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Pure Appl. Chem., 1977, Vol. 49, No. 1, pp. 107-113

http://dx.doi.org/10.1351/pac197749010107

Are reactions in superacid media due to protons or to powerful oxidising species such as SO3 or SbF5?

Michel Herlem

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  • Genuino Homer C., Opembe Naftali N., Njagi Eric C., McClain Skye, Suib Steven L.: A review of hydrofluoric acid and its use in the car wash industry. Journal of Industrial and Engineering Chemistry 2012, 18, 1529. <http://dx.doi.org/10.1016/j.jiec.2012.03.001>
  • Zhong D., Franke J.-H., Podiyanachari S. K., Blomker T., Zhang H., Kehr G., Erker G., Fuchs H., Chi L.: Linear Alkane Polymerization on a Gold Surface. Science 2011, 334, 213. <http://dx.doi.org/10.1126/science.1211836>
  • Herlem M, Mathieu C, Herlem D: About the reaction between asphaltenes and fluorosulfuric acid. J Fuel 2004, 83, 1665. <http://dx.doi.org/10.1016/j.fuel.2004.02.007>
  • Goeppert Alain, Bhering Daniel L., Sommer Jean, Mota Claudio J. A.: Reactivity of isobutane in fluorosulfonic based superacids. J Phys Org Chem 2002, 15, 869. <http://dx.doi.org/10.1002/poc.563>
  • Fărcaiu Dan, Li Jing Qi, Kogelbauer Andreas: The mechanism of conversion of hydrocarbons on sulfated metal oxides. Part IV. Kinetics of the reaction of methylcyclopentane on sulfated zirconia11Part III: A. Ghenciu and D. Fărcas̡iu, Catal. Lett., 44 (1997) 29. Part II: A. Ghenciu and D. Fărcas̡iu, J. Mol. Catal. 109 (1996) 273. Journal of Molecular Catalysis A 1997, 124, 67. <http://dx.doi.org/10.1016/S1381-1169(97)00067-8>
  • Herlem Michel, Jobert-Perol Anne: The anodic behavior of saturated hydrocarbons in fluorosulfuric acid. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 1991, 315, 87. <http://dx.doi.org/10.1016/0022-0728(91)80061-T>
  • Acidic sites on catalyst surfaces and their determination. Catal Today 1989, 5, 1. <http://dx.doi.org/10.1016/0920-5861(89)80034-3>
  • Kirchen R.P., Sorensen T.S., Wagstaff K., Walker A.M.: The characterization of and the evolution of molecular hydrogen by the μ-hydrido-bridged cyclodecyl cation. Relevance to the question of hydrocarbon protonation by superacids. Tetrahedron 1986, 42, 1063. <http://dx.doi.org/10.1016/S0040-4020(01)87510-4>
  • Rudenko A. P., Sarubin M. Ja., Pragst F.: Elektrochemische Oxydation organischer Verbindungen in Fluorsulfonsäure. I. Voltammetrische Untersuchung von Arylsulfonylfluoriden. J prakt Chem 1983, 325, 393. <http://dx.doi.org/10.1002/prac.19833250308>
  • Chang Clarence D.: Hydrocarbons from Methanol. Catal Rev —Sci Eng 1983, 25, 1. <http://dx.doi.org/10.1080/01614948308078874>
  • Feiring A.E.: Chemistry in hydrogen fluoride V. Catalysts for reaction of HF with halogenated olefins. J FLUORINE CHEM 1979, 14, 7. <http://dx.doi.org/10.1016/S0022-1139(00)82988-7>
  • Herlem Michel, Bobilliart Francis, Thiébault André, Jobert-Pérol Anne: The Reaction Between HSO3F and n-Alkanes. Anal Lett 1978, 11, 767. <http://dx.doi.org/10.1080/00032717808059729>