Pure and Applied Chemistry

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• Xu Ke, Cheng Bin, Li Yun, Xu Tingting, Yu Cunming, Zhang Jun, Ma Zhiqiang, Zhai Hongbin: Stereocontrolled Total Syntheses of (±)-Fawcettimine, (±)-Lycoflexine, and (±)-Lycoflexine N-Oxide. Org. Lett. 2014, 16, 196. <http://dx.doi.org/10.1021/ol403185g>
• Kobayashi Shū, Endo Toshimitsu, Yoshino Takumi, Schneider Uwe, Ueno Masaharu: Allylation Reactions of Aldehydes with Allylboronates in Aqueous Media: Unique Reactivity and Selectivity that are Only Observed in the Presence of Water. Chem. Asian J. 2013, 8, 2033. <http://dx.doi.org/10.1002/asia.201300440>
• Malkov Andrei V., Stončius Sigitas, Bell Mark, Castelluzzo Fabiomassimo, Ramírez-López Pedro, Biedermannová Lada, Langer Vratislav, Rulíšek Lubomír, Kočovský Pavel: Mechanistic Dichotomy in the Asymmetric Allylation of Aldehydes with Allyltrichlorosilanes Catalyzed by Chiral Pyridine N -Oxides. Chem. Eur. J. 2013, 19, 9167. <http://dx.doi.org/10.1002/chem.201203817>
• Castillo Rafael R., Abet Valentina, Aquino Maurizio, Gandara Zoila, Retailleau Pascal, Arseniyadis Siméon: Increasing the Dimensionality of Modular Domino Reactions Triggered by Oxidative Cleavage: A Two-Step Protocol Towards a Variety of Stereodefined Complex Oxygen Heterocycles. Eur. J. Org. Chem. 2013, 2013, 2401. <http://dx.doi.org/10.1002/ejoc.201201483>
• Varela Carla L., Amaral Cristina, Correia-da-Silva Georgina, Carvalho Rui A., Teixeira Natércia A., Costa Saul C., Roleira Fernanda M.F., Tavares-da-Silva Elisiário J.: Design, synthesis and biochemical studies of new 7α-allylandrostanes as aromatase inhibitors. Steroids 2013, 78, 662. <http://dx.doi.org/10.1016/j.steroids.2013.02.016>
• Wolf Larry M., Denmark Scott E.: A Theoretical Investigation on the Mechanism and Stereochemical Course of the Addition of (E)-2-Butenyltrimethylsilane to Acetaldehyde by Electrophilic and Nucleophilic Activation. J. Am. Chem. Soc. 2013, 135, 4743. <http://dx.doi.org/10.1021/ja311889v>
• Brook Michael A., Mohamed Mustafa: Lewis Acid-Mediated Addition of Amino Acid-Substituted α -Allylsilanes to Aromatic Acetals. HCA 2012, 95, 2660. <http://dx.doi.org/10.1002/hlca.201200533>
• Denmark Scott E., Weber Eric J., Almstead Neil G., Wolf Larry M.: On the stereochemical course of the addition of allylsilanes to aldehydes. Tetrahedron 2012, 68, 7701. <http://dx.doi.org/10.1016/j.tet.2012.05.084>
• Miyawaki Akari, Kikuchi Daisuke, Niki Masu, Manabe Yuki, Kanematsu Makoto, Yokoe Hiromasa, Yoshida Masahiro, Shishido Kozo: Total Synthesis of Natural Enantiomers of Heliespirones A and C via the Diastereoselective Intramolecular Hosomi-Sakurai Reaction. J. Org. Chem. 2012, 77, 8231. <http://dx.doi.org/10.1021/jo3016055>
• Li Jingwei, Liu Xiaoguang, Lee Daesung: Gold-Catalyzed Formation of Oxonium Ions from Enynes and Their Intra- and Intermolecular Trapping with Allylsilanes. Org Lett 2012, 14, 410. <http://dx.doi.org/10.1021/ol203206k>
• Kobayashi Shū, Arai Kenzo, Yamakawa Takeshi, Chen Yi-Jing, Salter Matthew M., Yamashita Yasuhiro: Lewis Acid-Mediated Acetal Substitution Reactions: Mechanism and Application to Asymmetric Catalysis. Synth Catal 2011, 353, 1927. <http://dx.doi.org/10.1002/adsc.201100346>
