe-NMR spectroscopy revisited: ferrocene derivatives containing heterosubstituents. J Organomet Chem 2001, 630, 263. <http://dx.doi.org/10.1016/S0022-328X(01)01008-7>
  • Wrackmeyer Bernd, Seidel Günter, Köster Roland: Isotope-induced chemical shifts1Δ12/13C(29Si) and57Fe NMR of organosubstituted 2,5-dihydro-1,2,5-azasilaboroles, a silole and their tricarbonyliron complexes. Magn Reson Chem 2000, 38, 520. <http://dx.doi.org/10.1002/1097-458X(200007)38:7<520::AID-MRC681>3.0.CO;2-A>
  • Asaro Fioretta, Costa Giacomo, Dreos Renata, Pellizer Giorgio, von Philipsborn Wolfgang: Steric effects in organometallic compounds. A 103Rh NMR study of alkylrhodoximes. J Organomet Chem 1996, 513, 193. <http://dx.doi.org/10.1016/0022-328X(95)06052-X>
  • Öhrström Lars: The Correlation Between Transition Metal NMR Chemical Shifts and the Stability of Coordination Compounds. Comments Inorg Chem 1996, 18, 305. <http://dx.doi.org/10.1080/02603599608033866>
  • Wrackmeyer Bernd, Hofmann Thomas, Herberhold Max: Characterization of manganese sandwich complexes by 55Mn NMR spectroscopy. J Organomet Chem 1995, 486, 255. <http://dx.doi.org/10.1016/0022-328X(94)05052-D>
  • Wrackmeyer Bernd: NMR-Spektroskopie von Metallkernen in Lösung. Chem Unserer Zeit 1994, 28, 309. <http://dx.doi.org/10.1002/ciuz.19940280610>
  • Hollenstein† Roger, Stupperich Erhard: Assignment of15N-NMR resonances of vitamin B12 analogues by 2D-[15N,1H] long-range correlation: Fully [15N]-labelled Co-β-cyano-5-hydroxybenzimidazoylcobamide (factor III) and derivatives. HCA 1993, 76, 1258. <http://dx.doi.org/10.1002/hlca.19930760312>
  • Ceccon Alberto, Elsevier Cornelis J., Ernsting Jan M., Gambaro Alessandro, Santi Saverio, Venzo Alfonso: Indenyl hapticity in (η-indenyl-RhL2) and Cr(CO)3(μ-η:η-indenyl-RhL2) complexes. A 1H, 13C and 103Rh NMR spectroscopic study. Inorg Chim Ada 1993, 204, 15. <http://dx.doi.org/10.1016/S0020-1693(00)88108-6>
  • Dowler Michael E., Le Thuy X., DeShong Philip, von Philipsborn Wolfgang, Vöhler Markus, Rentsch Daniel: Probing the chemistry of organomanganese complexes. a kinetic study of the role of coordinate bonds in a demetalation reaction. Tetrahedron 1993, 49, 5673. <http://dx.doi.org/10.1016/S0040-4020(01)87276-8>
  • Ernsting J. M., Elsevier C. J., De Lange W. G. J., Timmer K.: Inverse two-dimensional31P,103Rh{1H}NMR of cationic rhodium(I) complexes containing chelating diphosphines. Magn Reson Chem 1991, 29, S118. <http://dx.doi.org/10.1002/mrc.1260291320>
  • Rehder Dieter: Metal NMR of organometallic (d-block) systems. Coord Chem Rev - 1991, 110, 161. <http://dx.doi.org/10.1016/0010-8545(91)80025-9>
  • Tavagnacco Claudio, Balducci Gabriele, Costa Giacomo, Täschler Karl, von Philipsborn Wolfgang: Electronic and Steric Influence of Axial and Equatorial Ligands in Vitamin B12 Model Complexes Derived from Cobaloxime: Electrochemical and59Co-NMR Studies. HCA 1990, 73, 1469. <http://dx.doi.org/10.1002/hlca.19900730527>
  • Köster Roland, Seidel Günter, Wrackmeyer Bernd, Schlosser Dieter: (Ligand)Übergangsmetall-π-Komplexe organosubstituierter 2,5-Dihydro-1,2,5-azasilaborole — Herstellung und Charakterisierung in Lösung. Chem Ber 1989, 122, 2055. <http://dx.doi.org/10.1002/cber.19891221105>
  • Mason Joan: NMR spectroscopy of the early transition metals. J Polyhedron 1989, 8, 1657. <http://dx.doi.org/10.1016/S0277-5387(00)80614-2>
  • Köster Roland, Seidel Günter, Boese Roland, Wrackmeyer Bernd: Substituierte 2,5-Dihydro-1,2,5-oxasilaborole — Herstellung, Komplexierungen und Ringöffnung. Chem Ber 1988, 121, 597. <http://dx.doi.org/10.1002/cber.19881210404>
  • Adams Christoph M., Cerioni Giovanni, Hafner Andreas, Kalchhauser Hermann, von Philipsborn Wolfgang, Prewo Roland, Schwenk Andreas: Synthesis and1H-,13C-, and57Fe-NMR spectra of mono- and bis[tricarbonyl(η4-diene)iron], and (η3-allyl)tetracarbonyliron trifluoroborate complexes. HCA 1988, 71, 1116. <http://dx.doi.org/10.1002/hlca.19880710526>
  • Benn Reinhard, Rufińska Anna: Indirect two-dimensional heteronuclear NMR spectroscopy of low-γ metal nuclei (M =183W,57Fe,103Rh,61Ni). Magn Reson Chem 1988, 26, 895. <http://dx.doi.org/10.1002/mrc.1260261015>
  • Mague Joel T.: Cobalt, rhodium and iridium. J Organomet Chem 1988, 351, 215. <http://dx.doi.org/10.1016/0022-328X(88)83169-3>
  • Piantini Umberto, Philipsborn Wolfgang Von, Salzer Albrecht, Buchmann Brigitte: Protonated diolefin complexes: Model systems for C;h activationvia metal complexation. HCA 1987, 70, 1487. <http://dx.doi.org/10.1002/hlca.19870700606>
  • Arz C., Pregosin P. S., Anklin C.: 103Rh NMR studies of cyclometallated Rh(III) Schiff's base complexes. Magn Reson Chem 1987, 25, 158. <http://dx.doi.org/10.1002/mrc.1260250214>
  • Hafner A, von Philipsborn W, Schwenk A: Mechanisms for the longitudinal and transverse relaxation of iron-57. Journal of Magnetic Resonance (1969) 1987, 74, 433. <http://dx.doi.org/10.1016/0022-2364(87)90266-6>
  • Benn Reinhard, Rufiñska Anna: Hochauflösende Metallkern-NMR-Spektroskopie von Organometallverbindungen. Angew Chem 1986, 98, 851. <http://dx.doi.org/10.1002/ange.19860981003>
  • Benn Reinhard, Rufińska Anna: High-Resolution Metal NMR Spectroscopy of Organometallic Compounds [New Analytical Methods (30)]. Angew Chem Int Ed Engl 1986, 25, 861. <http://dx.doi.org/10.1002/anie.198608611>