• Wu Haisheng, Yang Jin, Wang Lei: An Efficient and Practical Synthesis of Dibenzo[d,f][1,3]-dioxepines from 2,2′-Dihydroxybiphenyl with Terminal Alkynes Catalyzed by Lewis Acid TiCl4. Chin J Chem 2011, 29, 1211. <http://dx.doi.org/10.1002/cjoc.201190225>
• Murugan Kaliyappan, Srimurugan Sankareswaran, Chen Chinpiao: Silicomolybdic acid supported on silica gel: an efficient catalyst for Hosomi–Sakurai reactions. Tetrahedron 2011, 67, 5621. <http://dx.doi.org/10.1016/j.tet.2011.05.093>
• Cyclisierungen von Allyl- und Vinylsilanen. Nachr Chem Tech Lab 2010, 35, 358. <http://dx.doi.org/10.1002/nadc.19870350406>
• Schinzer D.: Selektive Transformationen mit pentakoordinierten Siliciumverbindungen. Nachr Chem Tech Lab 2010, 37, 28. <http://dx.doi.org/10.1002/nadc.19890370110>
• Wang Jiacheng, Masui Yoichi, Onaka Makoto: Direct allylation of α-aryl alcohols with allyltrimethylsilane catalyzed by heterogeneous tin ion-exchanged montmorillonite. Tetrahetron Lett 2010, 51, 3300. <http://dx.doi.org/10.1016/j.tetlet.2010.04.074>
• Martinez Rémi, Genêt Jean-Pierre, Darses Sylvain, Simon Marc-Olivier: Ruthenium-Catalyzed CH Bond Activation of Michael Acceptors: An Unusual Reactivity Leading to Allylsilanes. Adv Synth Catal 2009, 351, 153. <http://dx.doi.org/10.1002/adsc.200800600>
• Bower John F., Kim In Su, Patman Ryan L., Krische Michael J.: Katalytische Carbonyladdition durch Transferhydrierung: weg von vorab gebildeten Organometallreagentien. Angew. Chem. 2009, 121, 36. <http://dx.doi.org/10.1002/ange.200802938>
• Bower John F., Kim In Su, Patman Ryan L., Krische Michael J.: Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents. Angew. Chem. Int. Ed. 2009, 48, 34. <http://dx.doi.org/10.1002/anie.200802938>
• Kampen Daniela, Ladépêche Arnaud, Claßen Gerrit, List Benjamin: Brønsted Acid-Catalyzed Three-Component Hosomi–Sakurai Reactions. Adv Synth Catal 2008, 350, 962. <http://dx.doi.org/10.1002/adsc.200800036>
• Yang Ming-Song, Xu Li-Wen, Zhang Fei-Bao, Qiu Hua-Yu, Jiang Jian-Xiong, Lai Guo-Qiao: Highly efficient iron-catalyzed allylation of aromatic aldehydes with allyltriethoxysilane: one-pot and practical synthesis of homoallyl ethers. Appl Organometal Chem 2008, 22, 177. <http://dx.doi.org/10.1002/aoc.1368>
• Yamamura Masaki, Kano Naokazu, Kawashima Takayuki: Intramolecular allylation of the azo group of 2-(allylsilyl)azobenzenes and its photocontrol. J Organomet Chem 2007, 692, 313. <http://dx.doi.org/10.1016/j.jorganchem.2006.08.045>
• De Surya K., Gibbs Richard A.: Bismuth(III) chloride-catalyzed direct deoxygenative allylation of substituted benzylic alcohols with allyltrimethylsilane. Tetrahetron Lett 2005, 46, 8345. <http://dx.doi.org/10.1016/j.tetlet.2005.09.161>
• Kobashi Yohei, Minowa Tomofumi, Mukaiyama Teruaki: Trimethylsilyl Triflate Mediated New Carbon–Carbon Bond Forming Reactions between Benzyl Diphenylphosphinates and Organosilicon Compounds. Chem Lett 2005, 34, 756. <http://dx.doi.org/10.1246/cl.2005.756>
• Watahiki Tsutomu, Akabane Yusuke, Mori Seiji, Oriyama Takeshi: Iron(III) Chloride-Catalyzed Convenient One-Pot Synthesis of Homoallyl Benzyl Ethers Starting from Aldehydes. Org Lett 2003, 5, 3045. <http://dx.doi.org/10.1021/ol035019w>
• Lucius Roland, Loos Robert, Mayr Herbert: Kinetische Untersuchungen von Carbokation-Carbanion-Kombinationen: Schlüssel zu einem allgemeinen Modell polarer organischer Reaktivität. Angew Chem 2002, 114, 97. <http://dx.doi.org/10.1002/1521-3757(20020104)114:1<97::AID-ANGE97>3.0.CO;2-4>
• Lucius Roland, Loos Robert, Mayr Herbert: Kinetic Studies of Carbocation-Carbanion Combinations: Key to a General Concept of Polar Organic Reactivity. Angewandte Chemie-Int Ed 2002, 41, 91. <http://dx.doi.org/10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P>
• Beszant Stephen, Giannini Elios, Zanoni Giuseppe, Vidari Giovanni: Enantioselective synthesis of both enantiomers of γ-ionone, γ-damascone, karahana lactone and karahana ether. Tet Asymm 2002, 13, 1245. <http://dx.doi.org/10.1016/S0957-4166(02)00335-X>
• Nair Vijay, Rajesh C., Dhanya R., Rath Nigam P.: Lewis Acid Promoted Annulation of p-Quinoneimines by Allylsilanes:  A Facile Entry into Benzofused Heterocycles^†. Org Lett 2002, 4, 953. <http://dx.doi.org/10.1021/ol025503j>
• Kabalka George W., Wu Zhongzhi, Ju Yuhong: A Novel Titanium Tetrahalide-Mediated Carbon−Carbon Bond-Forming Reaction:  Regioselective Synthesis of Substituted (E,Z)-1,5-Dihalo-1,4-dienes. Org Lett 2002, 4, 3415. <http://dx.doi.org/10.1021/ol026507r>
• Itami Kenichiro, Kamei Toshiyuki, Mineno Masahiro, Yoshida Jun-ichi: AgOAc-Catalyzed Aldehyde Allylation Using Allyldimethyl(2-pyridyl)silane. Chem Lett 2002, 1084. <http://dx.doi.org/10.1246/cl.2002.1084>
• Shimizu Masaki, Kitagawa Hirotaka, Kurahashi Takuya, Hiyama Tamejiro: 1-Silyl-1-boryl-2-alkenes: Reagents for Stereodivergent Allylation Leading to 4-Oxy-(E)-1-alkenylboronates and 4-Oxy-(Z)-1-alkenylsilanes. Angew Chem 2001, 113, 4413. <http://dx.doi.org/10.1002/1521-3757(20011119)113:22<4413::AID-ANGE4413>3.0.CO;2-F>
• Shimizu Masaki, Kitagawa Hirotaka, Kurahashi Takuya, Hiyama Tamejiro: 1-Silyl-1-boryl-2-alkenes: Reagents for Stereodivergent Allylation Leading to 4-Oxy-(E)-1-alkenylboronates and 4-Oxy-(Z)-1-alkenylsilanes. Angewandte Chemie-Int Ed 2001, 40, 4283. <http://dx.doi.org/10.1002/1521-3773(20011119)40:22<4283::AID-ANIE4283>3.0.CO;2-3>
• Wang Ming Wen, Chen Yong Jun, Wang Dong: Catalytic allylation of hydrates of α-keto aldehydes and glyoxylates with allyltrimethylsilane using non-fluorine-containing sulfonic acids as catalysts. Heteroatom Chem 2001, 12, 534. <http://dx.doi.org/10.1002/hc.1081>
• Cosp Annabel, Romea Pedro, Talavera Pere, Urpí Fèlix, Vilarrasa Jaume, Font-Bardia Mercè, Solans Xavier: Enantioselective Addition of a Chiral Thiazolidinethione-Derived Titanium Enolate to Acetals. Org Lett 2001, 3, 615. <http://dx.doi.org/10.1021/ol0070177>
• Rubin Michael, Gevorgyan Vladimir: B(C₆F₅)₃-Catalyzed Allylation of Secondary Benzyl Acetates with Allylsilanes. Org Lett 2001, 3, 2705. <http://dx.doi.org/10.1021/ol016300i>
• Yadav J. S., Subba Reddy B. V., Madhuri Ch., Sabitha G.: Indium(III) Chloride Catalyzed Allylation of gem-Diacetates: A Facile Synthesis of Homoallyl Acetates. Chem Lett 2001, 18. <http://dx.doi.org/10.1246/cl.2001.18>
• Nair Vijay, Sheela K. C., Radhakrishnan K. V., Vinod A. U., Nair J. Somarajan, Rajesh C., Treesa P. M.: Novel heterocyclic construction via dipolar cycloadditions to 1,2-dicarbonyl compounds. J Heterocyclic Chem 2000, 37, 659. <http://dx.doi.org/10.1002/jhet.5570370323>
• Asao Naoki, Yamamoto Yoshinori: Lewis Acid-Catalyzed Hydrometalation and Carbometalation of Unactivated Alkynes. Bull Chem Soc Jpn 2000, 73, 1071. <http://dx.doi.org/10.1246/bcsj.73.1071>
• Knölker Hans-Joachim, Foitzik Norbert, Schmitt Oliver: Cycloadditions of allylsilanes, part 14. Enantiospecific synthesis of bicyclo[4.3.0]nonanes by asymmetric [3+2] cycloaddition of chiral allylsilanes. Tetrahetron Lett 1999, 40, 3557. <http://dx.doi.org/10.1016/S0040-4039(99)00551-1>
• Suzuki Takeshi, Oriyama Takeshi: Novel Reactions of Ethylene Acetals with Silyl-Substituted Nucleophiles. A Mild and Efficient Procedure for the Synthesis of Homoallyl Alkyl Ethers and Unsymmetrical Dialkyl Ethers. Synth Common 1999, 29, 1263. <http://dx.doi.org/10.1080/00397919908086101>
• Schierle Kerstin, Vahle Ruth, Steckhan Eberhard: Efficient Pathways to Precursors of Pyrrolidine Azasugar Structures. Eur J Org Chem 1998, 1998, 509. <http://dx.doi.org/10.1002/(SICI)1099-0690(199803)1998:3<509::AID-EJOC509>3.0.CO;2-V>
• Rajaonah Michael, Rock Michael H., Bégué Jean-Pierre, Bonnet-Delpon Danièle, Condon Sylvie, Nédélec Jean-Yves: Electrosynthesis of new functionalized difluoro allylsilanes. Tetrahetron Lett 1998, 39, 3137. <http://dx.doi.org/10.1016/S0040-4039(98)00462-6>
• Knölker Hans-Joachim, Baum Elke, Schmitt Oliver: Cycloadditions of allylsilanes, part 13. Lewis acid-promoted stereospecific [2+2] cycloaddition of crotylsilanes and methyl propynoate. Tetrahetron Lett 1998, 39, 7705. <http://dx.doi.org/10.1016/S0040-4039(98)01678-5>
• Knölker Hans-Joachim, Foitzik Norbert, Goesmann Helmut, Graf Regina, Jones Peter G., Wanzl Günter: Highly Stereoselective Synthesis of Bicyclo[n.3.0]alkanes by Titanium Tetrachloride Promoted [3 + 2] Cycloaddition of Allylsilanes and 1-Acetylcycloalkenes. Chem Eur J 1997, 3, 538. <http://dx.doi.org/10.1002/chem.19970030409>
• Knölker Hans-Joachim: Cycloadditions of allylsilances. Part 10. Stereoselective Construction of Ring Systems by Cycloaddition Reactions of allyltriisopropylsilance. J Prakt Chem 1997, 339, 304. <http://dx.doi.org/10.1002/prac.19973390158>
• Momose Takefumi, Takizawa Shinobu, Kirihara Masayuki: Bicyclo[3.3.1]nonanes as Synthetic Intermediates. XXIII.¹ A Breakthrough by Lanthanoid Mediation in Nucleophilic Addition of Carbanions to the Inert “Fork Head” Carbonyl in Bicyclo[3.3.1]nonan-3-ones. Synth Common 1997, 27, 3313. <http://dx.doi.org/10.1080/00397919708005631>
• Zhang Luo Cheng, Sakurai Hideki, Kira Mitsuo: Enantioselective Allylation of Aldehydes Using Tartrate Ester Modified Allylsilanes. Chem Lett 1997, 129. <http://dx.doi.org/10.1246/cl.1997.129>
• Danielmeier Karsten, Schierle Kerstin, Steckhan Eberhard: Ein neues chirales, kationisches β-Aminoalkoholäquivalent: variabler Zugang zu enantiomerenreinen Bausteinen für Hydroxyethylendipeptid-Isostere. Angew Chem 1996, 108, 2397. <http://dx.doi.org/10.1002/ange.19961081928>
• Zoorob Hanafi H., Abou-El Zahab Mohamed M., Abdel-Mogib Mamdouh, Ismail Mohamed A.: Peculiar reaction behaviour of barbituric acid derivatives towards aromatic amines. Tetrahedron 1996, 52, 10147. <http://dx.doi.org/10.1016/0040-4020(96)00537-6>
• Aggarwal Varinder.K., Vennall Graham.P.: Scandium trifluoromethanesulfonate, a novel catalyst for the addition of allyltrimethylsilane to aldehydes. Tetrahetron Lett 1996, 37, 3745. <http://dx.doi.org/10.1016/0040-4039(96)00636-3>
• Monti Honoré, Afshari Mohammad, Léandri Gilbert: Etude de la réactivité de l'allyltriméthylsilane avec les cétones α-cyclopropaniques en présence de tétrachlorure de titane. J Organomet Chem 1995, 486, 69. <http://dx.doi.org/10.1016/0022-328X(94)05029-B>
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• Taniguchi Masahiko, Oshima Koichiro, Utimoto Kiitiro: Stereoselective Allylation of 2-Formyl Amides or 3-Oxo Amides. Bull Chem Soc Jpn 1995, 68, 645. <http://dx.doi.org/10.1246/bcsj.68.645>
• Mayr Herbert, Gorath Gorden, Bauer Bernhard: Flüssiges Schwefeldioxid als Lewis-acides Solvens für die Alkylierung und Alkoxyalkylierung von Allylsilanen. Angew Chem 1994, 106, 793. <http://dx.doi.org/10.1002/ange.19941060716>
• Knölker Hans-Joachim, Baum Gerhard, Graf Regina: Lewis-Säure-vermittelte [2 + 2]-Cycloaddition von Allylsilanen an ungesättigte Ester: eine neuartige Methode zum Aufbau von Cyclobutanen. Angew Chem 1994, 106, 1705. <http://dx.doi.org/10.1002/ange.19941061530>
• Sato Tsuneo, Otera Junzo: Mechanistic insight into the cinnamylmetal-thioacetal reaction employing 2-acetoxy-2-phenylacetaldehyde monothioacetal. J Organomet Chem 1994, 473, 55. <http://dx.doi.org/10.1016/0022-328X(94)80105-3>
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• Hashimoto Yukihiko, Kagoshima Hirotaka, Saigo Kazuhiko: Allylation of carbonyl compounds mediated by germanium(II) iodide. Tetrahetron Lett 1994, 35, 4805. <http://dx.doi.org/10.1016/S0040-4039(00)76973-5>
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• Davis Anthony P., Jaspars Marcel: Silylierungsmittel-katalysierte Addition von Allyltrimethylsilan an Aldehyde: Me3SiB(OTf)4, ein äußerst wirksames Silylierungsreagens. Angew Chem 1992, 104, 475. <http://dx.doi.org/10.1002/ange.19921040427>
• Denmark Scott E., Almstead Neil G.: Spectroscopic studies on the TiCl4-promoted reaction of allylsilanes with aldehydes and α,β-enones. Tetrahedron 1992, 48, 5565. <http://dx.doi.org/10.1016/0040-4020(92)80007-3>
• Seehof Norbert, Mehler Christof, Breunig Stefan, Risse Wilhelm, Blosch Laura L., Gamble A.Scott, Boncella James M., Finkel'shtein E.Sh., Bykov V.I., Portnykh E.B.: Pd2+ catalyzed addition polymerizations of norbornene and norbornene derivatives. Journal of Molecular Catalysis 1992, 76, 219. <http://dx.doi.org/10.1016/0304-5102(92)80144-6>
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